Positive electrode

Patent metadata

Field	Value
Publication number	US-9843044-B2
Application number	US-201715455999-A
Country	US
Kind code	B2
Filing date	Mar 10, 2017
Priority date	Aug 25, 2009
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

According to one embodiment, a positive electrode includes a positive electrode layer and a positive electrode current collector. The positive electrode layer includes a positive electrode active material including a first oxide represented by the following formula (α) and/or a second oxide represented by the following formula (β). The positive electrode layer has an intensity ratio falling within a range of 0.25 to 0.7. The ratio is represented by the following formula (1) in an X-ray diffraction pattern obtained by using CuKα radiation for a surface of the positive electrode layer.

Li x Ni 1-a-b Co a Mn b M c O 2   (α)

Li x Ni 1-a-c Co a M c O 2   (β)

I 2 /I 1   (1)

First claim

What is claimed is:

1. A positive electrode comprising:
a positive electrode current collector: and
a positive electrode layer comprising a positive electrode active material, a conductive agent and a binder,
the positive electrode active material comprising LiCoO 2 and at least one of a first oxide represented by formula (α) and a second oxide represented by formula (β), the positive electrode layer having an intensity ratio falling within a range of 0.25 to 0.7, the ratio being represented by formula (1) in an X-ray diffraction pattern obtained by using CuKα radiation for a surface of the positive electrode layer:
Li x Ni 1-a-b Co a Mn b M c O 2   (α)

wherein 0.9<x≦1.25, 0<a≦0.4, 0<b≦0.45, 0<c≦0.1, and M is at least one element selected from the group consisting of Mg, Al, Si, Ti, Zn, Zr, Ca and Sn,
Li x Ni 1-a-c Co a M c O 2   (β)

wherein 0.9<x≦1.25, 0<a≦0.4, 0<c≦0.1, and M is at least one element selected from the group consisting of Mg, Si, Ti, Zn, Zr, Ca and Sn,
I 2 /I 1   (1)

wherein I 1 is an intensity of a main peak in 2θ falling within a range of 15° to 25° in the X-ray diffraction pattern, and I 2 is an intensity of a main peak in 2θ falling within a range of 40° to 50° in the X-ray diffraction pattern,
wherein a content of the at least one of the first oxide and the second oxide is from 60 wt % to 95 wt %, relative to the total weight of components present in the positive electrode layer, and
wherein the positive electrode active material further comprises at least one selected from the group consisting of manganese dioxide, iron oxide, copper oxide, nickel oxide, Li a MnO 2 , where 0<a≦1.2, lithium-cobalt composite oxide, lithium-manganese-cobalt composite oxide, lithium-manganese-nickel composite oxide, spinel-type lithium-manganese composite oxide, spinel-type lithium-manganese nickel composite oxide, lithium phosphorous oxide having an olivine structure, iron sulfate, vanadium oxide, polyaniline, polypyrrole, disulfide polymer materials, fluorocarbons and sulfur.

2. The positive electrode according to claim 1 , wherein formula (β) satisfies
0< a≦ 0.2, and
0< c≦ 0.05.

3. The positive electrode according to claim 1 , wherein the intensity ratio falls within a range of 0.3 to 0.55.

4. The positive electrode according to claim 3 , wherein formula (α) satisfies
0< a≦ 0.2,
0< b≦ 0.3, and
0< c≦ 0.01.

5. The positive electrode according to claim 3 , wherein formula (β) satisfies
0< a≦ 0.2, and
0< c≦ 0.05.

6. The positive electrode according to claim 1 , wherein the positive electrode active material is dispersed in the binder, and
wherein the binder is present in the positive electrode layer in an amount of at least 2 wt %, relative to the amounts for all materials present in the positive electrode layer.

7. The electrode according to claim 1 , wherein the positive electrode active material is dispersed in the binder,
wherein the binder is present in the positive electrode layer in an amount of at least 2 wt %, relative to the amounts for all materials present in the positive electrode layer, and
wherein the I 2 /I 1 ratio is an index of dispersibility of the positive electrode active material in the binder.

8. The electrode according to claim 1 , wherein formula (β) satisfies:
0.03≦ c≦ 0.1.

9. A nonaqueous electrolyte battery comprising:
the positive electrode according to claim 1 ;
a negative electrode; and
a nonaqueous electrolyte.

10. A battery pack comprising the nonaqueous electrolyte battery according to claim 9 .

11. The battery pack according to claim 10 , comprising nonaqueous electrolyte batteries each of which is the nonaqueous electrolyte battery, wherein the nonaqueous electrolyte batteries are electrically connected in series or parallel.

12. The battery pack according to claim 10 , further comprising:
a protective circuit; and
an external terminal.

13. A vehicle comprising the battery pack according to claim 10 .

14. A positive electrode comprising:
a positive electrode current collector; and
a positive electrode layer comprising a positive electrode active material, a conductive agent and a binder,
the positive electrode active material comprising at least one of a first oxide represented by formula (α) and a second oxide represented by formula (β), the positive electrode layer having an intensity ratio falling within a range of 0.25 to 0.7, the ratio being represented by formula (1) in an X-ray diffraction pattern obtained by using CuKα radiation for a surface of the positive electrode layer:
Li x Ni 1-a-b Co a Mn b M c O 2   (α)

wherein 0.9<x≦1.25, 0<a≦0.4, 0<b≦0.45, 0<c≦0.1, and M is at least one element selected from the group consisting of Mg, Al, Si, Ti, Zn, Zr, Ca and Sn,
Li x Ni 1-a-c Co a M c O 2   (β)

wherein 0.9<x≦1.25, 0<a≦0.4, 0<c≦0.1, and M is at least one element selected from the group consisting of Mg, Si, Ti, Zn, Zr, Ca and Sn,
I 2 /I 1   (1)

wherein I 1 is an intensity of a main peak in 2θ falling within a range of 15° to 25° in the X-ray diffraction pattern, and I 2 is an intensity of a main peak in 2θ falling within a range of 40° to 50° in the X-ray diffraction pattern,
wherein a portion of the active material, a portion of the conductive agent, and a portion of the binder are present on a surface of the positive electrode layer,
wherein a content of the at least one of the first oxide and the second oxide is from 60 wt % to 95 wt %, relative to the total weight of components present in the positive electrode layer, and
wherein the positive electrode active material further comprises at least one selected from the group consisting of manganese dioxide, iron oxide, copper oxide, nickel oxide, Li a MnO 2 , where 0<a≦1.2, lithium-cobalt composite oxide, lithium-manganese-cobalt composite oxide, lithium-manganese-nickel composite oxide, spinel-type lithium-manganese composite oxide, spinel-type lithium-manganese nickel composite oxide, lithium phosphorous oxide having an olivine structure, iron sulfate, vanadium oxide, polyaniline, polypyrrole, disulfide polymer materials, fluorocarbons and sulfur.

15. A nonaqueous electrolyte battery comprising:
the positive electrode according to claim 14 ;
a negative electrode; and
a nonaqueous electrolyte.

16. A battery pack comprising the nonaqueous electrolyte battery according to claim 15 .

17. The battery pack according to claim 16 , comprising nonaqueous electrolyte batteries each of which is the nonaqueous electrolyte battery, wherein the nonaqueous electrolyte batteries are electrically connected in series or parallel.

18. The battery pack according to claim 16 , further comprising:
a protective circuit; and
an external terminal.

19. A vehicle comprising the battery pack according to claim 16 .

Assignees

• Toshiba Kk

Inventors

• Saruwatari Hidesato
• Iwasaki Takuya
• Takazawa Koji
• Takami Norio

Classifications

• H01M4/505 Primary

  of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

• H01M4/525

  of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

• H01M2004/028

  Positive electrodes · CPC title

• H01M10/0569

  characterised by the solvents · CPC title

• H01M4/131

  Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx · CPC title