Resin composition, prepreg, metal foil-clad laminate and printed wiring board

Patent metadata

Field	Value
Publication number	US-9832870-B2
Application number	US-201314407190-A
Country	US
Kind code	B2
Filing date	Jun 6, 2013
Priority date	Jun 12, 2012
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

A resin composition capable of achieving a printed wiring board or the like excellent in heat dissipation properties, water absorption properties, copper foil peel strength, and heat resistance after moisture absorption is provided. A prepreg, a laminate, a metal foil clad laminate, a printed wiring board and the like, which use the resin composition are also provided. The resin composition of the present invention having at least an epoxy resin, a cyanate ester compound, and an inorganic filler, wherein the inorganic filler includes at least a surface-treated silicon carbide of a silicon carbide powder having at least a part of the surface treated with an inorganic oxide.

First claim

The invention claimed is:

1. A resin composition comprising an epoxy resin (A), a cyanate ester compound (B), an inorganic filler (C), wherein the inorganic filler (C) comprises a surface-treated silicon carbide (C-1) of a silicon carbide powder having the surface treated with an inorganic oxide, and a maleimide compound (D) selected from at least one or more of the group consisting of bis(4-maleimidophenyl)methane, 2,2-bis(4-(4-maleimidephenoxy)-phenyl)propane, bis(3-ethyl-5-methyl-4-maleimidophenyl)methane, and a maleimide compound represented by the following formula (4):

wherein each R independently represents a hydrogen atom or a methyl group, and n represents an integer of 1 to 10 as an average value; and
wherein the inorganic filler (C) is contained in an amount of 150 to 900 parts by mass based on a total of 100 parts by mass of resin solid components.

2. The resin composition according to claim 1 ,
wherein the inorganic oxide with which the surface of the silicon carbide is treated is at least one or more selected from the group consisting of silica, titania, alumina, and zirconium oxide.

3. The resin composition according to claim 1 ,
wherein the inorganic filler (C) further comprises at least one or more second inorganic fillers (C-2) selected from the group consisting of alumina, magnesium oxide, boron nitride, and aluminum nitride, other than the surface-treated silicon carbide (C-1).

4. The resin composition according to claim 1 ,
wherein the epoxy resin (A) is at least one or more selected from the group consisting of a biphenyl aralkyl-based epoxy resin, a polyoxynaphthylene-based epoxy resin, a triphenolmethane-based epoxy resin, a bisphenol A-based epoxy resin, a bisphenol F-based epoxy resin, a phenol novolac-based epoxy resin, a cresol novolac-based epoxy resin, a bisphenol A novolac-based epoxy resin, a brominated bisphenol A-based epoxy resin, a brominated phenol novolac-based epoxy resin, a biphenyl-based epoxy resin, a phenol aralkyl-based epoxy resin, and naphthol aralkyl-based epoxy resin.

5. The resin composition according to claim 1 ,
wherein the cyanate ester compound (B) is at least one or more selected from the group consisting of a naphthol aralkyl-based cyanate ester compound represented by the following formula (1), a novolac-based cyanate ester compound represented by the following formula (2), and a biphenyl aralkyl-based cyanate ester compound represented by the following formula (3):

wherein each R independently represents a hydrogen atom or a methyl group, and n represents an integer of 1 or more;

wherein each R independently represents a hydrogen atom or a methyl group, and n represents an integer of 0 or more;

wherein each R independently represents a hydrogen atom or a methyl group, and n represents an integer of 1 or more.

6. The resin composition according to claim 1 ,
wherein the maleimide compound (D) is present in an amount of 5 to 50 parts by mass based on a total of 100 parts by mass of the epoxy resin (A), the cyanate ester compound (B), and the maleimide compound (D).

7. The resin composition according to claim 1 ,
wherein the epoxy resin (A) is contained in an amount of 10 to 90 parts by mass based on a total of 100 parts by mass of the epoxy resin (A), the cyanate ester compound (B), and the maleimide compound (D).

8. The resin composition according to claim 1 ,
wherein the cyanate ester compound (B) is contained in an amount of 10 to 90 parts by mass based on a total of 100 parts by mass of the epoxy resin (A), the cyanate ester compound (B), and the maleimide compound (D).

9. A prepreg comprising a substrate and the resin composition according to claim 1 which the substrate is impregnated with or which is attached to the substrate.

10. A metal foil clad laminate comprising the prepreg according to claim 9 as an insulating layer, and a metal foil disposed on a single side or both sides of the prepreg.

11. A printed wiring board comprising an insulating layer and a conductive layer formed on the surface of the insulating layer, wherein the insulating layer comprises the resin composition according to claim 1 .

Assignees

• Mitsubishi Gas Chemical Co

Inventors

• Kobayashi Hiroaki
• Sogame Masanobu
• Nomizu Kentaro
• Mabuchi Yoshinori
• Kato Yoshihiro

Classifications

• C08J2363/02

  Polyglycidyl ethers of bis-phenols · CPC title

• B32B2307/306

  Resistant to heat · CPC title

• B32B2260/046

  Synthetic resin · CPC title

• B32B2307/304

  Insulating · CPC title

• Y10T442/656

  Preformed metallic film or foil or sheet [film or foil or sheet had structural integrity prior to association with the nonwoven fabric] · CPC title