Lubricating oil composition for internal combustion engines of passenger and commercial four-wheeled vehicles

Patent metadata

Field	Value
Publication number	US-9834736-B2
Application number	US-201615183062-A
Country	US
Kind code	B2
Filing date	Jun 15, 2016
Priority date	Dec 16, 2013
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

A lubricating oil composition for internal combustion engines of passenger and commercial four-wheeled vehicles is provided which can exhibit excellent fuel efficiency performance and wear resistance reliability. The lubricating oil composition includes a base oil and a complex polyester mixture. The base oil includes at least one of poly-α-olefin, an ester-based base oil, or a partially hydrogenated mineral oil. The complex polyester mixture includes a polyester obtained by condensing a polyhydric alcohol, a polycarboxylic acid, and a monohydric alcohol having an oxyalkylene group. The content of the complex polyester mixture is 0.01% by mass or more with respect to the total mass of the lubricating oil composition, the high-temperature shear viscosity (HTHS viscosity) at 150° C. is 1.0 mPa·s to 2.6 mPa·s, and the NOACK evaporation amount is 40% or less.

First claim

What is claimed is:

1. A lubricating oil composition for internal combustion engines of passenger and commercial four-wheeled vehicles comprising:
a base oil; and
a complex polyester mixture,
wherein the base oil includes at least one of poly-α-olefin, an ester-based base oil, or a partially hydrogenated mineral oil,
the complex polyester mixture includes a polyester obtained by condensing a polyhydric alcohol having at least two hydroxyl groups, a polycarboxylic acid including at least two carboxyl groups, and a monohydric alcohol having at least one oxyalkylene group,
the content of the complex polyester mixture is 0.01% by mass to 2.5% by mass with respect to the total mass of the lubricating oil composition for internal combustion engines,
the HTHS viscosity of the lubricating oil composition for internal combustion engines, which is high-temperature shear viscosity at 150° C., is 1.0 mPa·s to 2.6 mPa·s,
the NOACK evaporation amount is 40% or less, and
the monohydric alcohol is represented by the following Formula (1-1):

wherein, in the Formula (1-1), x represents an integer of 4 to 9, y represents an integer of 2 to 9, z represents 2 or 3, p represents 1 or 2, and in the case in which p is 2 or greater, p-(OC z H 2z )-s may be the same or different from each other.

2. The lubricating oil composition for internal combustion engines according to claim 1 ,
wherein the number of carbon atoms in the polycarboxylic acid is 7 or more.

3. The lubricating oil composition for internal combustion engines according to claim 1 ,
wherein the polyhydric alcohol includes three or more hydroxyl groups.

4. The lubricating oil composition for internal combustion engines according to claim 1 ,
wherein the polyhydric alcohol is selected from pentaerythritol, trimethylolpropane, glycerin and dipentaerythritol.

5. The lubricating oil composition for internal combustion engines according to claim 1 ,
wherein the number of carbon atoms in the polycarboxylic acid is 24 to 54.

6. The lubricating oil composition for internal combustion engines according to claim 1 ,
wherein the polyester is obtained by mixing the polycarboxylic acid, the polyhydric alcohol, and the monohydric alcohol such that the molar ratio of the polycarboxylic acid is 1 to 5 and the molar ratio of the monohydric alcohol is 0.5 to 5 with respect to the polyhydric alcohol and condensing the mixture.

7. The lubricating oil composition for internal combustion engines according to claim 1 ,
wherein the polyester is obtained by mixing the polycarboxylic acid, the polyhydric alcohol, and the monohydric alcohol such that the molar ratio of the polycarboxylic acid is 2.2 to 5 and the molar ratio of the monohydric alcohol is 2.5 to 5 with respect to the polyhydric alcohol and condensing the mixture.

8. The lubricating oil composition for internal combustion engines according to claim 1 , further comprising:
an organic metal compound,
wherein the content of the organic metal compound is 0.001% by mass to 0.4% by mass with respect to the lubricating oil composition for internal combustion engines.

9. The lubricating oil composition for internal combustion engines according to claim 1 , wherein the base oil includes at least a partially hydrogenated mineral oil.

10. The lubricating oil composition for internal combustion engines according to claim 1 , further comprising an organic metal compound.

11. The lubricating oil composition for internal combustion engines according to claim 10 , wherein the organic metal compound is at least one selected from organic molybdenum compounds and organic zinc compounds.

12. The lubricating oil composition for internal combustion engines according to claim 10 , wherein the organic metal compound includes organic molybdenum compounds and organic zinc compounds.

Assignees

• Fujifilm Corp
• Toyota Motor Co Ltd

Inventors

• Fujiwara Toshiki
• Suzuki Hiroyuki
• Watanabe Saisuke
• Fukutomi Ippei
• Murakami Motoichi
• Suzuki Tetsushi

Classifications

• C10M2209/11

  Complex polyesters · CPC title

• C10M2209/111

  having dicarboxylic acid centres · CPC title

• C10N2030/54

  Fuel economy · CPC title

• C10N2020/02

  Viscosity; Viscosity index · CPC title

• C10M2219/068

  Thiocarbamate metal salts · CPC title