Multicomponent room temperature-curable organopolysiloxane composition, cured product of said composition, and molded product comprising said cured product

Patent metadata

Field	Value
Publication number	US-9850349-B2
Application number	US-201415106165-A
Country	US
Kind code	B2
Filing date	Oct 20, 2014
Priority date	Dec 17, 2013
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

Provided is a multicomponent room temperature-curable organopolysiloxane composition capable of providing a cured product superior in fast curability, storage stability and durability. The room temperature-curable organopolysiloxane composition comprises:
(A) an alkoxysilyl-ethylene group-terminated organopolysiloxane having in each molecule at least one silyl-ethylene bond represented by the following structural formula (1)

(wherein R 1 represents an alkyl group; R 2 represents a hydrocarbon group having 1 to 20 carbon atoms; a represents an integer of 1 to 3; and n represents an integer of 0 to 10);
(B) an organopolysiloxane represented by the following general formula (2)

(wherein R 2 represents a hydrocarbon group having 1 to 20 carbon atoms; and m represents a number at which such organopolysiloxane exhibits a viscosity of 10 to 1,000,000 mPa·s at 25° C.); and
(C) a curing catalyst.

First claim

The invention claimed is:

1. A room temperature-curable organopolysiloxane composition comprising:
(A) an alkoxysilyl-ethylene group-terminated organopolysiloxane having in one molecule at least one group represented by the following structural formula (1)

wherein R 1 represents an alkyl group that has 1 to 20 carbon atoms and may have one or more substituent groups, and when said alkyl group has 3 or more carbon atoms it may be a cycloalkyl group; R 2 represents a hydrocarbon group that has 1 to 20 carbon atoms and may have one or more substituent groups; a represents an integer of 1 to 3; and n represents an integer of 0 to 10;
(B) an organopolysiloxane in an amount of 10 to 250 parts by mass with respect to 100 parts by mass of said component (A), and represented by the following general formula (2)

wherein R 2 represents a hydrocarbon group that has 1 to 20 carbon atoms and may have one or more substituent groups; and m represents a number at which the organopolysiloxane exhibits a viscosity of 10 to 1,000,000 mPa·s at 25° C.; and
(C) a curing catalyst in an amount of 0.001 to 20 parts by mass with respect to 100 parts by mass of said component (A).

2. The room temperature-curable organopolysiloxane composition according to claim 1 , wherein said component (A) is a linear organopolysiloxane whose main chain comprises repetitive diorganosiloxane units.

3. The room temperature-curable organopolysiloxane composition according to claim 2 , wherein said component (A) is at least one alkoxysilyl-ethylene group-terminated organopolysiloxane selected from the diorganopolysiloxanes represented by the following general formulae (A) and (B)

wherein R 1 represents an alkyl group that has 1 to 20 carbon atoms and may have one or more substituent groups, and when said alkyl group has 3 or more carbon atoms it may be a cycloalkyl group; R 2 represents a monovalent hydrocarbon group that has 1 to 20 carbon atoms and may have one or more substituent groups; a represents an integer of 1 to 3; n represents an integer of 0 to 10; and each of 1 and m represents an integer of 0 to 2,000.

4. The room temperature-curable organopolysiloxane composition according to claim 1 , further comprising at least one of the following components (D) to (G) in amounts of the following parts by mass with respect to 100 parts by mass of said component (A):
(D) a hydrolyzable silane and/or a partial hydrolysis condensate thereof in an amount of 0.1 to 30 parts by mass;
(E) a filler in an amount of 1 to 1,000 parts by mass;
(F) an adhesion promotor in an amount of 0.1 to 30 parts by mass; and
(G) an organopolysiloxane in an amount of 1 to 100 parts by mass and represented by the following structural formula (3)

wherein R 2 represents a hydrocarbon group that has 1 to 20 carbon atoms and may have one or more substituent groups; and m represents an integer of 1 to 2,000.

5. The room temperature-curable organopolysiloxane composition according to claim 4 , wherein said composition is a two liquid-type comprising:
an organopolysiloxane composition I comprising said components (A) and (C) and optionally said component (G) and/or said component (E); and
an organosiloxane composition II comprising said component (B) and optionally said component (D) and/or said component (E).

6. The room temperature-curable organopolysiloxane composition according to claim 5 , wherein said component (F) and/or said component (G) are present in said organosiloxane composition I and/or said organosiloxane composition II.

7. A sealing agent, coating agent or adhesive agent comprising the room temperature-curable organopolysiloxane composition according to claim 1 .

8. A cured product of the room temperature-curable organopolysiloxane composition according to claim 1 .

9. A molded product comprising the cured product according to claim 8 .

10. The room temperature-curable organopolysiloxane composition according to claim 2 , further comprising at least one of the following components (D) to (G) in amounts of the following parts by mass with respect to 100 parts by mass of said component (A):
(D) a hydrolyzable silane and/or a partial hydrolysis condensate thereof in an amount of 0.1 to 30 parts by mass;
(E) a filler in an amount of 1 to 1,000 parts by mass;
(F) an adhesion promotor in an amount of 0.1 to 30 parts by mass; and
(G) an organopolysiloxane in an amount of 1 to 100 parts by mass and represented by the following structural formula (3)

wherein R 2 represents a hydrocarbon group that has 1 to 20 carbon atoms and may have one or more substituent groups; and m represents an integer of 1 to 2,000.

11. The room temperature-curable organopolysiloxane composition according to claim 3 , further comprising at least one of the following components (D) to (G) in amounts of the following parts by mass with respect to 100 parts by mass of said component (A):
(D) a hydrolyzable silane and/or a partial hydrolysis condensate thereof in an amount of 0.1 to 30 parts by mass;
(E) a filler in an amount of 1 to 1,000 parts by mass;
(F) an adhesion promotor in an amount of 0.1 to 30 parts by mass; and
(G) an organopolysiloxane in an amount of 1 to 100 parts by mass and represented by the following structural formula (3)

wherein R 2 represents a hydrocarbon group that has 1 to 20 carbon atoms and may have one or more substituent groups; and m represents an integer of 1 to 2,000.

Assignees

• Shinetsu Chemical Co

Inventors

• Yamaguchi Takahiro
• Sakamoto Takafumi

Classifications

• C08G77/16

  to hydroxy groups · CPC title

• C09K3/1018

  Macromolecular compounds having one or more carbon-to-silicon linkages · CPC title

• C08G77/20 Primary

  containing silicon bound to unsaturated aliphatic groups · CPC title

• C08K3/26

  Carbonates; Bicarbonates · CPC title

• C09D183/14

  in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms (C09D183/10 takes precedence) · CPC title