Method for producing olefins and monocyclic aromatic hydrocarbons by a combination of steam cracking, dicyclopentadiene reduction, and cracking and reforming

Patent metadata

Field	Value
Publication number	US-9845433-B2
Application number	US-201314437298-A
Country	US
Kind code	B2
Filing date	Oct 25, 2013
Priority date	Oct 25, 2012
Publication date	Dec 19, 2017
Grant date	Dec 19, 2017

Abstract

A method for producing an olefin and a monocyclic aromatic hydrocarbon of the present invention includes a dicyclopentadiene removal treatment step of removing dicyclopentadienes having a dicyclopentadiene skeleton from a feedstock oil which is a thermally-cracked heavy oil obtained from an apparatus for producing ethylene and which has a 90 volume % distillate temperature, as a distillation characteristic, of 390° C. or lower; and a cracking and reforming reaction step of obtaining a product containing an olefin and a monocyclic aromatic hydrocarbon by bringing the feedstock oil having a content of dicyclopentadienes adjusted to 10% by weight or less by treating a part or all of the feedstock oil through the dicyclopentadiene removal step into contact with a catalyst and reacting the feedstock oil.

First claim

The invention claimed is:

1. A method for producing an olefin and a monocyclic aromatic hydrocarbon, comprising:
thermally cracking a feedstock in a steam cracker to obtain a feedstock oil comprising a dicyclopentadienes content and having a 90 volume % distillation temperature of 220-390° C.;
treating the feedstock oil to reduce the dicyclopentadienes content in the feedstock oil to obtain a treated feedstock oil comprising a dicyclopentadienes content of 10% by weight or less; and
reacting the treated feedstock oil by contact with a cracking and reforming catalyst containing crystalline aluminosilicate to obtain a product comprising an olefin having 2 to 4 carbon atoms and a monocyclic aromatic hydrocarbon having 6 to 8 carbon atoms;
wherein
treating the feedstock oil comprises heating the feedstock oil to convert dicyclopentadiene to two cyclopentadiene monomers, or selectively hydrogenating an olefin portion included in the dicyclopentadiene, and
the thermally cracking is carried out at a temperature of 770-850° C.

2. The method according to claim 1 , further comprising:
partially hydrogenating part or all of the treated feedstock oil before reacting the treated feedstock oil.

3. The method according to claim 2 ,
wherein, the partially hydrogenating part or all of the treated feedstock oil is conducted at a hydrogen partial pressure in a range of 1 MPa to 9 MPa, a hydrogenation temperature in a range of 150° C. to 400° C., and in the presence of a catalyst comprising at least one metal selected from Group 6 metals in the periodic table at an amount of 10% by mass to 30% by mass, at least one metal selected from Groups 8 to 10 metals in the periodic table at an amount of 1% by mass to 7% by mass, and an inorganic carrier containing aluminum oxide.

4. The method according to claim 1 , further comprising:
returning a heavy fraction having 9 or more carbon atoms from the product to the reacting step.

5. The method according to claim 1 ,
wherein, in reacting the treated feedstock oil, two or more fixed-bed reactors are used and reacting the treated feedstock oil and reproduction of the cracking and reforming catalyst are repeated while the reactors are periodically switched.

6. The method according to claim 1 ,
wherein the crystalline aluminosilicate contained in the cracking and reforming catalyst includes a medium-pore zeolite and/or a large-pore zeolite as a main component.

7. The method according to claim 1 ,
wherein the cracking and reforming catalyst contains phosphorous.

Assignees

• Jx Nippon Oil & Energy Corp

Inventors

• Yanagawa Shinichiro
• Kobayashi Masahide
• YOSHIWARA Yukihiro
• Ida Ryoji

Classifications

• C10G2300/1055

  Diesel having a boiling range of about 230 - 330 °C · CPC title

• C10G2400/30

  Aromatics · CPC title

• C10G11/05 Primary

  Crystalline alumino-silicates, e.g. molecular sieves · CPC title

• Y02P20/132

  Cross-Sectional Technologies · mapped topic

• C10G35/095

  containing crystalline alumino-silicates, e.g. molecular sieves {(C10G35/065 takes precedence)} · CPC title