Process for the preparation of a catalyst based on molybdenum for use in hydrotreatment or in hydrocracking

Patent metadata

Field	Value
Publication number	US-9839903-B2
Application number	US-201414262835-A
Country	US
Kind code	B2
Filing date	Apr 28, 2014
Priority date	Apr 30, 2013
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

The invention concerns a process for the preparation of a catalyst for carrying out hydrogenation reactions in hydrotreatment and hydrocracking processes. Said catalyst is prepared from at least one mononuclear precursor based on molybdenum (Mo), in its monomeric or dimeric form, having at least one Mo═O or Mo—OR bond or at least one Mo═S or Mo—SR bond where [R=C x H y where x≧1 and (x−1)≦y≦(2x+1) or R=Si(OR′) 3 or R=Si(R′) 3 where R′=C x′ H y′ where x′≧1 and (x′−1)≦y′≦(2x′+1)], and optionally from at least one promoter element from group VIII. Said precursors are deposited onto an oxide support which is suitable for the process in which it is used, said catalyst being dried at a temperature of less than 200° C. then advantageously being sulphurized before being deployed in said process.

First claim

The invention claimed is:

1. A process for the preparation of a catalyst comprising at least one support, optionally at least one metal from group VIII of the periodic classification of the elements and at least molybdenum, said process comprising:
introducing the molybdenum onto the support, in an organic solvent A, in the form of at least one mononuclear precursor compound based on Mo, in its monomeric or dimeric form, having at least one Mo═O or Mo—OR bond or at least one Mo═S or Mo—SR bond where: R=C x H y where x≧1 and (x−1)≦y≦(2x+1) or R=Si(OR′) 3 or R=Si(R′) 3 and where R′=C x′ H y′ where x′≧1 and (x′−1)≦y′≦(2x′+1); to obtain an impregnated support,
drying the impregnated support under vacuum and at ambient temperature to obtain a dried impregnated support, and
conducting ex situ sulphurization of the dried impregnated support in a H 2 S/H 2 or H 2 S/N 2 mixture containing at least 5% by volume of H 2 S in the mixture at a temperature between 300 and 400° C.

2. The process as claimed in claim 1 , in which the catalyst contains a metal from group VIII which is selected from cobalt, iron and nickel.

3. The process as claimed in claim 2 , in which the metal from group VIII is nickel.

4. The process as claimed in claim 1 , in which the molybdenum precursor is a mononuclear precursor based on Mo, used in its monomeric or dimeric form, having the following formula:
Mo(═O) n (═S) n″ (OR) a (SR′) b (L1) c (L2) d (L3) e (L4) f (L5) g

where R=C x H y where x≧1 and (x−1)≦y≦(2x+1) or R=Si(OR″) 3 or R=Si(R″) 3 ,
where R″=C x′ ′H y′ ′ where [x″≧1 and (x″−1)≦y″≦(2x″+1)],
where R′=C x′ H y′ where x′≧1 and (x′−1)≦y′≦(2x′+1) or R′=Si(OR″′) 3 or R′=Si(R″′) 3
where R″′=C x″′ Hy″′ where [x″′≧1 and (x″′−1)≦y″′≦(2x″′+1)],
where 0≦n+n′≦2 and 0≦n≦2 and 0≦n′≦2,
where, if n =n′=0, then (a≠0 or b≠0) and (a+b+c+d+e+f+g=6 and 0≦a≦6, 0≦b≦6, 0≦c≦6, 0≦d≦6, 0≦e≦6, 0≦f≦6, 0≦g≦6, or(a+b+c+d+e+f+g=5 and 0≦a≦5, 0≦b≦5, 0≦c≦5, 0≦d≦5, 0≦e≦5, 0≦f≦5, 0≦g≦5),or (a+b+c+d+e+f+g=4 and 0≦a≦4, 0≦b≦4, 0≦c≦4, 0≦d≦4, 0≦e≦4, 0≦f≦4, 0≦g≦4),
where, if (n=1 and n′=0) or (n′=1 and n=0), then a+b+c+d+e+f+g=4 and 0≦a≦4, 0≦b≦4, 0≦c≦4, 0≦d≦4, 0≦e≦4, 0≦f≦4, 0≦g≦4) or (a+b+c+d+e+f+g=3 and 0≦a≦3, 0≦b≦3, 0≦c≦3, 0≦d≦3, 0≦e≦3 , 0≦f≦3, 0≦g≦3),
where, if n+n′=2 and 0≦n≦2 and 0≦n′≦2, then (a+b+c+d+e+f+g=2 and 0≦a≦2, and 0≦b≦2, 0≦c≦2, 0≦d≦2, 0≦e≦2, 0≦f≦2, 0≦g≦2),
with (L1), (L2), (L3), (L4) and (L5) being selected from the following ligands: THF, dimethyl ether, dimethylsulphide, P(CH 3 ) 3 , allyl, aryl, halogen, amine, acetate, acetylacetonate, halide, hydroxide and —SH.

5. The process as claimed in claim 4 , in which the molybdenum precursor is selected from Mo(OEt) 5 , Mo(OEt) 6 , Mo(═O)(OEt) 4 , Mo(═S)(OEt) 4 , Mo(═S)(SEt) 4 , Mo(═O) 2 (OEt) 2 , Mo(OC 6 H 5 ) 6 , Mo(SEt) 5 , Mo(SEt) 6 , Mo(OEt)(SEt) 4 , Mo(OEt) 2 (SEt) 3 , Mo(OEt) 3 (SEt) 2 , Mo(OEt) 4 (SEt), Mo(═O)(OEt) 3 (acac) with Et=CH 2 CH 3 (ethyl group) and acac=(CH 3 COCHCOCH 3 ) − (acetylacetonate) in their monomeric or dimeric form.

6. A process for the preparation of a catalyst as claimed in claim 1 , in which the molybdenum and the optional metal or metals from group VIII are introduced simultaneously or successively.

7. A process for the preparation of a catalyst as claimed in claim 1 , comprising at least the following steps:
a) impregnation by bringing a solution S comprising the organic solvent A with at least said mononuclear precursor based on molybdenum, in its monomeric or dimeric form, having at least one Mo═O or Mo—OR bond or at least one Mo═S or Mo—SR bond where R=C x H y where x≧1 and (x−1)≦y≦(2x+1) or R=Si(OR′) 3 or R=Si(R′) 3 where R′=C x′ H y′ where x′≧1 and (x′−1)≦y′≦(2x′+1), into contact with a porous mineral support, which has been calcined under vacuum or in a stream of inert gas to obtain an impregnated support;
b) maturing the impregnated support in an anhydrous atmosphere;
c) drying the impregnated support under vacuum and at ambient temperature to obtain a dried impregnated support;
d) conducting ex situ sulphurization of the dried impregnated support in a H 2 S/H 2 or H 2 S/N 2 mixture containing at least 5% by volume of H 2 S in the mixture at a temperature between 300 and 400° C.

8. A process for the preparation of a catalyst as claimed in claim 7 , in which the optional metal from group VIII is introduced into step a) in the same solution S as the molybdenum precursor or after the drying c) in a post-impregnation step a2) with the aid of a solution using an organic solvent B, or after the sulphurization step d) in a post-impregnation step a3) with the aid of an aqueous or organic solution.

9. A method comprising:
preparing a catalyst comprising at least one support, optionally at least one metal from group VIII of the periodic classification of the elements, and at least molybdenum by said process as claimed in claim 1 ; and
employing the catalyst in a reaction for the hydrogenation of hydrocarbon feeds.

10. A method as claimed in claim 9 , wherein the hydrogenation is hydrotreatment or hydrocracking.

Assignees

• Ifp Energies Now

Inventors

• Alphazan Thibault
• Bonduelle Audrey
• Legens Christele
• Raybaud Pascal
• Coperet Christophe

Classifications

• B01J37/0203 Primary

  the impregnation liquid containing organic compounds · CPC title

• B01J2531/64

  Molybdenum · CPC title

• B01J37/0009

  Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst · CPC title

• B01J37/20

  Sulfiding · CPC title

• B01J37/0207

  Pretreatment of the support · CPC title