Methods and apparatuses for hydrocarbon production

Patent metadata

Field	Value
Publication number	US-9834494-B2
Application number	US-201414499663-A
Country	US
Kind code	B2
Filing date	Sep 29, 2014
Priority date	Sep 29, 2014
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

Methods and apparatuses are provided for producing hydrocarbons. A method for producing hydrocarbons may include two or more reactors having a distributed aromatic rich feed and hydrogen system. Using this configuration, the aromatic rich feed and hydrogen streams are split equally to all reactors wherein each reactor contains a catalyst. The outlet from the last reactor may include a recycle that may be injected into the inlet of the first reactor.

First claim

The invention claimed is:

1. A method of producing hydrocarbon compounds comprising:
splitting an aromatic rich feed into a first aromatic rich feed stream comprising diolefins and a second aromatic rich feed stream comprising diolefins;
feeding the first aromatic rich feed stream comprising diolefins, a first hydrogen rich stream, and a recycle stream to a first reaction zone comprising a first catalyst to form a first effluent stream comprising mono-olefins, wherein the recycle stream is cooled; and
feeding the second aromatic rich feed stream comprising diolefins, a second hydrogen rich stream, and first effluent stream, wherein the first effluent stream is cooled and sent to a second reaction zone comprising a second catalyst to form a second effluent comprising mono-olefins wherein a portion of the second effluent stream may be recycled to the first reaction zone, the second reaction zone, or both the first reaction zone and the second reaction zone, the first and second reaction zones having an inlet temperature of about 40° C. to about 60° C. and an outlet temperature is about 120° C. to about 150° C., wherein the first reaction zone and the second reaction zone comprise independent temperature control.

2. The method of claim 1 wherein the first reaction zone and the second reaction zone are connected in series.

3. The method of claim 1 wherein the first reaction zone and the second reaction zone may include multiple reactors.

4. The method of claim 1 wherein the first aromatic rich feed stream, the first hydrogen stream, and the recycle stream are admixed before being fed to the first reaction zone and the second aromatic rich feed stream, the second hydrogen stream, and the first effluent stream are admixed before being fed to the second reaction zone.

5. The method of claim 1 wherein the flow rate of the first hydrogen stream and the second hydrogen stream may be controlled independently.

6. The method of claim 1 , wherein at least a portion of the first aromatic rich feed stream and at least a portion of the second aromatic rich feed stream are drawn from a common aromatic rich feed stream.

7. The method of claim 1 , further comprising feeding a third aromatic rich feed stream comprising diolefins, a third hydrogen rich stream, and a second effluent stream to a third reaction zone comprising a third catalyst to form a third reaction zone effluent stream comprising mono-olefins.

8. The method of claim 1 wherein the first catalyst comprises a metal from group 10 of the periodic table, and wherein the first catalyst further comprises a support selected from one or more of aluminum oxide, silicon oxide, titanium oxide, and zirconium oxide.

9. The method of claim 1 wherein the first catalyst and the second catalyst comprise palladium on an aluminum oxide support.

10. The method of claim 1 wherein the first catalyst and the second catalyst comprise nickel on an aluminum oxide support.

11. The method of claim 1 wherein the second catalyst comprises a metal from group 10 of the periodic table, and wherein the second catalyst further comprises a support selected from one or more of aluminum oxide, silicon oxide, titanium oxide, and zirconium oxide.

Assignees

• Uop Llc

Inventors

• Luebke Charles P
• Dziabala Bart
• Demirel Belma

Classifications

• C07C2523/44

  Palladium · CPC title

• C07C7/163

  by hydrogenation · CPC title

• B01J2219/0004

  Processes in series · CPC title

• B01J2219/00038

  Processes in parallel · CPC title

• C07C2523/755

  Nickel · CPC title