Method of recovering acetone and a plant for recovering the same

Patent metadata

Field	Value
Publication number	US-9845277-B2
Application number	US-201715421793-A
Country	US
Kind code	B2
Filing date	Feb 1, 2017
Priority date	Feb 23, 2016
Publication date	Dec 19, 2017
Grant date	Dec 19, 2017

Abstract

In an embodiment, a method of recovering acetone comprises separating a bisphenol A stream into a bisphenol A product stream and an extraction stream comprising unreacted acetone; recovering the unreacted acetone in a recovery section of the bisphenol A production facility and forming a bisphenol A plant acetone recovery stream comprising methanol and a recovered acetone; introducing the bisphenol A plant acetone recovery stream to a phenol purification plant; and purifying the bisphenol A plant acetone recovery stream in the phenol purification plant to form an acetone product stream. The acetone product stream can comprise a reduced amount of methanol as compared to the bisphenol A plant acetone recovery stream.

First claim

We claim:

1. A method of recovering acetone comprising:
reacting phenol and acetone in the presence of a catalyst in a bisphenol A reactor to produce a bisphenol A stream comprising bisphenol A;
separating the bisphenol A stream into a product bisphenol A stream and an extraction streamcomprising an unreacted acetone;
separating the extraction stream into an extraction top outlet stream and an extraction bottom outlet stream in an acetone extraction column;
separating the extraction bottom outlet stream in an acetone stripper column in the presence of steam to form a stripper top outlet stream and a stripper bottom outlet stream comprising water;
separating the extraction top outlet stream in a solvent recovery column to form a recovery top outlet stream and a recovery bottom outlet stream;
separating one or both of the recovery top outlet stream and the stripper top outlet stream in a decanter to form an organic decanter stream and an aqueous decanter stream;
forming a bisphenol A plant acetone recovery stream comprising at least a portion of one or more of the extraction top outlet stream, the stripper top outlet stream, the aqueous decanter stream, and the recovery top outlet stream;
introducing the bisphenol A plant acetone recovery stream to a phenol purification plant, wherein the bisphenol A plant acetone recovery stream comprises methanol and a recovered acetone; and
purifying the bisphenol A plant acetone recovery stream to form an acetone product stream.

2. The method of claim 1 , wherein the methanol is present in the bisphenol A plant acetone recovery stream in an amount of 0.4 to 2 wt % based on the total weight of the bisphenol A plant acetone recovery stream.

3. The method of claim 1 , wherein the acetone product stream comprises less than or equal to 0.3 wt % of methanol.

4. The method of claim 1 , wherein the acetone product stream comprises or less than or equal to 150 ppm of methanol based on the total weight of the acetone product stream.

5. The method of claim 3 , wherein the acetone product stream comprises greater than or equal to 10 ppm of methanol based on the total weight of the acetone product stream.

6. The method of claim 1 , wherein the bisphenol A plant acetone recovery stream comprises at least a portion of one or more of the aqueous decanter stream, the extraction top outlet stream, and the recovery top outlet stream.

7. The method of claim 1 , wherein the introducing the bisphenol A plant acetone recovery stream to the phenol purification plant comprises introducing the bisphenol A plant acetone recovery stream to at least one of a preheater, a splitter column, and a first acetone column; and
wherein the purifying comprises
heating a preheater inlet stream comprising cumene, phenol, and acetone in the preheater to form the splitter inlet stream;
separating a splitter inlet stream comprising the cumene, the phenol, and the acetone into a splitter top outlet stream comprising the acetone and the cumene and a splitter bottom outlet stream comprising the phenol in the splitter column;
separating the splitter top outlet stream in the first acetone column into a first top stream and a first bottom stream; and
separating the first bottom stream in a second acetone column into a second bottom stream and the acetone product stream.

8. The method of claim 7 , wherein the introducing the bisphenol A plant acetone recovery stream comprises introducing the bisphenol A plant acetone recovery stream to the preheater inlet stream.

9. The method of claim 7 , wherein the introducing the bisphenol A plant acetone recovery stream comprises introducing the bisphenol A plant acetone recovery stream to the splitter inlet stream.

10. The method of claim 7 , wherein the introducing the bisphenol A plant acetone recovery stream comprises introducing the bisphenol A plant acetone recovery stream to the splitter top outlet stream.

11. The method of claim 1 , further comprising introducing the acetone product stream to the bisphenol A reactor.

12. A method of purifying a recovered acetone comprising:
introducing a bisphenol A plant acetone recovery stream, preferably, the bisphenol A plant acetone recovery stream of any one of the preceding claims, to at least one of a preheater, a splitter column, and a first acetone column of a phenol purification plant; wherein the bisphenol A plant acetone recovery stream comprises methanol and the recovered acetone;
heating a preheater inlet stream comprising cumene, phenol, and acetone in the preheater to form a splitter inlet stream;
separating the splitter inlet stream comprising the cumene, the phenol, and the acetone into a splitter top outlet stream comprising the acetone and the cumene and a splitter bottom outlet stream comprising the phenol in the splitter column;
separating the splitter top outlet stream in the first acetone column into a first top stream and a first bottom stream;
separating the first bottom stream in a second acetone column into a second bottom stream and an acetone product stream comprising a purified acetone.

13. An integrated system for purifying acetone, comprising:
an acetone extraction column comprising a first extraction inlet, a top extraction outlet, and a bottom extraction outlet;
an acetone stripper column comprising comprise a stripper inlet, a steam stripper inlet, a top stripper outlet, and a bottom stripper outlet; wherein the bottom extraction outlet is in fluid communication with the stripper inlet;
a decanter comprising a decanter inlet, an aqueous decanter outlet, and an organic decanter outlet; wherein one or both of the top solvent recovery outlet and the top stripper outlet is in fluid communication with the decanter inlet; and
an optional solvent recovery column comprising a first solvent recovery inlet, a second solvent recovery inlet, a top solvent recovery outlet, and a bottom recovery outlet; wherein, if present, the top extraction outlet is in fluid communication with the first solvent recovery inlet; the organic decanter outlet is in fluid communication with one or both of the second solvent recovery inlet and a second extraction inlet of the acetone extraction column; and
wherein the top extraction outlet, the top stripper outlet, the aqueous decanter outlet, top solvent recovery outlet, or a combination comprising at least one of the foregoing is in fluid communication with a stream of a phenol purification system; wherein the phenol purification system is configured to recover an acetone product stream.

14. The integrated system of claim 13 , wherein the top stripper outlet, the aqueous decanter outlet, top solvent recovery outlet, or a combination comprising at least one of the foregoing is in fluid communication with the phenol purification system.

15. The integrated system of claim 13 , wherein the phenol purification system comprises
a preheater comprising a preheater inlet and a preheater outlet; and
a splitter column comprising a splitter inlet in fluid communication with the preheater outlet, a splitter top outlet, and a splitter bottom outlet;
a first acetone column comprising a first acetone inlet, a first acetone top outlet, and a first acetone bottom outlet; wherein the splitter top outlet is in fluid communication with the first acetone inlet; and
a second acetone column comprising a second acetone inlet, a second acetone top outlet, and a second acetone bottom outlet; wherein the first acetone bottom outlet is in fluid communication with the second acetone inlet; and
wherein the top extraction outlet, the top stripper outlet, the aqueous decanter outlet, top solvent recov

Assignees

• Sabic Global Technologies Bv

Inventors

• Nelson Mark Erik
• Youssef Ahmed Abouelfetouh

Classifications

• C07C45/82

  by distillation · CPC title

• C07C37/20

  using aldehydes or ketones · CPC title

• B01J2219/24

  Stationary reactors without moving elements inside · CPC title

• C07C45/80 Primary

  by liquid-liquid treatment · CPC title

• B01J19/24

  Stationary reactors without moving elements inside (B01J19/08, B01J19/26 take precedence; with stationary particles B01J8/02) · CPC title