Conducting metal oxide and metal nitride nanoparticles

Patent metadata

Field	Value
Publication number	US-9850140-B2
Application number	US-201013321325-A
Country	US
Kind code	B2
Filing date	May 20, 2010
Priority date	May 21, 2009
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

Conducting metal oxide and nitride nanoparticles that can be used in fuel cell applications. The metal oxide nanoparticles are comprised of for example, titanium, niobium, tantalum, tungsten and combinations thereof. The metal nitride nanoparticles are comprised of, for example, titanium, niobium, tantalum, tungsten, zirconium, and combinations thereof. The nanoparticles can be sintered to provide conducting porous agglomerates of the nanoparticles which can be used as a catalyst support in fuel cell applications. Further, platinum nanoparticles, for example, can be deposited on the agglomerates to provide a material that can be used as both an anode and a cathode catalyst support in a fuel cell.

First claim

What is claimed is:

1. Conducting metal oxide and/or metal nitride nanoparticles,
wherein the metal oxide comprises a metal selected from titanium, niobium, tantalum, tungsten and combinations thereof, and oxygen,
wherein the metal nitride comprises a metal selected from titanium, niobium, tantalum, tungsten, zirconium, and combinations thereof, and nitrogen,
wherein the metal oxide nanoparticles have at least one metal that has at least one valence electron available for conduction,
wherein the nanoparticles have a conductivity of at least 0.5 S/cm,
wherein the nanoparticles have a rutile structure, and
wherein the length of the longest axis of the nanoparticles is 20 nm to 200 nm.

2. The conducting metal oxide and/or nitride nanoparticles of claim 1 , wherein the metal oxide further comprises a metal selected from vanadium, molybdenum, ruthenium, tin, iron, chromium, manganese, nickel, cobalt and combinations thereof.

3. The metal oxide and/or nitride nanoparticles of claim 2 , wherein the nanoparticles have a composition represented as Ti 1−x M x O 2 , wherein M is a metal selected from tungsten, vanadium, niobium, tantalum, tin and ruthenium, wherein x is from 0.001 to 0.6.

4. The metal oxide and/or nitride nanoparticles of claim 2 , wherein the nanoparticles have a composition represented as Ti 1−x−y M x M′ y O 2 , wherein M and M′ are different metals and are selected from tungsten, vanadium, niobium, tantalum, tin and ruthenium, wherein x is from 0.01 to 0.5, and wherein y is 0.01 to 0.5.

5. The metal oxide and/or nitride nanoparticles of claim 2 , wherein the nanoparticles have a composition represented as Ti 1−x−y M x A′ y O 2 , wherein M is tungsten and A′ is a metal selected from chromium, manganese, iron, cobalt, and nickel, wherein if A′ is chromium x is greater than or equal to y and x+y is less than 0.4, wherein if A′ is manganese, iron, cobalt, or nickel x is greater than or equal to 2y and x+y is less than 0.4.

6. The conducting metal oxide and/or nitride nanoparticles of claim 1 , wherein the metal nitride further comprises molybdenum.

7. The metal oxide and/or nitride nanoparticles of claim 6 , wherein the nanoparticles have a composition represented as Ti 1−x Mo x N, Ti 1−x W x N or Nb 1−x W x N, wherein x is from 0.01 to 0.50.

8. A porous conducting material comprising agglomerates of the conducting metal oxide and/or nitride nanoparticles of claim 1 , wherein the length of the longest axis of the agglomerates is 20 nm to 10 microns,
wherein the material has pores and the longest axis of the pore opening is 50 to 500 nm,
wherein the material has a conductivity of at least 0.5 S/cm, and
wherein the nanoparticles have a rutile structure.

9. The porous conducting material of claim 8 , wherein the metal oxide of the conducting metal oxide and/or nitride nanoparticles of claim 1 further comprise a metal selected from vanadium, molybdenum, ruthenium, tin, iron, chromium, manganese, nickel, cobalt and combinations thereof.

10. The porous conducting material of claim 8 , wherein the metal nitride of the conducting metal oxide and/or nitride nanoparticles of claim 1 further comprise molybdenum.

11. The porous conducting material of claim 8 , wherein the material has at least 50% porosity.

12. The porous conducting material of claim 11 , wherein the material has 65% to 85% porosity.

13. The porous conducting material of claim 8 , wherein the length of the longest axis of the agglomerates is 50 nm to 1 micron.

14. The porous conducting material of claim 8 , wherein the material further comprises platinum.

15. The porous conducting material of claim 14 , wherein the platinum is disposed on the surface of the material.

16. A fuel cell comprising an electrode comprising the porous conducting material of claim 8 .

17. The fuel cell of claim 16 , wherein the metal oxide of the porous conducting material further comprises a metal selected from vanadium, molybdenum, ruthenium, tin, iron, chromium, manganese, nickel, cobalt and combinations thereof.

18. The fuel cell of claim 16 , wherein the metal nitride of the porous conducting material further comprises molybdenum.

Assignees

• Disalvo Jr Francis J
• Subban Chinmayee V
• Univ Cornell

Inventors

• Disalvo Jr Francis J
• Subban Chinmayee V

Classifications

• C01G23/047 Primary

  Titanium dioxide · CPC title

• C01P2002/72

  by d-values or two theta-values, e.g. as X-ray diagram · CPC title

• C01G33/00

  Compounds of niobium · CPC title

• C01G41/02

  Oxides; Hydroxides · CPC title

• H01B1/08

  oxides · CPC title