Porous separation article

Patent metadata

Field	Value
Publication number	US-9839881-B2
Application number	US-201314410644-A
Country	US
Kind code	B2
Filing date	Oct 1, 2013
Priority date	Oct 4, 2012
Publication date	Dec 12, 2017
Grant date	Dec 12, 2017

Abstract

The invention relates to a porous separation article having a fluoropolymer or polyamide binder interconnecting one or more types of interactive powdery materials or fibers. The interconnectivity is such that the binder connects the powdery materials or fibers in discrete spots rather than as a complete coating, allowing the materials or fibers to be in direct contact with, and interact with a fluid. The resulting article is a formed multicomponent, interconnected web, with porosity. The separation article is useful in water purification, as well as in the separation of dissolved or suspended materials in both aqueous and non-aqueous systems in industrial uses. The separation article can function at ambient temperature, as well as at elevated temperatures.

First claim

The invention claimed is:

1. A composite porous solid article for the separation of components of a fluid comprising:
a) 0.5 to 20 weight percent of a high molecular fluoropolymer binder in the form of particles of from 20 nm to 8 microns weight average particle size, having a melt viscosity of greater than 1 kpoise as measured by ASTM D3835 at 232° C. and 100 s −1 wherein said fluoropolymer comprises a homopolymer of vinylidene fluoride, or a copolymer comprising more than 50 weight percent of vinylidene fluoride units, and
b) 80 to 99.5 weight percent of interactive particles having an average particle diameter of from 0.1 to 3,000 microns, the weight percent based on the total of thermoplastic fluoropolymer and interactive particles,

wherein said interactive particles exhibit interconnectivity.

2. The composite solid article of claim 1 , wherein the fluoropolymer binder is a blend of from 5 to 49 weight percent polymethylmethacrylate polymer or copolymer with 51 to 95 weight percent of fluoropolymer, wherein said fluoropolymer comprises a homopolymer of vinylidene fluoride, or a copolymer comprising more than 50 weight percent of vinylidene fluoride units.

3. The composite solid article of claim 1 , wherein the fluoropolymer binder has a melt viscosity of 15 to 50 kpoise.

4. The composite solid article of claim 1 , wherein the interactive particles are selected from the group consisting of metallic particles of 410, 304, and 316 stainless steel, copper, aluminum and nickel powders, ferromagnetic materials, activated alumina, activated carbon, carbon nanotubes, silica gel, acrylic powders and fibers, cellulose fibers, glass beads, various abrasives, common minerals such as silica, wood chips, ion-exchange resins, ceramics, zeolites, diatomaceous earth, polyester particles and fibers, and particles of engineering resins such as polycarbonate.

5. The composite solid article of claim 1 , wherein the interactive particles comprise activated carbon.

6. A filtration system comprising the article of claim 1 , wherein said article is in block form.

7. The filtration system of claim 6 , wherein said filtration system is a hybrid system further comprising a secondary filtration system.

8. The composite solid article of claim 1 , wherein said fluoropolymer is a functionalized fluoropolymer.

9. A process for separating compounds from a fluid, comprising passing the fluid through the porous separation article of claim 1 .

10. The process of claim 9 , wherein said fluid is selected from the group consisting of cold water, hot water, organic solvents, and pharmaceutical or biological preparations.

11. The composite solid article of claim 1 , wherein the fluoropolym.er particles have an average weight average particle size of less than 500 nm.

Assignees

• Arkema Inc

Inventors

• Stabler Sean M
• Roland Thomas F
• Seiler David A
• Amin-Sanayei Ramin
• Kosar Walter

Classifications

• B01D2325/12

  Adsorbents being present on the surface of the membranes or in the pores · CPC title

• B01D2239/086

  Binders between particles or fibres · CPC title

• B01D41/04

  of rigid self-supporting filtering material · CPC title

• B01D2239/1216

  Pore size · CPC title

• B01D71/34

  Polyvinylidene fluoride · CPC title