Method for producing polyacetal resin composition

Patent metadata

Field	Value
Publication number	US-9834669-B1
Application number	US-201515538008-A
Country	US
Kind code	B1
Filing date	Nov 9, 2015
Priority date	Feb 6, 2015
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

A polyacetal resin composition which is suppressed low in formaldehyde generation, while having high stiffness and high toughness. The resin is produced by a method including blending from 0.1 part by weight to 2 parts by weight (inclusive) of a polyacetal copolymer having a branched or crosslinked structure, which is a copolymer of a trioxane, a compound having from 3 to 4 (inclusive) cyclic ether units in each molecule and a compound having one cyclic ether unit in each molecule, per 100 parts by weight of a linear polyacetal copolymer which contains an oxymethylene unit as a main constituent, while containing, as a comonomer unit, an oxyalkylene unit at a ratio of from 0.4% by mole to 0.9% by mole (inclusive) relative to the constituents of the linear polyacetal copolymer, the linear polyacetal copolymer being obtained by copolymerization wherein a heteropolyacid or the like is used as a polymerization catalyst.

First claim

The invention claimed is:

1. A method for producing a polyacetal resin composition comprising a step of blending, with respect to 100 parts by weight of (A) a linear polyacetal copolymer comprising an oxymethylene unit as a main constituent component and an oxyalkylene unit as a comonomer in a percentage of from 0.4 mol % to 0.9 mol % of the constituent units of the linear polyacetal copolymer, and produced with at least one selected from a heteropoly acid, an isopoly acid, or an acid salt thereof as a polymerization catalyst;
from 0.1 parts by weight to 2 parts by weight of (B) a polyacetal copolymer having a branched or crosslinked structure which is a copolymer of (b1) trioxane, (b2) a compound having from 3 to 4 cyclic ether units in each molecule, and (b3) compound having one cyclic ether unit in each molecule.

2. A method for producing a polyacetal resin composition according to claim 1 , wherein in a catalyst quenching when producing the (A) linear polyacetal copolymer, a melt kneading treatment is carried out using a carbonate, bicarbonate, or carboxylate of an alkali metal element as a quenching agent.

Assignees

• Polyplastics Co

Inventors

• Horiguchi Tadahiro
• Shimoda Akihide

Classifications

• C08L2205/025

  containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

• C08L59/04 Primary

  Copolyoxymethylenes · CPC title

• C08G2/20 Primary

  with other aldehydes or ketones · CPC title