Fuel-cell stack comprising an anode chamber comprising in the anode chamber an area for condensing and removing water and method for condensing and removing water formed in said chamber

Patent metadata

Field	Value
Publication number	US-9843058-B2
Application number	US-201214000787-A
Country	US
Kind code	B2
Filing date	Feb 28, 2012
Priority date	Mar 2, 2011
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

The fuel cell includes an anode chamber having a hydrogen inlet emerging into it. A wall separating the inside of the anode chamber from the outside thereof includes a main region having a first thermal conduction resistance between the outside and the inside of the anode chamber, and a region for promoting the condensation of water having a second thermal conduction resistance between the outside and the inside of the anode chamber strictly smaller than the first thermal conduction resistance so as to delimit a water condensation surface within the anode chamber. A channel for removing the condensed water connects the condensation area to the outside of the anode chamber.

First claim

The invention claimed is:

1. A fuel cell comprising an anode chamber having a hydrogen inlet emerging into it,
wherein
the fuel cell comprises a plurality of elementary cells delimited by pairs of electrodes, respectively forming an anode and a cathode, each pair being separated by an electrolyte membrane, the anodes being all arranged in the anode chamber,
a wall having a first, inner face and a second, outer face opposite to the first, inner face, the wall separating an inside of the anode chamber from an outside of the anode chamber, the wall comprises:
a main region extending from the first inner face to the second outer face, the main region having a first thermal conduction resistance measured between the first, inner face and the second, outer face of the wall,
at least one region for promoting condensation of water extending from the first inner face to the second outer face, the least one region for promoting condensation of water having a second thermal conduction resistance measured between the first, inner face and the second, outer face of the wall strictly smaller than the first thermal conduction resistance so as to delimit a water condensation area within the anode chamber,
a drain off channel for removing condensed water from the anode chamber, the drain off channel passing through the wall and is in direct contact with at least one of said regions for promoting condensation of water, the drain off channel being distinct from the main region,
the fuel cell comprises a liquid water storage and evaporation element arranged outside of the anode chamber and fitted with the drain-off channel so as to absorb the water extracted from said anode chamber,
wherein the main region is configured to block transfer of water between the first inner face and the second outer face,
wherein the at least one region for promoting condensation of water is configured to block transfer of water between the first inner face and the second outer face,
wherein the storage and evaporation element is at least partially covering the second outer face of the at least one of said regions for promoting the condensation of water, and
wherein the storage and evaporation element comprises a porous material configured to store and evaporate water concurrently and continuously.

2. The fuel cell according to claim 1 , wherein at least two of the plurality of elementary cells comprise a common electrolyte membrane.

3. The fuel cell according to claim 1 , wherein the fuel cell comprises a plurality of individual electrolyte membranes each corresponding to an elementary cell.

4. The fuel cell according to claim 1 , wherein the at least one region for promoting the condensation of water is formed by a local thinning of the wall in the anode chamber.

5. The fuel cell according to claim 1 , wherein at least one of said at least one region for promoting the condensation of water comprises an insert filling a hole in the wall having the inside of the anode chamber communicate with the outside of the anode chamber.

6. The fuel cell according to claim 5 , wherein the insert is made of a material having a greater thermal conductivity than a material used to delimit the main region.

7. The fuel cell according to claim 1 , wherein the drain-off channel is connected to a valve controlling removal of the condensed water through said drain-off channel.

8. The fuel cell according to claim 7 , wherein at least one of said at least one region for promoting the condensation of water is fitted with a sensor configured to detect presence of water, the sensor being connected to the valve so as to start removal of water when the sensor detects water on at least one of said at least one region for promoting the condensation of water.

9. The fuel cell according to claim 1 , wherein the storage and evaporation element comprises a material configured to carry out a catalytic combustion of hydrogen.

10. The fuel cell according to claim 1 , wherein a hydrophilic, porous material is arranged in the anode chamber.

11. The fuel cell according to claim 1 , wherein said at least one region for promoting condensation of water comprises a plurality of distinct regions interconnected by microchannels, the drain-off channel connecting at least one of the plurality of distinct regions for promoting condensation of water.

12. The fuel cell according to claim 1 , wherein the porous material has a pore size ranging between 1 μm and 1 mm.

13. The fuel cell according to claim 1 , wherein the storage and evaporation element is in direct contact with at least one of said at least one region for promoting condensation of water.

14. The fuel cell according to claim 1 , wherein a hydrophilic material is disposed on the first, inner face of the wall.

15. The fuel cell according to claim 14 , wherein the hydrophilic material is disposed so as to cover at least one of said at least one region for promoting the condensation of water.

16. The fuel cell according to claim 1 , wherein the drain off channel is surrounded by at least one of said at least one region for promoting condensation of water.

17. The fuel cell according to claim 1 , wherein said main region and said at least one region for promoting condensation are formed in the same plane face of said wall.

18. The fuel cell according to claim 1 , wherein the anode chamber comprises a first face formed by the electrolyte membrane, remaining faces of the anode chamber are formed by a cover and wherein the hydrogen inlet is separated from the drain off channel by the anodes of the plurality of elementary cells.

19. The fuel cell according to claim 1 , wherein the second, outer face of the wall is a planar face.

20. The fuel cell according to claim 1 , wherein the storage and evaporation element is arranged to cool at least one of said at least one region for promoting condensation of water by said evaporation of water.

21. A method for condensing and removing water formed in an anode chamber of a fuel cell according to claim 1 , wherein said method comprises the steps of:
locally lowering a temperature of the water condensation area of the wall of the anode chamber inside of the anode chamber,
condensing water vapor obtained by back diffusion during operation of the fuel cell on the water condensation area,
removing the condensed water on the water condensation area through a drain-off channel connecting said water condensation area to the outside of the anode chamber.

22. The method according to claim 21 , wherein before the step of removing, a step of detecting presence of the condensed water on the water condensation area is carried out, the step of removing being only carried out if the condensed water is detected on the water condensation area.

Assignees

• Faucheux Vincent
• Latour Antoine
• Thery Jessica
• Valon Bruno
• Commissariat à l'Energie Atomique et aux Energies Alternatives

Inventors

• Faucheux Vincent
• Latour Antoine
• Thery Jessica
• Valon Bruno

Classifications

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M8/04164 Primary

  by condensers, gas-liquid separators or filters · CPC title

• H01M8/04171

  using adsorbents, wicks or hydrophilic material · CPC title

• H01M8/04291 Primary

  Arrangements for managing water in solid electrolyte fuel cell systems (H01M8/04119 takes precedence) · CPC title

• Y02E60/50

  Fuel cells · CPC title