Metal oxide dispersion and uses thereof

Patent metadata

Field	Value
Publication number	US-9846263-B2
Application number	US-201414539280-A
Country	US
Kind code	B2
Filing date	Nov 12, 2014
Priority date	Nov 26, 2013
Publication date	Dec 19, 2017
Grant date	Dec 19, 2017

Abstract

The present invention provides a metal oxide dispersion comprises a metal oxide, a millbase and a dispersant. The dispersant in the metal oxide is selected from a group consisting of a phosphoric acid polyester copolymer, a trimethoxysilane compound, a triethoxysilanes compound, dimethylamino ethyl methacrylate (DMAEMA) and a combination thereof, and the dispersion is substantially free of water. The metal oxide dispersion of the invention is useful for manufacturing an inkjet ink to provide a high-quality color image on a contact lens or a mold so as to produce a colored contact lens.

First claim

What is claimed is:

1. A metal oxide dispersion composition comprising a metal oxide, a dispersant, a radical inhibitor, a thixotropic agent and a millbase, wherein the dispersant is selected from a group consisting of a phosphoric acid polyester copolymer, a trimethoxysilane compound, a triethoxysilanes compound, dimethylamino ethyl methacrylate (DMAEMA) and a combination thereof, wherein the radical inhibitor is selected from the group consisting of monomethyl ether of hydroquinone (MEHQ), hydroquinone (HQ), 4-hydroxytempo, formally 4-hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO), and butylated hydroxytoluene (BHT), wherein the thixotropic agent is silicon dioxide dispersion, wherein the dispersion is free of water, and wherein the metal oxide dispersion is used for making inkjet color ink for contact lens.

2. The metal oxide dispersion composition of claim 1 , wherein the radical inhibitor is monomethyl ether of hydroquinone (MEHQ).

3. The metal oxide dispersion composition of claim 1 , wherein the metal oxide has an average diameter that is not greater than 60 nanometers.

4. The metal oxide dispersion composition of claim 3 , wherein the metal oxide has an average diameter that is not greater than 50 nanometers.

5. The metal oxide dispersion composition of claim 1 , wherein the millbase is selected from a group consisting of a difunctional acrylate monomer, a monofunctional acrylate and a combination thereof.

6. The metal oxide dispersion composition of claim 5 , wherein the millbase is a difunctional acrylate monomer.

7. The metal oxide dispersion composition of claim 1 , wherein the metal oxide is a titanium dioxide.

8. The metal oxide dispersion composition of claim 7 , wherein the dispersant is a phosphoric acid polyester copolymer.

9. The metal oxide dispersion composition of claim 1 , wherein the metal oxide is selected from a group consisting of iron(II) oxide (FeO), iron(II,III) oxide (Fe 3 O 4 ), iron(III) oxide (Fe 2 O 3 ), oxyhydroxides and a combination thereof.

10. The metal oxide dispersion composition of claim 9 , the dispersant is selected from a group consisting of a trimethoxysilane compound, a triethoxysilanes compound and a combination thereof.

11. The metal oxide dispersion composition of claim 1 , wherein the silicon dioxide dispersion comprising a radical inhibitor selected from the group consisting of monomethyl ether of hydroquinone (MEHQ), hydroquinone (HQ), 4-hydroxytempo, formally 4-hydroxy-2,2,6,6-tetramethylpiperidin-1-oxyl (TEMPO), butylated hydroxytoluene (BHT).

12. The metal oxide dispersion composition of claim 11 , wherein the radical inhibitor in silicon dioxide dispersion is monomethyl ether of hydroquinone (MEHQ).

Assignees

• Novartis Ag

Inventors

• Breitkopf Richard Charles
• Panicker Rahul

Classifications

• G02B1/10 Primary

  Optical coatings produced by application to, or surface treatment of, optical elements (G02B1/08 takes precedence) · CPC title

• C09D11/326 Primary

  characterised by the pigment dispersant · CPC title

• B29D11/00894

  colouring or tinting · CPC title

• C09D17/007

  Metal oxide · CPC title

• G02C7/021

  with pattern for identification or with cosmetic or therapeutic effects (methods and processes take preference, e.g. printing, marking or copying processes B41M; identification in general G09F3/00; producing decorative effects in general B44C; surface treatment of glass C03C15/00 - C03C23/00; positioning or marking of lenses B24B13/0055) · CPC title