Process for preparing polysiloxane-polycarbonate block cocondensates

Patent metadata

Field	Value
Publication number	US-9845378-B2
Application number	US-201415027743-A
Country	US
Kind code	B2
Filing date	Oct 6, 2014
Priority date	Oct 8, 2013
Publication date	Dec 19, 2017
Grant date	Dec 19, 2017

Abstract

The present invention relates to a process for preparing polysiloxane-polycarbonate block cocondensates proceeding from specific polycarbonates and hydroxyaryl-terminated polysiloxanes.

First claim

The invention claimed is:

1. A process for preparing polysiloxane-polycarbonate block cocondensates, comprising reacting at least one hydroxyaryl-terminated siloxane of the formula (1)

in which
R 1 is H, Cl, Br or C 1 to C 4 -alkyl,
R 2 and R 3 are the same or different and each independently from one another selected from aryl, C 1 to C 10 -alkyl and C 1 to C 10 -alkylaryl,
X is a single bond, —CO—, —O—, C 1 to C 6 -alkylene, C 2 to C 5 -alkylidene, C 5 to C 12 -cycloalkylidene or C 6 to C 12 -arylene which may optionally be fused to further aromatic rings containing heteroatoms,
n is a number from 10 to 100,
m is a number from 2 to 5, and
p is 0 or 1;

with at least one polycarbonate in the melt at temperatures of 280° C. to 400° C. and pressures of 0.001 mbar to 50 mbar;
wherein the polycarbonate has at least one of the following structures (I) to (IV):

wherein
the phenyl rings are unsubstituted or independently mono- or disubstituted by C 1 to C 8 -alkyl and/or halogen,
X is a single bond, C 1 to C 6 -alkylene, C 2 to C 5 -alkylidene or C 5 to C 6 -cycloalkylidene, and
the linkages indicated by --- in the structural units (I) to (IV) are each part of a carboxylate group;

wherein the amount of the structural units (I) to (IV) totals 50 to 2000 ppm (determined after hydrolysis, based on the polycarbonate), and wherein the polycarbonate has a weight-average molecular weight of 16 000 to 28 000 g/mol.

2. The process according to claim 1 , wherein the amount of the structural units (I) to (IV) totals 80 to 850 ppm (based on the polycarbonate and determined after hydrolysis).

3. The process according to claim 1 , wherein the polycarbonate has phenolic OH groups in an amount of 250 ppm to 1000 ppm.

4. The process according to claim 1 , wherein the hydroxyaryl-terminated siloxane has a weight-average molecular weight of 3000-20 000 g/mol.

5. The process according to claim 1 , wherein the hydroxyaryl-terminated siloxane is used in an amount of 2 to 20% by weight, based on the polycarbonate used.

6. The process according to claim 1 , wherein R 1 is H, p is 1 and X is isopropylidene.

7. The process according to claim 1 , wherein R 2 and R 3 are methyl.

8. The process according to claim 1 , wherein a phosphonium catalyst of the formula of the formula (5) is used during the reaction:

where
R a , R b , R c and R d may be identical or different C 1 -C 10 -alkyls, C 6 -C 14 -aryls, C 7 -C 15 -arylalkyls or C 5 -C 6 -cycloalkyls, and
Y— may be an anion selected from the group consisting of hydroxide, sulphate, hydrogensulphate, hydrogencarbonate, carbonate, halide or an alkoxide or aroxide of the formula —OR e where R e is C 6 -C 14 -aryl, C 7 -C 15 -arylalkyl or C 5 -C 6 -cycloalkyl.

9. The process according to claim 1 , wherein the siloxane and the polycarbonate are reacted in the presence of at least one organic or inorganic salt of an acid having a pK A value within the range of from 3 to 7 (25° C.).

10. The process according to claim 9 , wherein the organic or inorganic salt is selected from the group consisting of alkali metal salts, earth alkaline metal salts, quaternary ammonium salts and quaternary phosphonium salts.

11. The process according to claim 9 , wherein the one or more organic or inorganic salts are used in amounts of 0.5 to 1000 ppm, based on the total weight of the siloxane and the organic and/or inorganic salt(s).

12. The process according to claim 1 , wherein the process is performed at pressures of 0.02 to 30 mbar.

Assignees

• Covestro Deutschland Ag

Inventors

• Meyer Alexander
• Horn Klaus
• Pfingst Thomas
• Wetzel Sebastian

Classifications

• C08G77/448

  containing polycarbonate sequences · CPC title

• C08G77/16

  to hydroxy groups · CPC title

• C08G64/186 Primary

  containing polysiloxane sequences · CPC title

• C08G64/04

  Aromatic polycarbonates · CPC title

• C08K5/50

  Phosphorus bound to carbon only · CPC title