Flexible and stretchable graphene film and preparing method of the same
US-2015273737-A1 · Oct 1, 2015 · US
US9849629B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-9849629-B2 |
| Application number | US-201414907668-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 21, 2014 |
| Priority date | Aug 23, 2013 |
| Publication date | Dec 26, 2017 |
| Grant date | Dec 26, 2017 |
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The present invention relates to a process for the formation of a structured film, a structured film as such, an article comprising the structured film, a device for the continuous formation of such a structured film and a composite comprising the structured film.
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The invention claimed is: 1. A process for the formation of a structured porous film comprising: a) applying a porous film onto an elastic substrate in a stretched state such that a reversible adhesion of the porous film on the stretched substrate occurs, b) relaxing the substrate with the applied film thereon to obtain a structured porous film, and c) removing the structured porous film from the substrate. 2. The process according to claim 1 , further comprising applying a backer material to the structured porous film. 3. The process according to claim 1 , wherein the porous film comprises a member selected from fluoropolymer, a polyvinylalcohol, a polyurethane and combinations thereof. 4. The process according to claim 3 , wherein the porous film comprises a member selected from polytetrafluoroethylene (PTFE) a modified PTFE, a fluorothermoplastic, a fluoroelastomer and combinations thereof. 5. The process according to claim 1 , wherein the porous film has a thickness between 0.5 μm and 250 μm. 6. The process according to claim 1 , wherein the substrate comprises a member selected from a polysiloxane, fluorosilicone a rubber and combinations thereof. 7. The process according to claim 1 , wherein the substrate is stretched at a processing ratio of at least 110% in at least one direction. 8. The process according to claim 1 , wherein the elastic substrate is stretched at a processing ratio of at most 1100% in at least one direction. 9. A structured porous film obtained by the process according to claim 1 . 10. The structured film according to claim 9 , wherein structures in the structured film have a height of at least two times the thickness of a non-structured film, and wherein the structure density in at least one direction is at least 1/mm. 11. A structured porous film comprising a porous film reversibly adhered to an elastic substrate, wherein structures in the porous film have a height at least two times the thickness of a non-structured film and the structure density in at least one direction is at least 1/mm. 12. The structured porous film according to claim 11 , wherein the structure density in at least one direction is at least 2/mm. 13. The structured porous film according to claim 12 , wherein the structure height is from 2 μm to 2000 μm. 14. The structured porous film according to claim 13 , wherein the area increase factor of the structured film is at least 1.8. 15. An article comprising a structured porous film according to claim 11 , wherein said elastic substrate is removed. 16. The article according to claim 15 , wherein the article is a vent or a filter. 17. A structured porous film obtained by the process of claim 1 , wherein said structured porous film has applied thereto a backer material to form a composite, and wherein said composite has an asymmetric airflow of at least 30%. 18. A composite comprising a structured film obtained by the process of claim 1 and having an asymmetric airflow of at least 30%. 19. A structured porous film consisting of: a porous film having structures in the porous film that have a height at least two times the thickness of a non-structured film and the structure density in at least one direction is at least 1/mm, wherein said porous film has a multi-layered structure. 20. The structured porous film according to claim 19 , wherein the structure density in at least one direction is at least 2/mm. 21. The structured porous film according to claim 20 , wherein the structure height is from 2 μm to 2000 μm. 22. A structured porous film comprising: a porous film having structures therein that have a height at least two times the thickness of the non-structured film and the structure density in at least one direction is at least 1/mm, wherein said structures are permanent in said porous film separate from a substrate. 23. The structured porous film according to claim 22 , wherein the structure density in at least one direction is at least 2/m. 24. The structured porous film according to claim 22 , wherein the structure height is from 2 μm to 2000 μm. 25. The structured porous film according to claim 24 , wherein the area increase factor of the structured film is at least 1.8. 26. The structured porous film according to claim 22 , wherein said porous film has a multi-layered structure. 27. The structured porous film according to claim 11 , wherein said porous film has a multi-layered structure. 28. The composite of claim 18 , wherein said composite is in the form of a vent or filter.
Polysiloxanes · CPC title
comprising polysiloxanes · CPC title
being porous, e.g. foam · CPC title
Films or sheets · CPC title
of synthetic resin · CPC title
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