Facilitated CO2 transport membrane, method for producing same, resin composition for use in method for producing same, CO2 separation module and method and apparatus for separating CO2

Patent metadata

Field	Value
Publication number	US-9833746-B2
Application number	US-201414780965-A
Country	US
Kind code	B2
Filing date	Mar 24, 2014
Priority date	Mar 29, 2013
Publication date	Dec 5, 2017
Grant date	Dec 5, 2017

Abstract

Provided is a facilitated CO 2 transport membrane having improved CO 2 permeance and improved CO 2 selective permeability. The facilitated CO 2 transport membrane includes a separation-functional membrane comprising a hydrophilic polymer gel membrane which contains a CO 2 carrier and a CO 2 hydration catalyst, wherein the hydrophilic polymer is a copolymer including a first structural unit derived from an acrylic acid cesium salt or an acrylic acid rubidium salt and a second structural unit derived from vinyl alcohol. More preferably, the CO 2 hydration catalyst has catalytic activity at a temperature of 100° C. or higher.

First claim

The invention claimed is:

1. A facilitated CO 2 transport member comprising:
a separation-functional membrane, the membrane being a gel membrane of a hydrophilic polymer, the hydrophilic polymer comprising a CO 2 carrier and a CO 2 hydration catalyst, wherein
the hydrophilic polymer is a copolymer comprising a first structural unit represented by Chemical Formula (1) shown below, where M represents cesium or rubidium, and a second structural unit represented by Chemical Formula (2) shown below, wherein
the copolymer comprises a third structural unit selected from a group consisting of a structural unit derived from a methacrylic acid alkyl ester having an alkyl group of 1 to 16 carbon atoms, a structural unit derived from a maleic acid dialkyl ester having an alkyl group of 1 to 16 carbon atoms, a structural unit derived from a fumaric acid dialkyl ester having an alkyl group of 1 to 16 carbon atoms, and a structural unit derived from an itaconic acid dialkyl ester having an alkyl group of 1 to 16 carbon atoms, and wherein
the CO 2 hydration catalyst has catalytic activity at a temperature of 100° C. or higher and a melting point of 200° C. or higher

2. The facilitated CO 2 transport member according to claim 1 , wherein the CO 2 hydration catalyst is soluble in water.

3. The facilitated CO 2 transport member according to claim 1 , wherein the CO 2 hydration catalyst comprises at least one of a tellurous acid compound, a selenious acid compound, an arsenious acid compound, and an orthosilicic acid compound.

4. The facilitated CO 2 transport member according to claim 1 , wherein a content of the second structural unit in the hydrophilic polymer is from 1 mol % to 90 mol % with respect to the total content of the first and second structural units.

5. The facilitated CO 2 transport member according to claim 1 , wherein the CO 2 carrier comprises at least one of an alkali metal carbonate, an alkali metal bicarbonate, and an alkali metal hydroxide.

6. The facilitated CO 2 transport member according to claim 5 , wherein an alkali metal included in one of the alkali metal carbonate, the alkali metal bicarbonate, and the alkali metal hydroxide is cesium or rubidium.

7. The facilitated CO 2 transport member according to claim 1 , further comprising a hydrophilic porous membrane, wherein the separation-functional membrane is supported by the hydrophilic porous membrane.

8. A method for producing the facilitated CO 2 transport member according to claim 1 , the method comprising the steps of:
coating a porous membrane with a coating liquid in which the hydrophilic polymer, the CO 2 carrier, the CO 2 hydration catalyst, and a medium containing water are included; and
removing the medium from a resultant coating to produce the separation-functional membrane in the form of a gel.

9. A CO 2 separating method comprising the steps of:
supplying a CO 2 -containing mixed gas to the facilitated CO 2 transport member according to claim 1 ; and
separating from the mixed gas the CO 2 having permeated the facilitated CO 2 transport member.

10. A CO 2 separation membrane module comprising the facilitated CO 2 transport member according to claim 1 .

11. A CO 2 separation apparatus comprising:
the facilitated CO 2 transport member according to claim 1 ;
a first feeding port, a second feeding port, a first discharge port, and a second discharge port, wherein:
the first feeding port is configured to feed a gas from a source of gas, including a CO 2 -containing mixed gas, into a supply side of the facilitated CO 2 transport member;
the second feeding port is configured to feed a sweep gas into a permeate side of the facilitated CO 2 transport member;
the first discharge port is configured to discharge a CO 2 -separated source gas from the supply side of the facilitated CO 2 transport member; and
the second discharge port is configured to discharge a CO 2 -containing permeate gas from the permeate side of the facilitated CO 2 transport member.

12. A resin composition comprising:
a CO 2 carrier;
a CO 2 hydration catalyst; and
a copolymer comprising a first structural unit represented by Chemical Formula (1) shown below, where M represents cesium or rubidium, and a second structural unit represented by Chemical Formula (2) shown below, wherein
the copolymer comprises a third structural unit selected from a group consisting of a structural unit derived from a methacrylic acid alkyl ester having an alkyl group of 1 to 16 carbon atoms, a structural unit derived from a maleic acid dialkyl ester having an alkyl group of 1 to 16 carbon atoms, a structural unit derived from a fumaric acid dialkyl ester having an alkyl group of 1 to 16 carbon atoms, and a structural unit derived from an itaconic acid dialkyl ester having an alkyl group of 1 to 16 carbon atoms, and wherein
the CO 2 hydration catalyst has catalytic activity at a temperature of 100° C. or higher and a melting point of 200° C. or higher

13. The resin composition according to claim 12 , wherein the CO 2 hydration catalyst is soluble in water.

14. The resin composition according to claim 12 , wherein the CO 2 hydration catalyst comprises an oxo acid compound.

15. The resin composition according to claim 12 , wherein the CO 2 hydration catalyst comprises at least one of a tellurous acid compound, a selenious acid compound, an arsenious acid compound, and an orthosilicic acid compound.

16. The resin composition according to claim 12 , wherein a content of the second structural unit is from 1 mol % to 90 mol % with respect to the total content of the first and second structural units.

17. The resin composition according to claim 12 , wherein the CO 2 carrier comprises at least one of an alkali metal carbonate, an alkali metal bicarbonate, and an alkali metal hydroxide.

18. The resin composition according to claim 17 , wherein an alkali metal included in one of the alkali metal carbonate, the alkali metal bicarbonate, and the alkali metal is cesium or rubidium.

19. The resin composition according to claim 12 , wherein a content of the CO 2 carrier is from 20% by weight to 90% by weight with respect to the total weight of the CO 2 carrier and the copolymer.

20. The resin composition according to claim 12 , wherein the number of moles of the CO 2 hydration catalyst is at least 0.02 times the number of moles of the CO 2 carrier.

Assignees

• Renaissance Energy Res Corp
• Sumimoto Chemical Company Ltd
• Sumitomo Chemical Co

Inventors

• Okada Osamu
• Hanai Nobuaki
• Yan Peng
• Miyata Junya
• Nakasuji Takehiro
• Sugiyama Hayato

Classifications

• C08F230/00

  Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal · CPC title

• B01D69/145 Primary

  containing embedded catalysts · CPC title

• B01D53/228

  characterised by specific membranes · CPC title

• B01D61/38

  Liquid-membrane separation · CPC title

• B01D69/142

  with "carriers" · CPC title