Polyolefin adhesive material for use in solar modules

Patent metadata

Field	Value
Publication number	US-9837569-B2
Application number	US-201615003874-A
Country	US
Kind code	B2
Filing date	Jan 22, 2016
Priority date	Nov 4, 2011
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

This disclosure generally relates to films capable of use in electronic device modules and to electronic device modules including such films. The disclosure also generally relates to materials for use in such films.

First claim

What is claimed is:

1. A film capable of use in a photovoltaic solar module, comprising:
a polyolefin;
a silane;
one or more cross-linking agents; and
a plasticizer;

wherein the average % transmittance of the film is at least 90% over a wavelength range of 400-1100 nm.

2. The film of claim 1 , wherein the plasticizer is non-polar.

3. The film of claim 1 , wherein the plasticizer has a Tg<−50° C.

4. The film of any of claim 1 , wherein the plasticizer is liquid at 20° C.

5. The film of any of claim 1 , wherein the polyolefin is an ethylene/α-olefin copolymer.

6. The film of claim 5 , wherein the α-olefin moiety of the ethylene/α-olefin copolymer has four or more carbons.

7. The film of claim 5 , wherein the low crystalline ethylene/α-olefin copolymer has a DSC peak melting point of less than or equal to 50° C.

8. The film of claim 7 , wherein the α-olefin moiety of the ethylene/α-olefin copolymer is a butene α-olefin.

9. The film of claim 1 , wherein the silane is an unsaturated alkoxysilane.

10. The film of claim 9 , wherein the unsaturated alkoxysilane is an acrylic alkoxysilane.

11. The film of claim 1 , wherein the one or more cross-linking agents are one of a thermal curative and a photo-curative.

12. The film of claim 11 , wherein the thermal curative is a peroxide.

13. The film of claim 1 , further comprising an additional ethylene/α-olefin copolymer.

14. The film of claim 13 , wherein the additional ethylene/α-olefin copolymer is one of an ethylene/butene copolymer and an ethylene/octene copolymer.

15. The film of claim 1 , wherein the average % transmittance of the film is at least 90% over a wavelength range of 400-1100 nm after exposure to an 85/85 durability test for 1000 hrs.

16. The film of claim 1 , wherein a machine direction shrinkage measurement of the film is less than a machine direction shrinkage measurement of a film not including the plasticizer.

17. The film of claim 1 , wherein a storage modulii measurement of the film at 150° C. is greater than storage modulii measurement at 150° C. of a film not including the plasticizer.

18. The film of claim 1 , wherein a gel fraction of the film is less than 20%.

19. A solar cell module comprising the film of claim 1 .

Assignees

• 3M Innovative Properties Co

Inventors

• Rasal Rahul M
• Jennen Jay M
• Linert Jeffrey G
• Erdogan-Haug Belma
• Clough Robert S

Classifications

• H01L31/0481 Primary

  Electricity · mapped topic

• C09J123/0807

  Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms · CPC title

• H01L31/02168

  Electricity · mapped topic

• Y02E10/50

  Photovoltaic [PV] energy · CPC title

• C09J123/0815

  Copolymers of ethene with aliphatic 1-olefins · CPC title