Coextrusion paper coating method forming multilayer comprising biodegradable polyester and polylactic acid

Patent metadata

Field	Value
Publication number	US-9844797-B2
Application number	US-201514864240-A
Country	US
Kind code	B2
Filing date	Sep 24, 2015
Priority date	Sep 29, 2008
Publication date	Dec 19, 2017
Grant date	Dec 19, 2017

Abstract

The present invention relates to a process for coating paper, wherein the coating material used is a biodegradable, aliphatic-aromatic polyester having a melt volume rate (MVR) according to EN ISO 1133 (190° C., 2.16 kg weight) of from 3 to 50 cm 3 /10 min.

First claim

We claim:

1. A process comprising:
applying by coextrusion a coating material to paper to form a coated paper, said coating material comprising;
20 to 90% by weight of a biodegradable, aliphatic-aromatic polyester, and
80 to 10% by weight of polylactic acid,

wherein the biodegradable, aliphatic-aromatic polyester comprises:
i) from 40 to 70 mol %, based on the total of components i to ii, of a adipic acid derivative or adipic acid;
ii) from 60 to 30 mol %, based on the total of components i to ii, of a terephthalic acid derivative;
iii) from 98 to 102 mol %, based on the total of components i to ii, of a C 2 -C 8 -alkylenediol or C 2 -C 6 -oxyalkylenediol; and
iv) from 0.01 to 2% by weight, based on the total weight of components i to iii, of a chain extender and/or crosslinking agent selected from the group consisting of: a di-functional isocyanate, polyfunctional isocyanate, isocyanurate, oxazoline, epoxide, carboxylic anhydride, an at least trifunctional alcohol, and an at least trifunctional carboxylic acid;
the coating material having a melt volume rate (MVR) according to EN ISO 1133(190° C., 2.16 kg weight) of from 10 to 30 cm 3 /10 min, and the applying the coating material to paper by coextrusion includes an average grammage of 15 to 35 g/m 2 wherein the coating material includes more than 50% by weight of the polylactic acid, which forms a continuous phase in the polymer mixture and
the coating material is applied as a multilayer coating that comprises:
i) an outer layer comprising the coating material with from 40 to 60% by weight of the aliphatic-aromatic polyester and from 60 to 40% by weight of the polylactic
acid and from 0 to 10% by weight of a wax formulation comprising wax, dispersant and antiblocking agents;
ii) a middle layer comprising from 50 to 100% by weight of the polylactic acid and from 0 to 50% by weight of the aliphatic-aromatic polyester; and
iii) an inner layer in contact with the paper, comprising from 50 to 100% of the aliphatic-aromatic polyester and from 0 to 50% of the polylactic acid.

2. The process according to claim 1 , wherein the adipic acid derivative, or adipic acid, is present from 52 to 65 mol %, and the terephthalic acid derivative is present from from 48 to 35 mol %, based on the total of components i to ii.

3. The process according to claim 1 , wherein the coating material further comprises up to 2% by weight of an epoxide-containing poly(meth)acrylate.

4. The process according to claim 1 , wherein the biodegradable, aliphatic-aromatic polyester further comprises:
v) from 0 to 50% by weight, based on the total weight of the components i to iv, of an organic filler selected from the group consisting of: native starch, plasticized starch, natural fiber, wood meal, and an inorganic filler, wherein said inorganic filler is selected from the group consisting of: chalk, precipitated calcium carbonate, graphite, gypsum, conductive carbon black, iron oxide, calcium chloride, dolomite, kaolin, silicon dioxide, sodium carbonate, titanium dioxide, silicate, wollastonite, mica, montmorillonite, talc, glass fibers and mineral fibers and
vi) from 0 to 2% by weight, based on the total weight of the components i to iv, of at least one stabilizer, nucleating agent, lubricant and release agent, surfactant, wax, antistatic agent, antifogging agent, dye, pigment, UV absorber, UV stabilizer or other plastics additive.

5. The process according to claim 1 , wherein component i) of the biodegradable, aliphatic-aromatic polyester is a mixture of adipic acid with other dicarboxyclic acids.

6. The process according to claim 1 , the polylactic acid having a melt volume rate (MVR) according to EN ISO 1133 (190° C., 2.16 kg weight) of from 9 to 70 cm 3 /10 min.

7. The process according to claim 4 , wherein the polymer mixture comprises from 0.1 to 1% by weight of nucleating agent(s).

8. The process of claim 1 wherein the applying the coating is used in the production of paper bags for dry foods, liquids, tube laminates, paper carrier bags, paper laminates and coextrudates, paper adhesive tape, cardboard cups, yoghurt pots, meal trays, wound cardboard containers, wet-strength cartons for outer packagings, fruit boxes of coated cardboard, fast food plates, clamp shells, beverage cartons, cartons for liquids, frozen food cartons, ice packaging, paper labels, flower pots and plant pots.

9. The process of claim 4 wherein the inorganic filler is quartz.

10. The process of claim 1 wherein the coating material comprises 70% to 50% by weight of the biodegradable, aliphatic-aromatic polyester, and 30% to 50% by weight of the polylactide.

Assignees

• Basf Se

Inventors

• Skupin Gabriel
• Loos Robert
• Füβl Andreas
• Nevalainien Kimmo

Classifications

• B05D2252/00

  Sheets · CPC title

• B05D2203/22

  Paper or cardboard · CPC title

• B05D2252/02

  of indefinite length · CPC title

• C08L2666/18

  Polyesters or polycarbonates according to C08L67/00 - C08L69/00; Derivatives thereof · CPC title

• D21H19/28

  Polyesters · CPC title