Method for revamping a conventional mineral oils refinery to a biorefinery

Patent metadata

Field	Value
Publication number	US-9845432-B2
Application number	US-201214425501-A
Country	US
Kind code	B2
Filing date	Sep 4, 2012
Priority date	Sep 3, 2012
Publication date	Dec 19, 2017
Grant date	Dec 19, 2017

Abstract

The invention relates to a method for revamping a conventional refinery of mineral oils into a biorefinery, characterized by a production scheme which allows the treatment of raw materials of a biological origin (vegetable oils, animal fats, exhausted cooking oils) for the production of biofuels, prevalently high-quality biodiesel. This method allows the re-use of existing plants, allowing, in particular, the revamping of a refinery containing a system comprising two hydrodesulfurization units, U 1 and U 2 , into a biorefinery containing a production unit of hydrocarbon fractions from mixtures of a biological origin containing fatty acid esters by means of their hydrodeoxygenation and isomerization, wherein each of the hydrodesulfurization units U 1 and U 2 comprises: a hydrodesulfurization reactor, (A 1 ) for the unit U 1 and (A 2 ) for the unit U 2 , wherein said reactor contains a hydrodesulfurization catalyst; one or more heat exchangers between the feedstock and effluent of the reactor; a heating system of the feedstock upstream of the reactor; an acid gas treatment unit downstream of the reactor, containing an absorbent (B) for H2S, said unit being called T 1 in the unit U 1 and T 2 in the unit U 2 , and wherein said method comprises: installing a line L between the units U 1 and U 2 which connects them in series; installing a recycling line of the product for the unit U 1 and possibly for the unit U 2 , substituting the hydrodesulfurization catalyst in the reactor A 1 with a hydrodeoxygenation catalyst; substituting the hydrodesulfurization catalyst in the reactor A 2 with an isomerization catalyst; installing a y-pass line X of the acid gas treatment unit T 2 of the unit U 2 ; substituting the absorbent (B) in the acid gas treatment unit T 1 with a specific absorbent for C02 and H2S. The operative configuration obtained with the method, object of the present invention, also leads to a substantial reduction in emissions of pollutants into the atmosphere, with respect to the original operative mode. The invention also relates to the transformation unit of mixtures of a biological origin obtained with said conversion method and particularly hydrodeoxygenation and isomerization processes.

First claim

The invention claimed is:

1. A method for revamping a refinery comprising a system comprising two hydrodesulfurization units, (U 1 ) and (U 2 ), into a biorefinery comprising a production unit of hydrocarbon fractions from mixtures of a biological origin comprising fatty acid esters by means of their hydrodeoxygenation and isomerization,
wherein each of the hydrodesulfurization units (U 1 ) and (U 2 ) comprises:
a hydrodesulfurization reactor, (A 1 ) for the unit (U 1 ) and (A 2 ) for the unit (U 2 ), wherein the reactor comprises a hydrodesulfurization catalyst;
a heat exchanger between a feedstock and effluent of the reactor;
a heating system of the feedstock upstream of the reactor;
an acid gas treatment unit downstream of the reactor, comprising an absorbent (B) for H 2 S, (T 1 ) in the unit (U 1 ) and (T 2 ) in the unit a (U 2 ),

the method comprising:
installing a line L between the units (U 1 ) and (U 2 ) which connects them in series;
installing a recycling line of the product for the unit (U 1 ) and optionally for the unit (U 2 ),
substituting the hydrodesulfurization catalyst in the reactor (A 1 ) with a hydrodeoxygenation catalyst;
substituting the hydrodesulfurization catalyst in the reactor (A 2 ) with an isomerization catalyst;
installing a by-pass line (X) of the acid gas treatment unit (T 2 ) of the unit (U 2 ); and
substituting the absorbent (B) in the acid gas treatment unit (T 1 ) with a specific absorbent for CO 2 and H 2 S.

2. The method according to claim 1 , wherein the biorefinery comprises a HDO/ISO unit, and
wherein the method further comprises:
installing an acid gas treatment unit (T 3 ) downstream of the acid gas treatment unit (T 1 ) to separate the H 2 S; and
recycling the H 2 S to the reactor (A 1 ).

3. The method according to claim 1 , wherein units (U 1 ) and (U 2 ) are employed, comprising hydrogen recycling lines which connect the acid gas treatment units (T 1 ) and (T 2 ) with the reactors (A 1 ) and (A 2 ).

4. The method according to claim 1 , wherein each of the hydrodesulfurization units (U 1 ) and (U 2 ) further comprises: a hydrogen recycling line and a compressor on the line, (K 1 ) for the unit (U 1 ) and (K 2 ) for the unit (U 2 ), and wherein the method comprises:
installing an acid gas treatment unit (T 3 ) downstream of the acid gas treatment unit (T 1 ); and
installing a recycling line (R 3 ) of H 2 S from the unit (T 3 ) to the compressor (K 1 ) of the hydrogen recycling line of the unit (U 1 ).

5. The method according to claim 4 , wherein the acid gas treatment unit (T 3 ) comprises two absorbing areas each comprising a specific absorbent for CO 2 .

6. The method according to claim 1 , comprising:
connecting the unit (U 1 ) to a sulfur recovery unit comprising a thermal section and a catalytic section by the installation, from the unit (T 1 ) of (U 1 ), of a by-pass line of the thermal section of the sulfur recovery unit; and
substituting the catalyst of the first reactor of the catalytic section of the sulfur recovery unit with a cold selective redox catalyst.

7. The method according to claim 1 , wherein a surge drum (S) is installed upstream of each of the reactors (A 1 ) and (A 2 ).

8. The method according to claim 1 , wherein units (U 1 ) and (U 2 ) comprising high-pressure separators, low-pressure separators, stripping columns and optionally driers, are employed.

9. The method according to claim 1 , wherein units (U 1 ) and (U 2 ) are employed, comprising lines for feeding make-up hydrogen, optionally after mixing with recycled hydrogen, to each of the reactors (A 1 ) and (A 2 ) and/or comprising gas separation/washing downstream of each of the reactors (A 1 ) and (A 2 ).

10. The method according to claim 9 , wherein the hydrogen feeding lines come from reforming units.

11. The method according to claim 1 , wherein the hydrocarbon fractions are obtained from the biorefinery are fuels or fuel components.

12. The method according to claim 11 , wherein the fuels or fuel components that are obtained from the biorefinery are LPG, kerosene, diesel, or naphtha.

Assignees

• Rispoli Giacomo Fernando
• Prati Claudia
• Amoroso Andrea
• Pollesel Paolo
• Eni Spa

Inventors

• Rispoli Giacomo Fernando
• Prati Claudia
• Amoroso Andrea
• Pollesel Paolo

Classifications

• Y02P30/20

  using bio-feedstock · CPC title

• C10G65/043

  at least one step being a change in the structural skeleton · CPC title

• Y10T29/49346

  Rocket or jet device making · CPC title

• C10G2300/4056

  Retrofitting operations · CPC title

• C10G3/52

  Hydrogen in a special composition or from a special source · CPC title