Water desalination/purification and bio-agent preconcentration by ion concentration polarization

Patent metadata

Field	Value
Publication number	US-9845252-B2
Application number	US-201414306607-A
Country	US
Kind code	B2
Filing date	Jun 17, 2014
Priority date	Jun 19, 2013
Publication date	Dec 19, 2017
Grant date	Dec 19, 2017

Abstract

Between two juxtaposed similar ion exchange membranes (AEMs or CEMs), an ion depletion zone (d de ) and ion enrichment zone (d en ) are generated under an electric field. As cations are selectively transferred through the CEMs, for example, anions are relocated in order to achieve electro-neutrality, resulting in the concentration drop (increase) in ion depletion (enrichment) zone. The concentration drop (i.e. salt removal) is low and spatially gradual at relatively low voltage or current (i.e. Ohmic regime). However, at higher voltage or current (i.e. overlimiting regime), strong electroconvective vortex accelerates cation transport through CEMs, allowing us to “relocate” most salt ions. The flat depletion zone occurs with significantly low ion concentration, and corresponding strong electric field in the zone, and any charged agents (e.g. proteins and bacteria) cannot penetrate this flat zone. As a result, we can separate and collect the desalted/purified flow from brine flow by bifurcating the channel at the end of the CEMs. This ICP desalination/purification also happens with two anion exchange membranes (AEMs) by relocating cations, but the location of desalted/brine flows are converted.

First claim

What is claimed is:

1. A method of purifying and/or concentrating a first water stream containing ionic impurities comprising:
a. directing the water stream in a channel comprising an inlet and an outlet and defined, at least in part by two juxtaposed ion exchange membranes, wherein the ion exchange membranes are characterized by the same charge, and a nonionic porous membrane;
b. applying an electric field across the water stream channel;
whereby, an ion depletion zone (d de ) comprising a purified water stream and an ion enrichment zone (d en ) comprising a concentrated ion aqueous stream are generated and ions are transferred through the ion exchange membrane, and wherein the nonionic porous membrane separates or bifurcates the ion depletion zone and the ion enrichment zone; and

c. collecting the purified water stream and/or the concentrated ion aqueous stream.

2. The method of claim 1 wherein the channel formed by the two juxtaposed ion exchange membranes does not contain a membrane carrying a charge counter to the two juxtaposed ion exchange membranes.

3. The method of claim 1 wherein the two juxtaposed ion exchange membranes are cationic exchange membranes.

4. The method of claim 1 wherein the two juxtaposed ion exchange membranes are anionic exchange membranes.

5. The method of claim 1 wherein the nonionic porous membrane is located at the outlet of the channel.

6. The method of claim 1 wherein the first water stream comprises salt.

7. The method of claim 1 wherein the first water stream comprises biomolecules.

8. A method of purifying and/or concentrating a first water stream containing ionic impurities comprising:
a. directing the water stream in a channel comprising an inlet and an outlet and defined, at least in part by two juxtaposed ion exchange membranes, wherein the ion exchange membranes are characterized by the same charge,
b. applying an electric field across the water stream channel;

whereby, an ion depletion zone (d de ) comprising a purified water stream and an ion enrichment zone (d en ) comprising a concentrated ion aqueous stream are generated and ions are transferred through the ion exchange membranes;
wherein the electric field creates a boundary layer comprising at least one electroconvective vortex proximal to at least one of the two juxtaposed ion exchange membranes; and
collecting the purified water stream and/or the concentrated ion aqueous stream.

9. A method of purifying and/or concentrating a first water stream containing ionic impurities comprising:
a. directing the water stream in a channel comprising an inlet and an outlet and defined, at least in part by two juxtaposed ion exchange membranes, wherein the ion exchange membranes are characterized by the same charge,
b. applying an electric field across the water stream channel;
whereby, an ion depletion zone (d de ) comprising a purified water stream and an ion enrichment zone (d en ) comprising a concentrated ion aqueous stream are generated and ions are transferred through the ion exchange membranes and wherein the electric field is created by an electrode and a ground each located external and parallel to the channel; and

c. collecting the purified water stream and/or the concentrated ion aqueous stream.

10. The method of claim 9 wherein the electrode forms a second channel with the first of said two juxtaposed ion exchange membranes and the ground forms a third channel with the second of said two juxtaposed ion exchange membranes.

11. The method of claim 10 wherein the second and third channel are filled with an electrolyte solution.

12. The method of claim 11 wherein the electrolyte solution is the first water stream.

13. The method of claim 11 wherein a voltage or current in the overlimiting regime is applied.

14. The method of claim 9 , wherein the channel formed by the two juxtaposed ion exchange membranes does not contain a membrane carrying a charge counter to the two juxtaposed ion exchange membranes.

15. The method of claim 9 , wherein the two juxtaposed ion exchange membranes are cationic exchange membranes.

16. The method of claim 9 , wherein the two juxtaposed ion exchange membranes are anionic exchange membranes.

17. The method of claim 9 , further comprising a nonionic porous membrane separating or bifurcating the ion depletion zone and the ion enrichment zone.

18. The method of claim 17 , wherein the nonionic porous membrane is located at the outlet of the channel.

19. The method of claim 9 , wherein the electric field creates a boundary layer comprising at least one electroconvective vortex proximal to at least one of the two juxtaposed ion exchange membranes.

Assignees

• Massachusetts Inst Technology

Inventors

• Kwak Rhokyun
• Han Jongyoon

Classifications

• B01D61/42

  Electrodialysis; Electro-osmosis {; Electro-ultrafiltration; Membrane capacitive deionization} · CPC title

• C02F2201/46115

  Electrolytic cell with membranes or diaphragms · CPC title

• C02F2103/08

  Seawater, e.g. for desalination · CPC title

• C02F1/469 Primary

  by electrochemical separation, e.g. by electro-osmosis, electrodialysis, electrophoresis · CPC title