Polycarbonate-polyorganosiloxane copolymer and method for continuously producing same

Patent metadata

Field	Value
Publication number	US-9850351-B2
Application number	US-201615151742-A
Country	US
Kind code	B2
Filing date	May 11, 2016
Priority date	Jul 5, 2012
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

Provided are a polycarbonate-polyorganosiloxane copolymer having a carbon tetrachloride concentration of less than 4 ppm by mass, and the following production method for producing the polycarbonate-polyorganosiloxane copolymer. More specifically, provided is a method of continuously producing a polycarbonate-polyorganosiloxane copolymer, the method comprising the steps of: (A) continuously or intermittently taking a polymerization reaction liquid, which is obtained by polymerizing a dihydric phenol compound, a carbonate precursor, and a specific polyorganosiloxane in the presence of an alkaline compound aqueous solution and a water-insoluble organic solvent, out of a reactor; (B) separating the polymerization reaction liquid taken out in the step (A) into an aqueous phase and a water-insoluble organic solvent phase; (C) washing the water-insoluble organic solvent phase separated in the step (B), followed by separation thereof into an aqueous phase and a water-insoluble organic solvent phase; (D) concentrating the water-insoluble organic solvent phase separated in the step (C); and (E) recovering part or all of the water-insoluble organic solvent removed by evaporation in the step (D), followed by distillation purification thereof in a distillation column, the water-insoluble organic solvent obtained in the step (E) being reused as at least part of the water-insoluble organic solvent in the step (A) or as an extraction solvent for the aqueous phase separated in the step (B), or as both thereof, in the step (E), the distillation purification being performed while a concentration of the polycarbonate-polyorganosiloxane copolymer in a column bottom liquid of the distillation column is controlled to 6% by mass or less.

First claim

The invention claimed is:

1. A polycarbonate-polyorganosiloxane copolymer having a carbon tetrachloride concentration of greater than 0 ppm by mass to less than 4 ppm by mass and having a repeating unit represented by formula (I) and a constituent unit represented by formula (II):

where:
R 1 and R 2 each independently represent a halogen atom, an alkyl group having 1 to 6 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms;
X represents a single bond, an alkylene group having 1 to 8 carbon atoms, an alkylidene group having 2 to 8 carbon atoms, a cycloalkylene group having 5 to 15 carbon atoms, a cycloalkylidene group having 5 to 15 carbon atoms, —S—, —SO—, —SO 2 —, —O—, or —CO—; and
a and b each independently represent an integer of 0 to 4;

where:
R 3 to R 6 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, or an aryl group having 6 to 12 carbon atoms;
Y represents a single bond or an organic residue including an aliphatic or aromatic moiety; and
n represents an average repetition number, the average repetition number n being 70 to 120.

2. The polycarbonate-polyorganosiloxane copolymer according to claim 1 , wherein the copolymer has a viscosity-average molecular weight of 10,000 to 30,000.

3. The polycarbonate-polyorganosiloxane copolymer according to claim 1 , wherein the carbon tetrachloride concentration is greater than 0 ppm by mass to less than 1 ppm by mass.

4. The polycarbonate-polyorganosiloxane copolymer according to claim 1 , wherein the polycarbonate-polyorganosiloxane copolymer is obtained by interfacial polymerization.

5. The polycarbonate-polyorganosiloxane copolymer according to claim 1 , wherein a content of the constituent unit represented by formula (II) in the polycarbonate-polyorganosiloxane copolymer is 1 to 25% by mass.

6. The polycarbonate-polyorganosiloxane copolymer according to claim 1 , wherein the average repetition number n in the constituent unit represented by formula (II) is 70 to 100.

Assignees

• Idemitsu Kosan Co

Inventors

• Nagao Yukiko
• Ishikawa Yasuhiro
• Motegi Hiroaki

Classifications

• C08G64/406

  Purifying; Drying · CPC title

• C08G64/186 Primary

  containing polysiloxane sequences · CPC title

• C08G64/22

  using carbonyl halides · CPC title

• C08G77/34

  Purification · CPC title

• C08G64/24

  and phenols · CPC title