Process for fluid catalytic cracking oligomerate

Patent metadata

Field	Value
Publication number	US-9834492-B2
Application number	US-201314074739-A
Country	US
Kind code	B2
Filing date	Nov 8, 2013
Priority date	Nov 12, 2012
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

Distillate cracks to propylene more readily than VGO. Additionally, less branched hydrocarbons crack to propylene more readily than more branched hydrocarbons. Oligomerization to diesel range oligomers followed by catalytic cracking with less branched oligomers can provide more propylene.

First claim

The invention claimed is:

1. A process for making propylene comprising:
cracking a hydrocarbon feed stream and a distillate recycle stream comprising distillate hydrocarbons over an FCC catalyst in an FCC zone to produce a cracked product stream;
recovering a propylene product stream from said cracked product stream;
obtaining an oligomerization feed stream comprising C 4 olefins and between 15 to 70 wt % C 5 olefins from said cracked product stream;
passing said oligomerization feed stream to an oligomerization zone to oligomerize said oligomerization feed stream over a zeolite catalyst having a uni-dimensional 10-membered ring pore structure to produce an oligomerate stream comprising less than about 80 wt % C 9+ hydrocarbons;
separating said oligomerate stream in a distillate separator, having an overhead pressure of between about 10 and about 60 kPa (gauge) and a bottom temperature of between about 225° C. and about 275° C. to provide a gasoline stream and said distillate recycle stream comprising distillate hydrocarbons; and
wherein said distillate recycle stream has a boiling point of between about 200° C. and about 400° C.

2. The process of claim 1 , wherein said zeolite catalyst has an MTT pore structure.

3. The process of claim 1 wherein a maximum temperature of a bed of said zeolite catalyst is between about 200 and about 250° C.

4. The process of claim 1 wherein a portion of said C 4 olefins oligomerize with a portion of said C 5 olefins in said oligomerization zone.

5. The process of claim 1 wherein said distillate recycle stream and said hydrocarbon feed stream are cracked in a riser in the FCC zone.

6. The process of claim 1 further comprising obtaining an intermediate stream comprising C 5 hydrocarbons from said oligomerate stream in a recovery zone and purging a portion of said intermediate stream as a purge stream and recycling a portion of said intermediate stream as a C 5 recycle stream to said oligomerization zone.

7. The process of claim 1 further comprising sending said gasoline stream to a gasoline tank or a gasoline blending line.

8. A process for making propylene comprising:
cracking a hydrocarbon feed stream and a distillate recycle stream comprising distillate hydrocarbons over an FCC catalyst in an FCC zone to produce spent FCC catalyst and a cracked product stream;
regenerating said spent FCC catalyst;
recovering a propylene product stream from said cracked product stream;
obtaining an oligomerization feed stream comprising C 4 olefins from said cracked product stream;
passing said oligomerization feed stream to an oligomerization zone to oligomerize C 4 olefins in said oligomerization feed stream over a zeolite catalyst having a uni-dimensional 10-membered ring pore structure to produce an oligomerate stream comprising C 8+ olefins;
separating said oligomerate stream in a distillate separator having an overhead pressure of between about 10 and about 60 kPa (gauge) and a bottom temperature of between about 225° C. and about 275° C. to provide a gasoline stream and said distillate recycle stream comprising distillate hydrocarbons;
wherein said distillate recycle stream has a boiling point of between about 200° C. and about 400° C.; and
wherein said zeolite catalyst is an MTT.

9. The process of claim 8 wherein the oligomerization feed stream also comprises C 5 olefins and wherein a portion of said C 4 olefins oligomerize with a portion of said C 5 olefins in said oligomerization zone.

10. The process of claim 8 wherein said distillate recycle stream comprises C 12 olefins.

11. The process of claim 8 wherein said distillate recycle stream and said hydrocarbon feed stream are cracked in a riser in the FCC zone.

12. The process of claim 8 further comprising sending said gasoline stream to a gasoline tank or a gasoline blending line.

13. A process for making propylene comprising:
cracking a hydrocarbon feed stream and a distillate recycle stream comprising distillate hydrocarbons over an FCC catalyst in an FCC zone to produce spent FCC catalyst and a cracked product stream;
regenerating said spent FCC catalyst;
recovering a propylene product stream from said cracked product stream;
obtaining an oligomerization feed stream comprising C 4 olefins from said cracked product stream;
passing said oligomerization feed stream to an oligomerization zone to oligomerize C 4 olefins in said oligomerization feed stream to produce an oligomerate stream comprising greater than 30 wt % C 9+ olefins;
separating the oligomerate stream in a distillate separator having an overhead pressure of between about 10 and about 60 kPa (gauge) and a bottom temperature of between about 225° C. and about 275° C. to provide a gasoline stream and said distillate recycle stream comprising distillate hydrocarbons;
recycling a portion of the gasoline stream to the oligomerization zone; and
wherein said distillate recycle stream consists essentially of C 11+ olefins and has a boiling point of between about 200° C. and about 400° C.

14. The process of claim 13 further comprising oligomerizing said C 4 olefins over an MTT zeolite.

15. The process of claim 13 wherein said distillate recycle stream and said hydrocarbon feed stream are cracked in a riser in the FCC zone.

Assignees

• Uop Llc

Inventors

• Nicholas Christopher P
• Freet Christian D
• Vanden Bussche Kurt M
• Kruse Todd M

Classifications

• C07C2/12 Primary

  with crystalline alumino-silicates {or with catalysts comprising} molecular sieves · CPC title

• C10G11/05

  Crystalline alumino-silicates, e.g. molecular sieves · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title

• C10G11/18

  according to the "fluidised-bed" technique · CPC title

• C10G57/02

  with polymerisation · CPC title