System and method for transitioning a reversible solid oxide fuel cell system between generation and electrolysis modes

Patent metadata

Field	Value
Publication number	US-9834846-B2
Application number	US-201514745250-A
Country	US
Kind code	B2
Filing date	Jun 19, 2015
Priority date	Jun 19, 2015
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

A method for transitioning between fuel cell and electrolysis modes in a Reversible Solid Oxide Fuel Cell (RSOFC) system includes measuring and recording sensor data indicating a status of components associated with an RSOFC system coupled to an electrical power grid, the system comprising an RSOFC unit, a hydrogen compression system, a hydrogen storage system, and a water supply, determining a state of the RSOFC system based on the sensor data through a conditional logic algorithm, and transitioning the RSOFC system between the fuel cell mode and the electrolysis mode based upon the sensor data and the system state.

First claim

What is claimed is:

1. A method for transitioning between fuel cell and electrolysis modes in a Reversible Solid Oxide Fuel Cell (RSOFC) system, the method comprising:
measuring and recording sensor data indicating a status of components associated with a reversible solid oxide fuel cell (RSOFC) system coupled to an electrical power grid, the system comprising an RSOFC unit, a hydrogen compression system, a hydrogen storage system, and a water supply, the RSOFC unit producing power when in the fuel cell mode and the RSOFC unit generating hydrogen when in the electrolysis mode;
determining a state of the RSOFC system based on the sensor data through a conditional logic algorithm; and
transitioning the RSOFC system between the fuel cell mode and the electrolysis mode based upon the sensor data and the system state.

2. A method in accordance with claim 1 , wherein transitioning the RSOFC system between the fuel cell mode and the electrolysis mode further comprises:
heating up the RSOFC unit;
opening fluid communication between the hydrogen storage system and the RSOFC unit; and
closing fluid communication between the hydrogen compression system and the RSOFC unit, to initiate operation of the RSOFC unit in fuel cell mode.

3. A method in accordance with claim 2 , further comprising verifying that a pressure of hydrogen in the hydrogen storage system exceeds a first minimum threshold pressure, prior to opening fluid communication between the hydrogen storage system and the RSOFC unit.

4. A method in accordance with claim 1 , wherein transitioning the RSOFC system between the fuel cell mode and the electrolysis mode further comprises:
heating up the RSOFC unit;
closing fluid communication between the hydrogen storage system and the RSOFC unit;
opening fluid communication between the hydrogen compression system and the RSOFC unit, and opening fluid communication between the hydrogen compression system and the hydrogen storage system; and
activating the water supply to provide process water to the RSOFC unit, to allow operation of the RSOFC unit in electrolysis mode.

5. A method in accordance with claim 4 , further comprising condensing water from an output stream of the RSOFC unit during operation in electrolysis mode, and recycling residual hydrogen from the output stream to an intake of the RSOFC unit.

6. A method in accordance with claim 4 , further comprising verifying that a pressure of hydrogen at an intake of the hydrogen compression system is below a minimum intake pressure threshold, prior to opening fluid communication between the hydrogen compression system and an output of the RSOFC unit.

7. A method in accordance with claim 4 , wherein activating the water supply comprises activating a deionization unit of the water supply, to modify a quality of the process water prior to providing the process water to the RSOFC unit.

8. A method in accordance with claim 4 , further comprising:
detecting a pressure at the hydrogen storage system that equals or exceeds a high pressure threshold;
closing fluid communication between the hydrogen compression system and the RSOFC unit; and
opening an RSOFC system vent to vent hydrogen while the RSOFC unit operates in electrolysis mode.

9. A method in accordance with claim 1 , wherein transitioning the RSOFC system between the fuel cell mode and the electrolysis mode further comprises:
detecting a power supply or power demand condition of the electrical power grid;
transitioning to the fuel cell mode when a power demand condition is indicated; and
transitioning to the electrolysis mode when an excess power supply condition is indicated.

10. A method in accordance with claim 1 , wherein determining a state of the RSOFC system further comprises:
detecting an error condition of the RSOFC system; and
initiating a shutdown of the RSOFC system.

11. A method for controlling a system having a Reversible Solid Oxide Fuel Cell (RSOFC) unit coupled to an electrical power grid, the method comprising:
maintaining a heated state of an RSOFC unit coupled to an electrical power grid;
transitioning to an electrolysis mode of the RSOFC unit based upon sensor data indicating that the electrical power grid has excess power and that a hydrogen storage system associated with the RSOFC unit has unused capacity; and
transitioning to a fuel cell mode of the RSOFC unit based upon sensor data indicating that the electrical power grid presents power demand and the hydrogen compression and storage system has sufficient hydrogen fuel.

12. A method in accordance with claim 11 , further comprising verifying that a pressure of hydrogen in the hydrogen storage system exceeds a first minimum threshold pressure while operating in fuel cell mode.

13. A method in accordance with claim 11 , further comprising verifying that a pressure of hydrogen at an intake of a compressor associated with the hydrogen storage system is below a minimum intake pressure threshold while operating in electrolysis mode.

14. A method in accordance with claim 11 , further comprising:
detecting a pressure at the hydrogen storage system that equals or exceeds a high pressure threshold;
closing fluid communication between a compressor associated with the hydrogen storage system and the RSOFC unit; and
venting hydrogen while the RSOFC unit operates in electrolysis mode.

15. A method in accordance with claim 11 , further comprising:
detecting an error condition of the RSOFC system; and
initiating a shutdown of the RSOFC system.

16. A Reversible Solid Oxide Fuel Cell (RSOFC) system, comprising:
a hydrogen fuel source, having elevated pressure;
a water source;
a hydrogen compressor, coupled to the hydrogen fuel source;
an RSOFC unit, having a fuel cell mode and an electrolysis mode, coupled to the hydrogen fuel source, the water source, the hydrogen compressor, and to an electrical power grid; and
a controller, coupled to the RSOFC unit, the hydrogen fuel source, the water source, the hydrogen compressor, and to the electrical power grid, the controller configured to
receive sensor data regarding the hydrogen fuel source, the water source, the hydrogen compressor, and the electrical power grid;
determine a state of the RSOFC system using a conditional logic algorithm; and
switch the RSOFC unit between the fuel cell mode and the electrolysis mode depending upon the state of the RSOFC system and a power surplus or power demand condition of the power grid.

17. A system in accordance with claim 16 , further comprising a vent, controlled by the controller, configured to open to vent hydrogen gas without shutting down the RSOFC unit.

18. A system in accordance with claim 17 , wherein the controller is configured to open the vent in response to a pressure condition of the hydrogen gas and an operating condition of the RSOFC unit.

19. A system in accordance with claim 16 , wherein the water source comprises a supply of deionized water, disposed in a closed loop with the RSOFC unit, whereby water from the water supply is provided to the RSOFC unit when in electrolysis mode, and water is recovered from the RSOFC unit when in fuel cell mode.

20. A system in accordance with claim 16 , further comprising a water conditioning unit, configured to deionize input water to the system.

Assignees

• Boeing Co

Inventors

• Mermelstein Joshua M
• Espinoza Sergio

Classifications

• H01M8/04955

  Shut-off or shut-down of fuel cells · CPC title

• H01M2008/1293

  Fuel cells with solid oxide electrolytes · CPC title

• H01M8/04604

  Power, energy, capacity or load · CPC title

• H01M8/186

  by electrolytic decomposition of the electrolytic solution or the formed water product · CPC title

• Y02E60/528

  Cross-Sectional Technologies · mapped topic