Infrared gas analysis device, and method for using same

Patent metadata

Field	Value
Publication number	US-9835551-B2
Application number	US-201515321372-A
Country	US
Kind code	B2
Filing date	Jul 3, 2015
Priority date	Jul 4, 2014
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

The infrared gas analysis device includes: a measurement cell to allow a sample gas containing a component to be measured to flow therethrough; a comparison cell including a reference gas; a pair of light sources provided in one end side of the measurement cell and the comparison cell, the cells being irradiated with an infrared ray from one and the other of the light sources, respectively; and a detection unit provided in another end side of the measurement cell and the comparison cell to detect the component to be measured by using infrared rays output from the measurement cell and the comparison cell. A gas for detection made of a component different from the component to be measured and having an infrared absorption band at at least a part of wavenumbers in infrared absorption bands of the component to be measured is encapsulated in the detection unit.

First claim

The invention claimed is:

1. An infrared gas analysis device comprising:
a measurement cell to allow a sample gas containing a component to be measured to flow therethrough;
a comparison cell including a reference gas;
a pair of light sources provided in one end side of the measurement cell and the comparison cell, the measurement cell and the comparison cell being irradiated with an infrared ray from one and the other of the light sources, respectively; and
a detection unit provided in another end side of the measurement cell and the comparison cell to detect the component to be measured by using infrared rays output from the measurement cell and the comparison cell, wherein
the detection unit encapsulating a gas for detection consisting of a component, which is different from the component to be measured, having an infrared absorption band at least at a part of wavenumbers in infrared absorption bands of the component to be measured, and
the detection unit comprises a first chamber, a second chamber, and a membrane separating the first chamber and the second chamber whereby the membrane is configured to move based on a temperature difference between the first chamber and second chamber.

2. The infrared gas analysis device according to claim 1 , wherein
an inner space of the detection unit to encapsulate the gas for detection is separated into the first chamber, which is in a side of the measurement cell, and the second chamber, which in a side of the comparison cell, and
the detection unit detects the component to be measured on a basis of the temperature difference between the first chamber and the second chamber.

3. The infrared gas analysis device according to claim 2 , wherein
the component to be measured is a nitrite ester, and
the gas for detection contains ammonia.

4. The infrared gas analysis device according to claim 3 , for online analysis for a production device for a nitrite ester.

5. The infrared gas analysis device according to claim 2 , wherein
the detection unit has a signal processing unit and a computing unit,
the signal processing unit outputs the concentration of the gas for detection on the basis of the temperature difference between the first chamber and the second chamber, and
the computing unit calculates the concentration of the component to be measured by correcting the concentration of the gas for detection output from the signal for detection.

6. The infrared gas analysis device according to claim 2 , wherein
the membrane comprises an insulating polymer film on which an electro-conductive film of metal is formed.

7. The infrared gas analysis device according to claim 1 , wherein
the component to be measured is a nitrite ester, and
the gas for detection contains ammonia.

8. The infrared gas analysis device according to claim 7 , for online analysis for a production device for a nitrite ester.

9. A method for using an infrared gas analysis device,
the method comprising:
irradiating: (1) a measurement cell that allows a sample gas containing nitrite ester to be measured to flow therethrough, and (2) a comparison cell including a reference gas with an infrared ray from a pair of light sources provided in one end side of the measurement cell and the comparison cell while the sample gas is flowing through the measurement cell; and
detecting the nitrite ester on a basis of temperature change of a gas including ammonia for detection encapsulated in a detection unit, which is provided in another end side of the measurement cell and the comparison cell, wherein
the temperature change is caused by infrared rays entering the detection unit from the measurement cell and the comparison cell, and
the gas for detection has an infrared absorption band at least at a part of wavenumbers in infrared absorption bands of the component to be measured.

10. The method according to claim 9 , wherein
the detection unit is separated in a first chamber and a second chamber by a membrane that is configured to move based on the temperature change between the first chamber and second chamber, and
the detecting is performed by detecting that a membrane has moved because of the temperature change.

11. The method according to claim 10 , wherein
the membrane comprises an insulating polymer film on which an electro-conductive film of metal is formed.

Assignees

• Ube Industries

Inventors

• Il Hirofumi
• FUKUI Yuya
• Tanaka Syuji

Classifications

• G01N33/0036

  specially adapted to detect a particular component (physical analysis of gaseous biological material G01N33/497) · CPC title

• G01N21/3504 Primary

  for analysing gases, e.g. multi-gas analysis · CPC title

• G01N2201/061

  Sources · CPC title

• G01N21/37

  using pneumatic detection {(opto-acoustic detection G01N21/1702)} · CPC title