Flame-retardant copolymers of dialkyl (meth)acryloyloxyalkyl phosphate or dialkyl (meth)acryloyloxyalkyl phosphonate monomers and polymer foams based made therefrom

Patent metadata

Field	Value
Publication number	US-9840605-B2
Application number	US-201315100956-A
Country	US
Kind code	B2
Filing date	Dec 27, 2013
Priority date	Dec 27, 2013
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

Polymer foam bodies are made from phosphorus-containing thermoplastic random copolymers of a dialkyl (meth)acryloyloxyalkyl phosph(on)ate. Foam bodies made from these copolymers exhibit increased limiting oxygen indices and surprisingly have good properties. In certain embodiments, the phosphorus-containing thermoplastic copolymer is blended with one or more other polymers and formed into nanofoams.

First claim

What is claimed is:

1. A polymer foam body comprising a polymeric matrix containing gas-filled cells, the foam body having a porosity of at least 50% and a number average cell size of 50 to 1000 nm, wherein the polymeric matrix comprises A) a phosphorus-containing, thermoplastic random copolymer of at least one dialkyl (meth)acryloyloxyalkylphosph(on)ate and one or more comonomers, the phosphorus-containing copolymer being characterized in having a glass transition temperature of 70 to 150° C., a weight average molecular weight of at least 60,000 g/mol and 3 to 8% by weight phosphorus contributed by the dialkyl(meth)acryloyloxyalkylphosph(on)ate and B) at least one thermoplastic poly(methyl methacrylate) or thermoplastic non-phosphorus-containing copolymer of methyl methacrylate in which the comonomer(s) have a solubility parameter lower than 20 (megaPascals) 0.5 and the chemical composition of the non-phosphorus-containing copolymer is such that twice the mass fraction of oxygen plus the mass fraction of each of nitrogen, fluorine and silicone in the monomers is greater than 0.2, and wherein the foam body contains 2.5 to 5% by weight phosphorus contributed by the dialkyl(meth)acryloyloxyalkylphosph(on)ate.

2. The polymer foam body of claim 1 , wherein the diethyl(meth)acryloyloxyalkyl phosphate is diethylmethacryloyloxymethyl phosphate or diethylmethacryloyloxyethyl phosphate.

3. The polymer foam body of claim 1 , wherein the comonomer(s) of the phosphorus-containing, thermoplastic random copolymer of at least one dialkyl (meth)acryloyloxyalkylphosph(on)ate include at least one alkyl (meth)acrylate.

4. The polymer foam body of claim 3 , wherein the alkyl (meth)acrylate is methyl methacrylate.

Assignees

• Dow Global Technologies Llc
• Qi Yudong
• Li Yan
• Bunker Shana P
• Costeux Stephane
• Morgan Ted A

Inventors

• Qi Yudong
• Li Yan
• Bunker Shana P
• Costeux Stephane
• Morgan Ted A

Classifications

• C08J2333/10

  Homopolymers or copolymers of methacrylic acid esters · CPC title

• C08J9/0061

  characterized by the use of several polymeric components · CPC title

• C08J2205/044

  Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter · CPC title

• C08F220/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08L33/12

  Homopolymers or copolymers of methyl methacrylate · CPC title