Optical glass and method for producing the same

Patent metadata

Field	Value
Publication number	US-9834465-B2
Application number	US-201414917841-A
Country	US
Kind code	B2
Filing date	Sep 26, 2014
Priority date	Sep 30, 2013
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

An optical glass may be a phosphate based glass containing at least any one of oxides selected from TiO2, Nb2O5, WO3, and Bi2O2. The total content (HR) of the TiO2, Nb2O5, WO3, and Bi2O2 may be 35 mol % or above, the noble metal content may be less than 2.0 ppm, and the βOH value, given by the following general formula, may be 0.1 mm-1 or above: βOH=−[ln(B/A)]/t.

First claim

What is claimed is:

1. An optical glass that is a phosphate-based glass containing at least one oxide selected from the group consisting of TiO 2 , Nb 2 O 5 , WO 3 and Bi 2 O 3 ,
wherein a total content (HR) of the TiO 2 , Nb 2 O 5 , WO 3 and Bi 2 O 3 is 35 mol % or more, a content of noble metal is less than 2.0 ppm, and a value of βOH represented by the following equation (1) is 0.1 mm −1 or more:
βOH=−[ln( B/A )]/ t   (1),

wherein in the equation (1), t denotes a thickness (mm) of the glass used for a measurement of an external transmittance, A denotes the external transmittance (%) at a wavelength of 2500 nm when a light enters into said glass in parallel to a thickness direction thereof, B denotes the external transmittance (%) at the wavelength of 2900 nm when a light enters into said glass in parallel to the thickness direction thereof, and ln is a natural logarithm.

2. A method for producing an optical glass,
wherein the method has a melting process that obtains a molten glass by heating and melting a glass raw material containing phosphorus and a glass raw material containing at least one component selected from the group consisting of TiO 2 , Nb 2 O 5 , WO 3 and Bi 2 O 3 , in a melting vessel made of noble metal,
a total content (HR) of the TiO 2 , Nb 2 O 5 , WO 3 and Bi 2 O 3 in the glass raw materials is 35 mol % or more, and
at least one of a treatment (ia) of adding water vapor to a melting atmosphere and a treatment (ib) of bubbling water vapor in a melting product is carried out in the melting process.

3. The method according to claim 2 , wherein a non-oxidizing gas is supplied together with the water vapor in either or both of the treatment (ia) and the treatment (ib).

4. The method according to claim 3 , wherein the non-oxidizing gas comprises at least one selected from the group consisting of argon, nitrogen, carbon monoxide, carbon dioxide, hydrogen, helium and iodine.

5. The method according to claim 3 , wherein a ratio occupied by the water vapor in the gas being supplied is 3 volume % or more and less than 100 volume %, and a ratio occupied by the non-oxidizing gas in the gas being supplied is more than 0 volume % and 97 volume % or less.

6. The method according to claim 2 , wherein the optical glass is a phosphate-based glass.

7. The method according to claim 2 , further comprising:
thermally treating the optical glass under an oxidizing atmosphere.

Assignees

• Hoya Corp

Inventors

• Mikami Shuhei

Classifications

• Y02P40/57

  Improving the yield, e-g- reduction of reject rates · CPC title

• C03C3/064

  containing boron · CPC title

• C03C3/21 Primary

  containing titanium, zirconium, vanadium, tungsten or molybdenum · CPC title

• C03C3/16

  containing phosphorus · CPC title

• C03B5/167

  Means for preventing damage to equipment, e.g. by molten glass, hot gases, batches (C03B5/20, C03B5/42 take precedence) · CPC title