Diesel and turbine fuels from ethanol

Patent metadata

Field	Value
Publication number	US-9840676-B1
Application number	US-201615195257-A
Country	US
Kind code	B1
Filing date	Jun 28, 2016
Priority date	Jul 26, 2012
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

A three step method for the conversion of ethanol into fuels that can be utilized as full-performance military jet or diesel fuels. Embodiments of the invention further describe methods for the selective conversion of ethanol to full performance saturated hydrocarbon fuels that are suitable for both jet and diesel propulsion.

First claim

What is claimed is:

1. A method for converting ethanol to turbine and/or diesel fuels, comprising:
dehydrating ethanol by the use of at least one heterogeneous catalyst to produce ethylene;
converting said ethylene into 1-hexene by reacting said ethylene with a selective oligomerization catalyst that produces exclusively 1-hexene as the primary product, or an unselective oligomerization catalyst that generates a mixture of alpha olefins including 1-hexene;
converting said 1-hexene into a mixture of dimer(s) and trimer(s) by reacting said 1-hexene with a Ziegler Natta catalyst and a cocatalyst at a temperature ranging from ambient to about 60° C.; and
hydrogenating said mixture of dimer(s) including 5-methylundecane and trimer(s) including 7-butyl-5-methylundecane with a hydrogenation catalyst to form a mixture of hydrogenated dimer(s) including 5-methylundecane and trimer(s) including 7-butyl-5-methyltridecane and distilling said mixture of hydrogenated dimer(s) and trimer(s) to produce a C 12 turbine/jet fuel with a density of about 0.75 g/mL, a flashpoint of about 74 C, and a cetane number of about 67; a C 18 diesel fuel with a density of about 0.78 g/mL, a flashpoint of about 128° C., and a cetane number of about 92; and residues.

2. The method according to claim 1 , wherein said ethanol is dehydrated to said ethylene in a continuous process utilizing a low acidity alumina catalyst at elevated temperature ranging from about 250° C. to about 400° C. and under an inert atmosphere.

3. The method according to claim 1 , wherein said ethylene is dried by passage through a drying agent.

4. The method according to claim 1 , wherein said ethylene is condensed under increased pressure or prepared in a continuous process.

5. The method according to claim 1 , wherein said oligomerization catalyst and a fractional distillation is used to isolate 1-hexene.

6. The method according to claim 1 , wherein said conversion of ethylene produces a C 6+ + olefin fraction in addition to said 1-hexene and further comprising separating the C 6+ olefin fraction into a C 6 -C 8 fraction, a C 10 -C 14 fraction, a C 16 -C 20 fraction, and a C 20 + fraction.

7. The method according to claim 6 , wherein said C 6 -C 8 fraction is selectively oligomerized with a Ziegler-Natta catalyst to generate a mixture of dimers and trimers, and said C 10 -C 14 fraction is blended with said C 12 turbine/jet fuel.

8. The method according to claim 1 , wherein said Ziegler-Natta catalyst are metallocene based catalysts of the group 4 elements selected from the group consisting of Ti, Zr, Hf, and any combination thereof.

9. The method according to claim 8 , further comprising adding at least one cocatalyst including aluminum alkyls or methylaluminoxane.

10. The method according to claim 1 , wherein a mixture of 1-hexene/1-octene is oligomerized to produce a product mixture substantially of said dimer(s) and trimer(s).

11. The method according to claim 10 , wherein said oligomerization of 1-hexene produces greater than 81% products 5-methyleneundecane and/or 7-butyl-5-methyleneundecane.

12. The method according to claim 9 , wherein said cocatalyst(s) is added to achieve metal/aluminum ratios of from about 1 up to about 500 and said Ziegler Natta catalyst is added in olefin:catalyst ratios of from about 10,000,000:1 to about 5000:1.

13. The method according to claim 1 , wherein said ethylene is generated from a renewable source and/or a petrochemical source.

14. The method according to claim 1 , wherein said ethanol is from a renewable source selected from the group consisting of sugars, cellulosic or lignocellulosic feedstocks, CO 2 , and bio-derived syngas.

15. The method according to claim 1 , wherein said heterogeneous catalyst(s) includes alumina.

16. The method according to claim 1 , wherein said oligomerization catalyst includes an ethylene trimerization catalyst that is Ti, Cr, Ta, or Zr-based.

17. The method according to claim 1 , wherein said selective oligomerization catalyst is a chromium or titanium based catalyst and is selective towards 1-hexene formation.

18. The method according to claim 1 , wherein said oligomerization conversion of 1-hexene is conducted with a Ziegler-Natta catalyst is either a batch or continuous process.

19. The method according to claim 1 , further comprising adding at least one chain transfer catalyst to said Ziegler Natta catalyst.

20. The method according to claim 19 , wherein said chain transfer catalyst is a zinc alkyl compound added to alter the distribution of said dimer(s), trimer(s), and heavier oligomers.

21. The method according to claim 20 , wherein said zinc alkyl compound to Ziegler Natta catalyst (M) ratio is from about 2 to 8 when the Al:Ziegler Natta catalyst (M) ratio is 100:1.

22. The method according to claim 1 , further comprising catalytically hydrogenating said dimer(s), trimer(s), and heavier oligomers with catalysts selected from the group consisting of nickel, palladium, platinum, and ruthenium catalysts under a hydrogen atmosphere.

23. The method according to claim 1 , wherein said hydrogenation includes temperatures ranging from ambient temperature up to 200° C. and pressures from 1 atm up to about 50 atm.

24. The method according to claim 1 , wherein said residues are further vacuum distilled to produce synthetic oil.

25. The method according to claim 6 , wherein said C 10 -C 14 fraction and/or C 16 -C 20 fraction is blended with said C 18 diesel fuel.

Assignees

• Us Navy
• The Goverment of United States of America as Represented by to Secretary of the Navy

Inventors

• Harvey Benjamin G

Classifications

• C10L2290/08

  Drying or removing water · CPC title

• C10L2270/04

  for turbines, planes, power generation · CPC title

• C10L2200/0469

  Renewables or materials of biological origin · CPC title

• C10G45/00

  Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds · CPC title

• C10L1/04

  essentially based on blends of hydrocarbons · CPC title