Process for the production of water and solvent-free polymers

Patent metadata

Field	Value
Publication number	US-9834618-B2
Application number	US-201514603482-A
Country	US
Kind code	B2
Filing date	Jan 23, 2015
Priority date	Mar 24, 2010
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

The present invention relates to water and solvent-free polymers, in particular water and solvent-free synthetic rubber products like non-halogenated and halogenated butyl rubber products as well as a process for the production thereof. The invention further relates to a device suitable to accomplish said process.

First claim

What is claimed is:

1. A process of removing volatile compounds from a concentrated fluid containing at least one non-volatile polymer and at least one volatile compound, the process comprising:
feeding a concentrated fluid comprising 10 wt % to 80 wt % of at least one synthetic rubber and 20 wt % to 90 wt % of at least one volatile compound into at least one drying unit, wherein:
the at least one synthetic rubber and the at least one volatile compound comprise up to 90% to 100% of the total mass of the concentrated fluid, and
the drying unit comprises, in a flow direction:
I) a first drying section, and
II) a main extruder section comprising:
an extruder degassing section comprising a conveying section and a vent port with one or more vapor lines, and
an accumulating section and an outlet section,

whereby
the first drying section is a first extruder, and the main extruder section is a main extruder, wherein the main extruder has a larger cross sectional area than the first extruder;

removing the at least one volatile compound via the vent ports and vapor lines to dry the concentrated fluid and obtain, at the outlet section of the main extruder, a product substantially free of volatile compounds.

2. The process pursuant to claim 1 , wherein the at least one synthetic rubber is at least one halogenated butyl rubber.

3. The process pursuant to claim 1 , further comprising:
producing the concentrated fluid from a fluid F that contains from 3 to 50 wt % of the synthetic rubber and from 60 to 97 wt % of the volatile compounds, whereby the aforementioned components add up to 90 to 100 of the total mass of the fluid F, and
producing the concentrated fluid from the Fluid F by heating the fluid F and degassing the fluid F.

4. The process pursuant to claim 1 , wherein the vent ports comprise stuffer screws.

5. The process pursuant to claim 1 , further comprising adjusting the main extruder to have a dimensionless throughput V/(n*d 3 ) of 0.01 to 0.7.

6. The process pursuant to claim 1 , wherein the vent ports are configured for preventing concentrated fluid from coming out of the vent ports.

7. The process pursuant to claim 1 , further comprising adding a stripping agent to the concentrated fluid.

8. The process pursuant to claim 1 , wherein the outlet section comprises an underwater processing device.

9. A process of removing volatile compounds from a concentrated fluid containing at least one non-volatile polymer and at least one volatile compound, the process comprising:
preparing a concentrated fluid by a process comprising:
A) treating a fluid F comprising volatile compounds in at least one concentrator unit comprising at least a heater, a degassing vessel and a vapor line, the treating comprising heating the fluid F in the heater, feeding the heated fluid into the degassing vessel, and removing at least a portion of the volatile compounds via the vapor line to obtain a fluid H, and
B) reheating the fluid H from step A) in at least one reheating unit to obtain a concentrated fluid comprising 10 wt % to 80 wt % of at least one synthetic rubber and 20 wt % to 90 wt % of at least one volatile compound;

feeding the concentrated fluid into at least one drying unit, wherein:
the at least one synthetic rubber and the at least one volatile compound comprise up to 90% to 100% of the total mass of the concentrated fluid, and
the drying unit comprises, in a flow direction:
I) a first drying section, and
II) a main extruder section comprising:
an extruder degassing section comprising a conveying section and a vent port with one or more vapor lines,
an accumulating section, and
an outlet section,

whereby
the first drying section is either a kneader or a first extruder, and the main extruder section is a main extruder;

removing the at least one volatile compound via the vent ports and vapor lines to dry the concentrated fluid and obtain, at the outlet section of the main extruder, a product substantially free of volatile compounds.

10. The process pursuant to claim 9 , further comprising preparing the fluid F by a process comprising:
treating a crude fluid A in at least one pre-washing unit comprising at least a separating apparatus, wherein the treating comprises mixing the crude fluid A with water to obtain an organic phase comprising primarily non-volatile polymer and volatile organic compounds, and an aqueous phase comprising primarily water and hydrophilic compounds,
separating the organic phase from the aqueous phase in the separating apparatus,
using the organic phase as fluid F, and
removing at least a part of the aqueous phase from the separating apparatus.

11. The process pursuant to claim 10 , further comprising preparing the crude fluid A by a process comprising:
I) providing a reaction medium comprising
a common aliphatic medium comprising at least 50 wt.-% of one or more aliphatic hydrocarbons having a boiling point in the range of 45° C. to 80° C. at a pressure of 1013 hPa, and
a monomer mixture comprising at least one monoolefin monomer, at least one multiolefin monomer and either no or at least one other co-polymerizable monomer in a mass ratio of monomer mixture to common aliphatic medium of from 40:60 to 95:5;

II) polymerizing the monomer mixture within the reaction medium to form a rubber solution comprising a rubber polymer which is at least substantially dissolved in the medium comprising the common aliphatic medium and residual monomers of the monomer mixture;
III) separating residual monomers of the monomer mixture from the rubber solution to form a separated rubber solution comprising the rubber polymer and the common aliphatic medium, and
IV) halogenating the rubber polymer in the separated rubber solution to obtain the crude fluid A, a solution comprising halogenated rubber, and the common aliphatic medium.

12. The process pursuant to claim 11 , wherein:
the halogenating comprises halogenating the rubber polymer using a bromination agent, and
after use of the bromination agent, the process further comprises at least partially reoxidizing the bromination agent using an oxidizing agent.

13. The process pursuant to claim 9 , further comprising preparing the concentrated fluid by a process comprising:
treating a crude fluid A comprising non-volatile polymer, volatile organic compounds and hydrophilic compounds in at least one pre-washing unit comprising at least a separating apparatus, wherein the treating comprises mixing the crude fluid A with water to obtain an organic phase comprising primarily the non-volatile polymer and the volatile organic compounds, and an aqueous phase comprising primarily water and the hydrophilic compounds,
separating the organic phase from the aqueous phase in the separating apparatus,
using the organic phase as the concentrated fluid, and
removing at least a part of the aqueous phase from the separating apparatus.

14. A process of removing volatile compounds from a concentrated fluid containing at least one non-volatile polymer and at least one volatile compound, the process comprising:
heating a fluid F that contains 3 to 50 wt % synthetic rubber and 60 to 97 wt % volatile compounds, whereby the aforementioned components add up to 90 to 100% of the total mass of the fluid F;
degassing the fluid F to produce a concentrated fluid comprising 10 wt % to 80 wt % of at least one synthetic rubber and 20 wt % to 90 wt % of at least one volatile compound;
feeding the concentrated fluid into at least one drying unit, wherein:
the at least one synthetic rubber and the at least one volatile compound comprise up to 90% to 100% of the total m

Assignees

• Lanxess Int Sa
• Arlanxeo Deutschland Gmbh

Inventors

• Kirchhoff Jorg
• Backer Werner
• Feller Rolf
• Wagner Paul
• Paul Hanns-Ingolf
• Lovegrove John

Classifications

• B29C48/44

  Planetary screws · CPC title

• B29C48/365

  using pumps, e.g. piston pumps · CPC title

• B29C48/41

  Intermeshing counter-rotating screws · CPC title

• B29C48/405

  Intermeshing co-rotating screws · CPC title

• B29C48/40

  using two or more parallel screws {or at least two parallel non-intermeshing screws}, e.g. twin screw extruders · CPC title