Method and device for dissolved gas analysis

Patent metadata

Field	Value
Publication number	US-9846148-B2
Application number	US-201615275089-A
Country	US
Kind code	B2
Filing date	Sep 23, 2016
Priority date	Dec 19, 2012
Publication date	Dec 19, 2017
Grant date	Dec 19, 2017

Abstract

A system, comprising at least one source for irradiating electromagnetic radiation into a sample fluid and a reference fluid resulting in a change in a temperature of the sample fluid and a change in a temperature of the reference fluid, and a processing subsystem that monitors and determines a concentration of a gas of interest dissolved in the sample fluid based upon a difference between the change in the temperature of the sample fluid and the change in the temperature of the reference fluid, wherein the reference fluid does not contain the gas of interest, and the electromagnetic radiation has a wavelength range corresponding to a spectral absorption range of the gas of interest.

First claim

What is claimed is:

1. A method, comprising:
irradiating, in a first irradiating process, a sample fluid and a reference fluid by electromagnetic radiation having a first wavelength range resulting in a first time temperature change of the sample fluid and a first time temperature change of the reference fluid, wherein the sample fluid or the reference fluid are substantially non-transparent;
determining a first difference based upon the first time temperature change of the sample fluid and the first time temperature change of the reference fluid;
irradiating, in a second irradiating process, the sample fluid and the reference fluid by electromagnetic radiation having a second wavelength range resulting in a second time temperature change of the sample fluid and a second time temperature change of the reference fluid;
determining a second difference based upon the second time temperature change of the sample fluid and the second time temperature change of the reference fluid; and
determining a concentration of a gas of interest in the sample fluid based upon the first difference and the second difference.

2. The method of claim 1 , wherein the first irradiating process comprises simultaneously irradiating the sample fluid and the reference fluid by the electromagnetic radiation having the first wavelength range, further comprising:
irradiating a first portion of the electromagnetic radiation having the first wavelength range into the sample fluid; and
irradiating a second portion of the electromagnetic radiation having the first wavelength range into the reference fluid.

3. The method of claim 2 , wherein intensity of the first portion of the electromagnetic radiation having the first wavelength range is substantially similar to intensity of the second portion of the electromagnetic radiation having the first wavelength.

4. The method of claim 1 , wherein the first wavelength range corresponds to a spectral absorption peak of the gas of interest and the second wavelength range corresponds to a spectral absorption valley of the gas of interest.

5. The method of claim 1 , wherein the reference fluid does not contain the gas of interest.

6. A method, comprising:
irradiating, in a first irradiating process, a sample fluid by electromagnetic radiation having a first wavelength range resulting in a first time temperature change of the sample fluid;
irradiating, in a second irradiating process, a reference fluid by a second wavelength range resulting in a first time temperature change of the reference fluid, wherein the sample fluid or the reference fluid are substantially non-transparent;
determining a first difference based upon the first time temperature change of the sample fluid and the first time temperature change of the reference fluid; and
monitoring and determining the concentration of the gas of interest in the sample fluid based upon the first difference.

7. The method of claim 6 , wherein the sample fluid and the reference fluid are substantially same.

8. The method of claim 6 , further comprising:
irradiating the sample fluid and the reference fluid by electromagnetic radiation having the second wavelength range resulting in a second time temperature change of the sample fluid and a second time temperature change of the reference fluid;
determining a second difference based upon the second time temperature change of the sample fluid and the second time temperature change of the reference fluid; and
monitoring and determining concentration of a gas of interest based upon a third difference between the first difference and the second difference.

9. The method of claim 8 , wherein the sample fluid is substantially similar to the reference fluid.

10. The method of claim 9 , wherein the first wavelength range corresponds to a spectral absorption peak of the gas of interest and the second wavelength range corresponds to a spectral absorption valley of the gas of interest.

11. The method of claim 10 , wherein the reference fluid contains the gas of interest.

12. The method of claim 1 , wherein the second irradiating comprises simultaneously irradiating the sample fluid and the reference fluid by the electromagnetic radiation having the second wavelength range, further comprising:
irradiating a third portion of the electromagnetic radiation having the second wavelength range into the sample fluid; and
irradiating a fourth portion of the electromagnetic radiation having the second wavelength range into the reference fluid.

13. The method of claim 12 , wherein intensity of the third portion of the electromagnetic radiation having the second wavelength is substantially similar to intensity of the fourth portion of the electromagnetic radiation having the second wavelength.

Assignees

• Gen Electric

Inventors

• Maity Sandip
• Kavoori Sethurnadhavan Nagapriya
• Palanganda Poonacha Samhitha
• Raghavendra Prasad Prashanth

Classifications

• G01N33/2841 Primary

  Gas in oils, e.g. hydrogen in insulating oils · CPC title

• G01N25/005

  by investigating specific heat · CPC title

• G01N21/3504

  for analysing gases, e.g. multi-gas analysis · CPC title