Method to produce catalytically active nanocomposite coatings

Patent metadata

Field	Value
Publication number	US-9845441-B2
Application number	US-201615012667-A
Country	US
Kind code	B2
Filing date	Feb 1, 2016
Priority date	Sep 30, 2011
Publication date	Dec 19, 2017
Grant date	Dec 19, 2017

Abstract

A nanocomposite coating and method of making and using the coating. The nanocomposite coating is disposed on a base material, such as a metal or ceramic; and the nanocomposite consists essentially of a matrix of an alloy selected from the group of Cu, Ni, Pd, Pt and Re which are catalytically active for cracking of carbon bonds in oils and greases and a grain structure selected from the group of borides, carbides and nitrides.

First claim

The invention claimed is:

1. A method for lubricating materials in wear contact, comprising the steps of:
providing a base material;
disposing a nanocomposite coating on the base material, the nanocomposite consisting essentially of a microstructural matrix of a catalytically active alloy with grains embedded in the microstructural, the microstructural matrix selected from the group of Cu, Ni, Pd, Pt and Re and mixtures thereof and the grains selected from the group of transition metal carbides, transition metal nitrides, transition metal carbo-nitrides, transition metal borides, refractory metal carbides, refractory metal nitrides, refractory metal carbo-nitrides, refractory metal borides
disposing an oil on the nanocomposite coating;
engaging the nanocomposite coating with a surface, the oil disposed therebetween;
cracking carbon bonds of the oil;
forming a carbon film disposed between the coating and the surface, thereby lubricating the nanocomposite coating.

2. The method as defined in claim 1 wherein the alloy is about 1% to 10% by weight and the grains from about 90% to 99% by weight.

3. The method as defined in claim 1 wherein the base material is selected from the group of a metal and a ceramic.

4. The method as defined in claim 1 wherein the base material comprises a steel based material.

5. The method as defined in claim 1 wherein the oil is essentially free of additives.

6. The method as defined in claim 1 where the carbon film consists essentially of diamond like carbon.

7. The method as defined in claim 1 where the grains are selected from the group of refractory metal carbides, carbo-nitrides, nitrides and borides.

8. A method for lubricating materials in wear contact, comprising the steps of:
providing a base material;
disposing a nanocomposite coating on the base material, the nanocomposite consisting essentially of about 1% to 10% by weight a microstructural matrix of a catalytically active alloy with about 90% to 99% by weight grains embedded in therein, the microstructural matrix selected from the group of Cu, Ni, Pd, Pt and Re and mixtures thereof and the grains selected from the group of transition metal carbides, transition metal nitrides, transition metal carbo-nitrides, transition metal borides, refractory metal carbides, refractory metal nitrides, refractory metal carbo-nitrides, refractory metal borides;
disposing a hydrocarbon on the nanocomposite coating;
engaging the nanocomposite coating with a surface, the hydrocarbon disposed therebetween;
forming a carbon film disposed between the coating and the surface, thereby lubricating the nanocomposite coating.

9. The method as defined in claim 8 wherein the base material is selected from the group of a metal and a ceramic.

10. The method as defined in claim 8 wherein the base material comprises a steel based material.

11. The method as defined in claim 8 wherein the hydrocarbon is an oil.

12. The method as defined in claim 8 where the carbon film consists essentially of diamond like carbon.

13. The method as defined in claim 8 where the grains are selected from the group of refractory metal carbides, carbo-nitrides, nitrides and borides.

14. A method for lubricating materials in wear contact, comprising the steps of:
providing a base material;
disposing a nanocomposite coating on the base material, the nanocomposite consisting essentially of a microstructural matrix of a catalytically active alloy with grains embedded in the microstructural, the microstructural matrix selected from the group of Cu, Ni, Pd, Pt and Re and mixtures thereof and the grains selected from the group of transition metal carbides, transition metal nitrides, transition metal carbo-nitrides, transition metal borides, refractory metal carbides, refractory metal nitrides, refractory metal carbo-nitrides, refractory metal borides
disposing a hydrocarbon on the nanocomposite coating;
engaging the nanocomposite coating with a surface, the hydrocarbon disposed therebetween;
forming a carbon film disposed between the coating and the surface, thereby lubricating the nanocomposite coating.

15. The method as defined in claim 14 wherein the alloy is about 1% to 10% by weight and the grains from about 90% to 99% by weight.

16. The method as defined in claim 14 wherein the base material is selected from the group of a metal and a ceramic.

17. The method as defined in claim 14 wherein the base material comprises a steel based material.

18. The method as defined in claim 14 where the carbon film consists essentially of diamond like carbon.

19. The method as defined in claim 14 where the grains are selected from the group of refractory metal carbides, carbo-nitrides, nitrides and borides.

Assignees

• Uchicago Argonne Llc

Inventors

• Erdemir Ali
• Eryilmaz Osman Levent
• Urgen Mustafa
• Kazmanli Kursat

Classifications

• C10M2201/061

  Carbides; Hydrides; Nitrides · CPC title

• B01J27/22

  Carbides · CPC title

• C10M169/04 Primary

  Mixtures of base-materials and additives · CPC title

• B01J27/24

  Nitrogen compounds · CPC title

• C10N2010/06

  Groups 3 or 13 · CPC title