Component having a coating and method for the production thereof

Patent metadata

Field	Value
Publication number	US-9840766-B2
Application number	US-201314437943-A
Country	US
Kind code	B2
Filing date	Oct 23, 2013
Priority date	Oct 23, 2012
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

The invention relates to a component having a coating containing chromium, nitrogen and carbon. According to the invention the coating comprises a sliding layer having a ceramic phase and a carbon phase, the ceramic phase forms a crystalline ceramic phase from Crx(C 1-y N y ) with 0.8=x=1.2 and y>0.7, and the crystalline ceramic phase and the carbon phase form a layer system of alternating individual layers (A, B), wherein the carbon phase has interstices that are filled with the crystalline ceramic phase.

First claim

The invention claimed is:

1. A component ( 10 ) having a coating ( 13 ) containing chromium, nitrogen, and carbon, wherein the coating ( 13 ) has a lubricating layer ( 16 ) having a ceramic phase ( 17 ) and a carbon phase ( 18 ), wherein the ceramic phase ( 17 ) forms a crystalline ceramic phase composed of Cr x (C 1-y N y ) with 0.8≦x≦1.2 and y>0.7, wherein the crystalline ceramic phase ( 17 ) and the carbon phase ( 18 ) form a layer system composed of alternating individual layers (A, B), wherein the carbon phase ( 18 ) has gaps that are filled with the crystalline ceramic phase ( 17 ), wherein the lubricating layer ( 16 ) has a total carbon content of 12 to 20 atom-%, and wherein the crystalline ceramic phase does not have gaps that are filled with the carbon phase.

2. The component according to claim 1 , wherein it holds true for the crystalline ceramic matrix ( 17 ) composed of Cr x (C 1-y N y ): 0.9≦x≦1.1 and y>0.8.

3. The component according to claim 1 , wherein the crystalline ceramic phase ( 17 ) forms bridges between its individual layers (A).

4. The component according to claim 1 , wherein the crystalline ceramic phase ( 17 ) and the carbon phase ( 18 ) are present in the form of lamellae.

5. The component according to claim 4 , wherein the lamellae of the carbon phase ( 18 ) are disposed parallel to the surface ( 19 ) of the lubricating layer ( 16 ).

6. The component according to claim 1 , wherein the thickness of the lubricating layer ( 16 ) amounts to 1 to 50 μm.

7. The component according to claim 1 , wherein the thickness of each individual layer (A, B) amounts to between 1.0 nm and 4.0 nm.

8. The component according to claim 1 , wherein the Vickers hardness of the lubricating layer ( 16 ) amounts to 1000 HV to 2000 HV 0.05.

9. The component according to claim 1 , wherein the modulus of elasticity of the lubricating layer ( 16 ) amounts to 100 GPa to 200 GPa.

10. The component according to claim 1 , wherein the lubricating layer ( 16 ) has an average roughness depth Rz of less than 1 μm at its surface and/or that the material proportion Rmr(02) amounts to more than 50% and/or that the material proportion Rmr(03) amounts to more than 70%.

11. The component according to claim 1 , wherein an adhesion layer ( 14 ) composed of a metallic material is applied between a body ( 11 ) of the component and the lubricating layer ( 16 ).

12. The component according to claim 11 , wherein an intermediate layer ( 15 ) composed of a metal nitride material is applied between the adhesion layer ( 14 ) and the lubricating layer ( 16 ).

13. The component according to claim 1 for an internal combustion engine, wherein the component is a piston ring, a piston pin, a cam of a camshaft, a valve, a valve tappet or a rocker arm.

14. A method for coating a component ( 10 ) with the lubricating layer ( 16 ) of claim 1 , wherein at least one component ( 10 ) is mounted on a spindle ( 30 ) disposed on a turntable ( 28 ), so as to rotate, in a vacuum chamber ( 21 ), wherein for the production of the lubricating layer ( 16 ), a PVD method with arc vaporization, having the following parameters, is used:
Material sources: at least one metal target ( 24 ) and at least one carbon target ( 25 );
Ratio of the target streams of metal to carbon: 2 to 7; Deposition temperature at the component ( 10 ): 350° C. to 500° C.;
Bias voltage: −50 V to −150 V;
Pressure in the vacuum chamber: 0.2 Pa to 1.0 Pa;
Atmosphere in the vacuum chamber: nitrogen and inert gas having a ratio of the nitrogen partial pressure to the total pressure of 0.6 to 1.0;
Rotation of the turntable ( 28 ): 20 to 40 revolutions per minute;
Rotation of the at least one spindle ( 30 ): 5 to 7 revolutions per revolution of the turntable ( 28 ).

Assignees

• Mahle Int Gmbh

Inventors

• Lehnert Monika
• Maier Kurt

Classifications

• C23C14/325 Primary

  Electric arc evaporation · CPC title

• C23C14/0664

  Carbonitrides · CPC title

• Y10T428/24975

  No layer or component greater than 5 mils thick · CPC title

• C23C14/0605

  Carbon · CPC title

• C23C14/14

  Metallic material, boron or silicon · CPC title