PIPA polyol based conventional flexible foam

Patent metadata

Field	Value
Publication number	US-9840602-B2
Application number	US-201414917000-A
Country	US
Kind code	B2
Filing date	Sep 11, 2014
Priority date	Sep 13, 2013
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

A process for forming a conventional flexible polyurethane foam includes providing a polyol component including a PIPA polyol that is a dispersion having a solids content from 10% to 75 wt %, based on a total weight of the PIPA polyol, providing an isocyanate component that includes at least one polyisocyanate, providing an additive component that includes a catalyst, and forming a reaction mixture including the polyol component, the isocyanate component, and the additive component to form a flexible polyurethane foam with a resiliency value below 45%. The reaction mixture has an isocyanate index from 90 to 150. The PIPA polyol is a reaction product of a mixture including at least a low equivalent weight polyol having a number average hydroxyl equivalent weight of less than 80, a polyisocyanate compound having a number average isocyanate equivalent weight that is less than 225, and a liquid base poly ether polyol having a number average hydroxyl equivalent weight from 200 to 1500 and at least 80% of secondary hydroxyl groups based on a total amount of hydroxyl groups in the liquid base polyether polyol.

First claim

The invention claimed is:

1. A process for forming a flexible polyurethane foam, the process comprising:
providing a polyol component including 1) a PIPA polyol that is a dispersion having a solids content from 15% to 75 wt %, based on a total weight of the PIPA polyol, the PIPA polyol being prepared in the absence of a tin catalyst from a reaction product of a first mixture including at least a low equivalent weight polyol having a number average hydroxyl equivalent weight of less than 80, a polyisocyanate compound having a number average isocyanate equivalent weight that is less than 225, and a liquid base polyether polyol having a number average hydroxyl equivalent weight from 200 to 1500 and at least 90% of secondary hydroxyl groups based on a total amount of hydroxyl groups in the liquid base polyether polyol and 2) a polyoxypropylene-polyoxyethylene polyether triol having a molecular weight from 3000 to 3500, having a polyoxyethylene content that is less than 15 wt % based on the total weight of polyoxyethylene and polyoxypropylene in the polyoxypropylene-polyoxyethylene polyether triol, and having less than 10% primary hydroxyl groups, based on the total amount of hydroxyl groups in the polyoxypropylene-polyoxyethylene polyether triol, wherein the polyol component has an overall solids content from 2 wt % to 50 wt %, based on the total weight of the polyol component;
providing an isocyanate component that includes at least one polyisocyanate;
providing an additive component that includes a catalyst; and
forming a reaction mixture including the polyol component, the isocyanate component, and the additive component to form a flexible polyurethane foam with a resiliency value below 45%, the reaction mixture having an isocyanate index from 90 to 150.

2. The process as claimed in claim 1 , wherein the liquid base polyether polyol is prepared by reacting one or more alkylene oxides in the presence of a potassium hydroxide polymerization catalyst.

3. The process as claimed in claim 1 , wherein the polyurethane foam has a density within a range of 10 kg/m 3 to 100 kg/m 3 .

4. The process as claimed in claim 1 , wherein the polyurethane foam has a density within a range of 15 kg/m 3 to 50 kg/m 3 .

5. The process as claimed in claim 1 , wherein the low equivalent weight polyol is triethanolamine or a blend including triethanolamine and another low equivalent weight polyol having a number average hydroxyl equivalent weight of less than 80.

6. The process as claimed in claim 1 , wherein the liquid base polyether polyol is a triol that is a polyoxypropylene homopolymer or a copolymer of 80 wt % to 99.5 wt % of polyoxypropylene and 0.5 wt % to 20 wt % of polyoxyethylene based on the total weight of polyoxyethylene and polyoxypropylene in the liquid base polyether polyol, and the hydroxyl equivalent weight of the liquid base polyether polyol is from 900 to 1350.

7. The process as claimed in claim 1 , wherein the first mixture further includes a non-silicone based stabilizer that is different from the PIPA polyol.

8. The process as claimed in claim 1 , wherein the first mixture further includes a primary amine as a co-reactant with the low equivalent weight polyol to get PIPA/PHD copolymer based particles.

9. A foam product prepared according to the process as claimed in claim 1 .

Assignees

• Dow Global Technologies Llc

Inventors

• Cookson Paul A
• Amici-Kroutilova Irena
• Lora Lamia Alberto
• Casati Francois

Classifications

• C08G18/0876 Primary

  the dispersing or dispersed phase being a polyol · CPC title

• C08G18/3281

  containing three hydroxy groups · CPC title

• C08G18/165

  covered by C08G18/18 and C08G18/24 · CPC title

• C08G18/7621

  being toluene diisocyanate including isomer mixtures · CPC title

• C08G18/1808

  having alkylene polyamine groups · CPC title