System and method for mass production of graphene platelets in arc plasma

Patent metadata

Field	Value
Publication number	US-9839896-B2
Application number	US-201414547747-A
Country	US
Kind code	B2
Filing date	Nov 19, 2014
Priority date	Jun 12, 2012
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

A system and method for producing graphene includes a discharge assembly and a substrate assembly. The discharge assembly includes a cathode and an anode, which in one embodiment are offset from each other. The anode produces a flux stream that is deposited onto a substrate. A collection device removes the deposited material from the rotating substrate. The flux stream can be a carbon vapor, with the deposited flux being graphene.

First claim

The invention claimed is:

1. A graphene producing arc discharge device comprising:
a chamber;
a graphite cathode comprising a graphite cathode electrode inside the chamber and forming a graphite cathode ring with a central opening, the graphite cathode ring lying in a cathode ring plane and having a first side and a second side opposite the first side;
an ablative carbon anode comprising a carbon anode electrode inside the chamber and forming a carbon anode rod with a longitudinal axis, the longitudinal axis substantially orthogonal to the cathode ring plane and the carbon anode rod aligned with the central opening of the graphite cathode at the first side of said graphite cathode;
a substrate inside the chamber and aligned with said graphite cathode and said ablative carbon anode at the second side of said graphite cathode, wherein said substrate is a cylindrical tube that extends along a longitudinal axis, the longitudinal axis being substantially perpendicular to a longitudinal axis of the carbon anode electrode, and the cylindrical tube being rotatable,
wherein said graphite cathode electrode and said carbon anode electrode are configured to create an arc discharge producing a carbon vapor flux stream from said carbon anode rod that extends through the central opening of the graphite cathode ring and directly deposits graphene material from the carbon vapor flux stream of said carbon anode rod onto an outer surface of the cylindrical tube as the cylindrical tube rotates; and
a collection device inside the chamber comprising a brush and configured to remove the graphene material that has been deposited onto the outer surface of the cylindrical tube.

2. The device of claim 1 , further comprising a collection device configured to remove the deposited material from said substrate.

3. The device of claim 2 , wherein said collection device comprises a brush.

4. The device of claim 1 , wherein the collection device removing the graphene material from said substrate simultaneous with said ablative carbon anode depositing the graphene material on said substrate.

5. The device of claim 1 , wherein said substrate is heated by the carbon vapor flux stream.

6. The device of claim 1 , wherein said carbon anode a carbon anode electrode and said graphite cathode is a graphite cathode electrode, wherein said carbon anode electrode and graphite cathode electrode are configured to provide said flux stream.

7. The device of claim 1 , wherein the device operates at a pressure of up to 500 Torr of helium and a substrate temperature of 700-1,200° C.

8. The device of claim 1 , further comprising a heating block comprising a solid cylindrical heating block and wherein said substrate is coaxially arranged about said solid cylindrical heating block.

9. The device of claim 8 , further comprising a heating element embedded in the heating block, said heating element imparting heat to said heating block, and said heating block dispersing the heat from said heating element uniformly throughout said heating block to uniformly heat said substrate.

10. The device of claim 9 , wherein said substrate includes a conical top connected to a rotation device to rotate said heating block.

11. The device of claim 9 , wherein said solid cylindrical heating block is concentrically arranged inside said cylindrical tube whereby an inside diameter of said cylindrical tube is greater than an outer diameter of said solid cylindrical heating block.

12. The device of claim 8 , wherein said heating block comprises cement.

13. The device of claim 8 , wherein said cylindrical tube has at least one open end, and said heating block is received in the open end of said substrate.

14. The device of claim 1 , further comprising a collection device configured to remove the deposited material from said substrate, said collection device comprising a brush.

15. The device of claim 1 , further comprising a rotation device configured to rotate said substrate, and wherein said carbon vapor flux stream is deposited on said substrate at a first side of said substrate simultaneously with said collection device removing the graphene material from a second side of said substrate as the substrate rotates, wherein said first side is different from said second side.

16. The device of claim 15 , wherein the first side comprises a top portion of said substrate and the second side comprises a bottom portion of said substrate.

17. The device of claim 1 , wherein the longitudinal axis of said ablative carbon anode is substantially vertical whereby the carbon vapor flux stream projects substantially outward and downward from a distal end of said ablative carbon anode.

Assignees

• Univ George Washington

Inventors

• Keidar Michael
• Shashurin Alexey

Classifications

• B01J2219/0809

  employing two or more electrodes · CPC title

• C01B31/0453

  Chemistry & Metallurgy · mapped topic

• B01J2219/0822

  The electrode being consumed · CPC title

• B82Y40/00

  Manufacture or treatment of nanostructures · CPC title

• B01J2219/0839

  Carbon · CPC title