Process and plant for the production of liquid acid

Patent metadata

Field	Value
Publication number	US-9849419-B2
Application number	US-201415308720-A
Country	US
Kind code	B2
Filing date	May 9, 2014
Priority date	May 9, 2014
Publication date	Dec 26, 2017
Grant date	Dec 26, 2017

Abstract

A process for the production of liquid acid, comprising the steps of: feeding liquid acid with a first concentration into a gas purification; passing a gas through the gas purification such that a second concentration of the liquid acid is reached; withdrawing the liquid acid from the sump of the gas purification, where in the gas purification sump is divided by a partition wall into a first and a second section. The concentration of the liquid acid collected in the first section is adjusted to the first concentration. The liquid acid with the first concentration from the first section is at least partially fed back into step and the liquid acid with the second concentration collected in the second section is at least partially withdrawn as product.

First claim

The invention claimed is:

1. A process for the production of sulfuric acid, comprising the steps of:
(i) feeding liquid acid with a first concentration into a gas purification in form of a packed bed absorber or a packed bed drying tower;
(ii) passing a gas through the gas purification such that a second concentration of the liquid acid is reached;
(iii) withdrawing the liquid acid from the sump of the gas purification, wherein the gas purification sump is divided by a partition wall into a first and a second section,

wherein
the concentration of the liquid acid collected in the first section is adjusted to the first concentration,
the liquid acid with the first concentration from the first section is at least partially fed back into step (i), and
the liquid acid with the second concentration collected in the second section is at least partially withdrawn as product, and
the concentration of the liquid acid in the first section is adjusted with acid or water.

2. The process according to claim 1 , wherein the gas in step (ii) is conducted through the gas purification in counter-flow or in co-current flow to the liquid acid.

3. The process according to claim 1 , wherein the first and/or the second section is level controlled.

4. The process according to claim 1 , wherein the volume of down coming acid introduced into the second section is greater than the amount of product withdrawn from the second section.

5. The process according to claim 1 , wherein the liquid acid is sulfuric acid or oleum and that the gas comprises SO 3 .

6. A plant for the production of sulfuric acid, by a process according to claim 1 , comprising a gas purifier in form of a packed bed absorber or a packed bed drying tower containing a supply system for liquid acid, a gas inlet, and a gas purifier sump, wherein the gas purifier sump is divided by a partition wall into a first section and a second section, that separate outlets are provided for the first and second sections, respectively, and that the first section is connected with the acid supply system via a recycling line,
wherein an inlet for an adjusting liquid is provided in the first section.

7. The plant according to claim 6 , wherein a lance is provided for introducing the adjusting liquid into the first section.

8. The plant according to claim 6 , wherein the partition wall is made of bricks or carbon steel or stainless steel.

9. The plant according to claim 6 , wherein the top level of the partition wall is located below the lowest point of the gas inlet.

10. The plant according to claim 6 , wherein an overflow is provided between the first and second sections.

11. The plant according to claim 6 , wherein a level control is provided in the first and/or second section.

Assignees

• Outotec Finland Oy

Inventors

• Daum Karl-Heinz
• Storch Hannes
• Schalk Wolfram

Classifications

• C01B17/88

  Concentration of sulfuric acid · CPC title

• B01D53/507 Primary

  by treating the gases with other liquids · CPC title

• B01D53/1481

  Removing sulfur dioxide or sulfur trioxide · CPC title

• B01D2251/506

  Sulfuric acid · CPC title

• C01B17/806

  Absorbers; Heat exchangers · CPC title