Liquid crystal device

Patent metadata

Field	Value
Publication number	US-9840668-B2
Application number	US-201314652323-A
Country	US
Kind code	B2
Filing date	Dec 16, 2013
Priority date	Dec 14, 2012
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

Provided are a liquid crystal device, a composition capable of forming a liquid crystal layer, a method of manufacturing the liquid crystal device, a system for manufacturing the liquid crystal device, and a use of the liquid crystal device. The liquid crystal device is a device capable of exhibiting, for example, a normally transparent or black mode, exhibiting a high contrast ratio, being driven with a low driving voltage, and exhibiting excellent durability such as thermal stability. Such a liquid crystal device may be applied to various optical modulators such as a smart window, a window protective film, a flexible display device, an active retarder for displaying 3D images, or a viewing angle control film.

First claim

What is claimed is:

1. A liquid crystal device, which comprises a liquid crystal layer comprising an alignable polymer network and a liquid crystal compound which is orientationally ordered in the polymer network and of which the ordering direction is changeable by an external action, and which is configured to be switchable between a light transmission mode and a light blocking mode according to the ordering direction of the liquid crystal compound,
wherein the liquid crystal device further comprises an alignment layer adjacent to the liquid crystal layer, and polarizing layers on both sides of the liquid crystal layer, and
wherein the liquid crystal layer satisfies Equation B:
(1− a )×{(2 n o 2 +n e 2 )/3} 0.5 ≦n p ≦(1+ a ) ×n e   [Equation B]

wherein the “a” is a number within a range from 0 to 0.5, the “n o ” is an ordinary refractive index of the liquid crystal compound, the “n e ” is an extraordinary refractive index of the liquid crystal compound, and the “n p ” is a refractive index of the polymer network.

2. The liquid crystal device according to claim 1 , wherein hazes in the light transmission mode and the light blocking mode are 10% or less.

3. The liquid crystal device according to claim 1 , wherein the maximum value of a ratio (T/B) of a brightness (T) of the light transmission mode with respect to a brightness (B) of the light blocking mode is 200 or more.

4. The liquid crystal device according to claim 1 , which is configured to maintain a normally transparent mode or a normally black mode.

5. The liquid crystal device according to claim 4 , wherein a voltage required for realizing a transmittance of 10% from the normally transparent mode or a voltage required for realizing a transmittance of 90% from the normally black mode is 30 V or less.

6. The liquid crystal device according to claim 1 , wherein the liquid crystal layer satisfies the following Equation A after thermal treatment in which it is maintained at 70° C. for 200 hours:
|100×( X 2 −X 1 )/ X 1 |≦10%  [Equation A]

wherein the “X” is a retardation of the liquid crystal layer before the thermal treatment, and the “X 2 ” is a retardation of the liquid crystal layer after the thermal treatment.

7. The liquid crystal device according to claim 1 , wherein the liquid crystal layer satisfies Equation C:
( n e +n o )/2 −b ≦{(2 n o 2 +n e 2 )/3} 0.5 ≦( n e +n o )/2 +b   [Equation C]

where the “n e ” is an extraordinary refractive index of the liquid crystal compound, the “n o ” is an ordinary refractive index of the liquid crystal compound, and the “b” is a number within a range from 0.1 to 1.

8. The liquid crystal device according to claim 1 , wherein the polymer network is a network of a precursor comprising at least one selected from the group consisting of a bifunctional acrylate compound, a multifunctional acrylate compound that is a tri- or more functional compound and a monofunctional acrylate compound such that they satisfy Equations 1 to 3:
A≧ 1.3× B   [Equation 1]

A≧C  [Equation 2]

A≧ 0.6×( B+C )  [Equation 3]

wherein the “A,” “B” and “C” are weight ratios, respectively, between the compounds obtained after converting the sum of weights of the bifunctional acrylate compound, the multifunctional acrylate compound and the monofunctional acrylate compound present in the precursor to be 100.

9. The liquid crystal device according to claim 8 , wherein the precursor comprises at least one selected from the group consisting of the bifunctional acrylate compound, the multifunctional acrylate compound that is a tri- or more functional compound and the monofunctional acrylate compound such that they further satisfy Equations 4 to 6:
A≧40  [Equation 4]

B≦30  [Equation 5]

C≦50  [Equation 6]

wherein the “A,” “B” and “C” are weight ratios, respectively, between the compounds obtained after converting the sum of weights of the bifunctional acrylate compound, the multifunctional acrylate compound and the monofunctional acrylate compound present in the precursor to be 100.

10. The liquid crystal device according to claim 1 , wherein the alignable polymer network has a double refraction of 20 nm or less.

11. The liquid crystal device according to claim 1 , further comprising two base layers which are disposed opposite to each other, and between which the liquid crystal layer is.

12. The liquid crystal device according to claim 11 , wherein an electrode layer is formed on a surface facing the liquid crystal layer of at least one base layer.

13. An optical modulator comprising the liquid crystal device of claim 1 .

Assignees

• Lg Chemical Ltd

Inventors

• Min Sung Joon
• You Jung Sun
• Oh Dong Hyun

Classifications

• C09K19/42

  Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40 · CPC title

• C08L33/14

  of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen · CPC title

• G02F1/1334 Primary

  based on polymer dispersed liquid crystals, e.g. microencapsulated liquid crystals · CPC title

• G02F1/133528

  Polarisers · CPC title

• C09K19/0208

  Twisted Nematic (T.N.); Super Twisted Nematic (S.T.N.); Optical Mode Interference (O.M.I.) · CPC title