Olefin polymerization process with continuous transfer

Patent metadata

Field	Value
Publication number	US-9840567-B2
Application number	US-201414762529-A
Country	US
Kind code	B2
Filing date	Jan 21, 2014
Priority date	Jan 22, 2013
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

A process for the preparation of a polyolefin is disclosed. The process includes introducing one or more olefin reactants, diluents and polymerization catalyst into a first loop reactor, and while circulating the olefin reactants, diluents and polymerization catalyst in the first loop reactor. The method includes polymerizing the one or more olefin reactants to produce a polyolefin slurry comprising liquid diluent and solid olefin polymer particles. The method includes withdrawing polyolefin slurry comprising solid olefin polymer particles and diluent from the first reactor and introducing the withdrawn particles into a second loop reactor, by means of one or more settling legs provided on the first reactor, wherein each settling leg has an inlet connected to the first reactor and an outlet connected to the second reactor by means of a transfer line wherein at least one settling leg is continuously open allowing continuous transfer of solid olefin polymer particles from the first loop reactor to the second loop reactor. The process further comprises controlling the continuous transfer of solid olefin polymer particles from the first loop reactor to the second loop reactor by at least one continuously open settling leg.

First claim

The invention claimed is:

1. A process for the preparation of a polyolefin in at least two slurry loop reactors comprising a first loop reactor connected in series with a second loop reactor, the process comprising the steps of:
introducing one or more olefin reactants, diluents and polymerization catalyst into said first loop reactor, and while circulating said olefin reactants, diluents and polymerization catalyst in said first loop reactor;
polymerizing said one or more olefin reactants to produce a polyolefin slurry comprising liquid diluent and solid olefin polymer particles;
withdrawing polyolefin slurry comprising solid olefin polymer particles and diluent from said first loop reactor and introducing the withdrawn solid olefin polymer particles into the second loop reactor by means of one or more settling legs provided on said first loop reactor, wherein each settling leg has an inlet connected to the first loop reactor and an outlet connected to the second loop reactor by means of a transfer line;
characterized in that at least one settling leg is continuously open allowing continuous transfer of solid olefin polymer particles from said first loop reactor to said second loop reactor, and in that the process further comprises the step of controlling the continuous transfer of solid olefin polymer particles from said first loop reactor to said second loop reactor by at least one continuously open settling leg;
wherein the step of controlling the continuous transfer of solid olefin polymer particles from said first loop reactor to said second loop reactor by at least one continuously open settling leg comprises the step of controlling the number of continuously open settling legs and/or the step of controlling the flow rate of said at least one continuously open settling leg, and monitoring one or more parameters selected from ratio between polymer solids and reactants transferred into the second loop reactor, ratio between polymer solids and diluent transferred into the second loop reactor, the residence time of polymer solids in the one or more settling legs, and combinations thereof.

2. The process according to claim 1 , characterized in that the outlet of at least one settling leg is provided with a control valve, so that the outlet of the settling leg can be completely or partially open.

3. The process of claim 1 , wherein the monitoring one or more parameters is a continuous monitoring.

4. The process of claim 1 , characterized in that the step of controlling the continuous transfer of solid olefin polymer particles from said first loop reactor to said second loop reactor by at least one continuously open settling leg comprises one or more of:
i) lowering the volumetric flow rate of the polyolefin slurry transferred from said first loop reactor to said second loop reactor when:
the ratio between polymer solids and reactants transferred into the second loop reactor is lower than a first predetermined value; and/or
the ratio between polymer solids and diluent transferred into the second loop reactor is lower than a first predetermined value; and/or
the residence time of polymer solids in the settling legs is lower than a first predetermined value;

ii) raising the volumetric flow rate of the polyolefin slurry transferred from said first loop reactor to said second loop reactor when:
the ratio between polymer solids and reactants transferred into the second loop reactor is higher than a second predetermined value; and/or
the ratio between polymer solids and diluent transferred into the second loop reactor is higher than a second predetermined value; and/or
the residence time of polymer solids in the settling legs is higher than a second predetermined value.

5. The process according to claim 4 , characterized in that raising the volumetric flow rate of the polyolefin slurry transferred from said first loop reactor to said second loop reactor comprises raising the number of continuously open settling legs and/or lowering the volumetric flow rate of the polyolefin slurry transferred from said first loop reactor to said second loop reactor comprises lowering the number of continuously open settling legs.

6. The process according to claim 4 , characterized in that the outlet of at least one continuously open settling leg is provided with a control valve and in that raising the volumetric flow rate of the polyolefin slurry transferred from said first loop reactor to said second loop reactor comprises raising the opening of the outlet control valve of at least one continuously open settling leg and/or lowering the volumetric flow rate of the polyolefin slurry transferred from said first loop reactor to said second loop reactor comprises lowering the opening of the outlet control valve of at least one continuously open settling leg.

7. The process according to claim 1 , characterized in that each inlet of said settling legs is connected to said first loop reactor by means of one transfer conduit provided with a bulk valve and in that a continuously open settling leg is a settling leg having its inlet bulk valve opened.

8. The process according to claim 1 , characterized in that said first loop reactor is provided with two or more settling legs.

9. The process according to claim 1 , characterized in that at least two settling legs are continuously open allowing continuous withdrawal and transfer of said slurry from said first loop reactor to said second loop reactor, and in that said process further comprises the step of controlling flow distribution among the continuously open settling legs.

10. The process of claim 1 , wherein the step of controlling the flow distribution among the continuously open settling legs comprises:
monitoring flow from each settling leg, wherein said monitored flow is selected from flow of reactants to the subsequent reactor, flow of diluent to the subsequent reactor, flow of polymer solids to the subsequent reactor, the total flow transferred to the subsequent reactor, and combination thereof, and
adjusting the monitored flow of at least one settling leg, the outlet of said settling leg being provided with a valve which is continuously open and in that said valve is used to adjust the flow of said settling leg.

11. The process according to claim 1 , characterized in that no flow control and/or no pressure control are provided in said transfer line.

12. The process according to claim 1 , wherein one or more flushing system is provided in each settling leg.

13. The process according to claim 1 , wherein said polyolefin has a multimodal molecular weight distribution.

14. The process according to claim 1 , wherein said polyolefin is polyethylene.

15. The process according to claim 1 , wherein said polyolefin is prepared in the presence of at least one metallocene catalyst.

Assignees

• Total Res & Technology Feluy

Inventors

• Fouarge Louis
• Horre Annelies
• Nauwelaerts Geert
• Richet Marc
• Wilderiane Pascal

Classifications

• C08F2/14 Primary

  Organic medium · CPC title

• C08F2/01 Primary

  characterised by special features of the polymerisation apparatus used · CPC title

• C08F210/16

  Copolymers of ethene with alpha-alkenes, e.g. EP rubbers · CPC title

• C08F210/14

  Monomers containing five or more carbon atoms · CPC title

• C08F4/65927

  two cyclopentadienyl rings being mutually bridged · CPC title