High clarity low haze compositions

Patent metadata

Field	Value
Publication number	US-9845368-B2
Application number	US-201615047078-A
Country	US
Kind code	B2
Filing date	Feb 18, 2016
Priority date	May 22, 2014
Publication date	Dec 19, 2017
Grant date	Dec 19, 2017

Abstract

A first embodiment which is a bimodal polymer having a weight fraction of a lower molecular weight (LMW) component ranging from about 0.25 to about 0.45, a weight fraction of a higher molecular weight (HMW) component ranging from about 0.55 to about 0.75 and a density of from about 0.931 g/cc to about 0.955 g/cc which when tested in accordance with ASTM D1003 using a 1 mil test specimen displays a haze characterized by equation: % Haze=2145−2216*Fraction LMW −181*a molecular weight distribution of the LMW component (MWD LMW )−932*a molecular weight distribution of the HMW component (MWD HMW )+27*(Fraction LMW *MWD LMW )+1019*(Fraction LMW *MWD HMW )+73*(MWD LMW *MWD HMW ) wherein fraction refers to the weight fraction of the component in the polymer as a whole.

First claim

What is claimed is:

1. A polymerization system comprising:
one or more polymerization reactors; and
a bimodal polymer having a weight fraction of a lower molecular weight (LMW) component ranging from about 0.25 to about 0.45, a weight fraction of a higher molecular weight (HMW) component ranging from about 0.55 to about 0.75 and a density of from about 0.931 g/cc to about 0.955 g/cc which when tested in accordance with ASTM D1003 using a 1 mil test specimen displays a haze characterized by equation: % Haze=2145−2216*Fraction LMW −181*a molecular weight distribution of the LMW component (MWD LMW )−932*a molecular weight distribution of the HMW component(MWD HMW )+27*(Fraction LMW *MWD LMW )+1019*(Fraction LMW *MWD HMW )+73*(MWD LMW *MWD HMW ) wherein fraction refers to the weight fraction of the component in the polymer as a whole,
wherein the one or more polymerization reactors are configured to contact monomer with a polymerization catalyst in the presence of hydrogen at conditions sufficient to yield the bimodal polymer.

2. The polymerization system of claim 1 , wherein the bimodal polymer when tested in accordance with ASTM D1746 displays a clarity characterized by equation: % Clarity=1934*Fraction LMW +139*(MWD LMW )+709*(MWD HMW )−60*(Fraction LMW *MWD LMW )−819*(Fraction LMW *MWD HMW )−47*(MWD LMW *MWD HMW )−1632.

3. The polymerization system of claim 1 , wherein the one or more polymerization reactors is selected from batch, slurry, gas-phase, solution, high pressure, tubular, autoclave, or combinations thereof.

4. The polymerization system of claim 1 , wherein the one or more polymerization reactors comprises multiple loop reactors, multiple gas phase reactors, a combination of one or more loop reactors and one or more gas phase reactors, multiple high pressure reactors, or a high pressure reactor in combination with a loop reactor and/or a gas phase reactor.

5. The polymerization system of claim 1 , wherein the monomer is ethylene, and wherein the bimodal polymer is a polyethylene polymer.

6. The polymerization system of claim 1 , wherein the polymerization catalyst comprises a dual metallocene catalyst system.

7. The polymerization system of claim 6 , wherein the dual metallocene catalyst system comprises a tightly bridged metallocene compound having a substituent that includes a terminal olefin and an unbridged metallocene compound.

8. The polymerization system of claim 6 , wherein the polymerization catalyst further comprises an activator.

9. The polymerization system of claim 8 , wherein the activator comprises an organoaluminum compound.

10. A polymerization system comprising:
a catalyst composition; and
a bimodal polymer having a weight fraction of a lower molecular weight (LMW) component ranging from about 0.25 to about 0.45, a weight fraction of a higher molecular weight (HMW) component ranging from about 0.55 to about 0.75 and a density of from about 0.931 g/cc to about 0.955 g/cc which when tested in accordance with ASTM D1003 using a 1 mil test specimen displays a haze characterized by equation: % Haze=2145−2216*Fraction LMW −181*a molecular weight distribution of the LMW component (MWD LMW )−932*a molecular weight distribution of the HMW component(MWD HMW)+ 27*(Fraction LMW *MWD LMW )+1019*(Fraction LMW *MWD HMW )+73*(MWD LMW *MWD HMW ) wherein fraction refers to the weight fraction of the component in the polymer as a whole,
wherein the catalyst composition cantacts monomer in the presence of hydrogen in one or more polymerization reactors at polymerization conditions sufficient to yied the bimodal polymer.

11. The polymerization system of claim 10 , wherein the bimodal polymer when tested in accordance with ASTM D1746 displays a clarity characterized by equation: % Clarity=1934*Fraction LMW +139*(MWD LMD )+709*(MWD HMW )−60*(Fraction LMW *MWD HMW )−819*(Fraction LMW *MWD HMW )−47*(MWD LMW *MWD HMW )−1632.

12. The polymerization system of claim 10 , wherein the catalyst composition comprises a dual metallocene catalyst system.

13. The polymerization system of claim 12 , wherein the dual metallocene catalyst system comprises a tightly bridged metallocene compound having a substituent that includes a terminal olefin and an unbridged metallocene compound.

14. The polymerization system of claim 12 , further comprising an activator.

15. The polymerization system of claim 14 , wherein the activator comprises an organoaluminum compound.

16. A polymerization system comprising:
a first catalyst composition which contacts monomer in the presence of hydrogen in a first polymerization reactor at polymerization conditions sufficient to yield a first polymer product; and
a second catalyst composition which contacts monomer in the presence of hydrogen in a second polymerization reactor at polymerization condition sufficient to yield a second polymer product: and
a bimodal polymer comprising the first polymer product and the second polymer product, wherein the bimodal polymer has a weight fraction of a lower molecular weight (LMW) component ranging from about 0.25 to about 0.45, a weight fraction of a higher molecular weight (HMW) component ranging from about 0.55 to about 0.75 and a density of from about 0.931 g/cc to about 0.955 g/cc which when tested in accordance with ASTM D1003 using a 1 mil test specimen displays a haze characterized by equation: % Haze=2145−2216*Fraction LMW −181*a molecular weight distribution of the LMW component (MWD LMW )−932*a molecular weight distribution of the HMW component(MWD HMW )+27*(Fraction LMW *MWD LMW )+1019*(Fraction LMW *MWD HMW )+73*(MWD LMW *MWD HMW ) wherein fraction refers to the weight fraction of the component in the polymer as a whole.

17. The polymerization system of claim 16 , wherein the bimodal polymer when tested in accordance with ASTM D1746 displays a clarity characterized by equation: % Clarity=1934*Fraction LMW +139*(MWD LMW )+709*(MWD HMWw )−60*(Fraction LMW *MWD LMW )−819*(Fraction LMW *MWD HMW )−47*(MWD LMW *MWD HMW )−1632.

18. The polymerization system of claim 16 , wherein the first catalyst composition comprises a tightly bridged metallocene compound having a substituent that includes a terminal olefin, wherein the second catalyst composition comprises an unbridged metallocene compound.

19. The polymerization system of claim 16 , wherein the monomer is ethylene, and wherein the bimodal polymer is a polyethylene polymer.

Assignees

• Chevron Phillips Chemical Co Lp

Inventors

• St Jean Guylaine
• Lanier Elizabeth M
• Lanier J Todd
• Yang Qing
• Gill Brooke A

Classifications

• B01J19/2415

  Tubular reactors · CPC title

• C08F4/65912

  in combination with an organoaluminium compound · CPC title

• Y10T428/139

  Open-ended, self-supporting conduit, cylinder, or tube-type article · CPC title

• C08F4/65916

  supported on a carrier, e.g. silica, MgCl2, polymer · CPC title

• C08F4/65925

  two cyclopentadienyl rings being mutually non-bridged · CPC title