Method for activating an inner surface of a substrate tube for the manufacturing of an optical-fiber preform

Patent metadata

Field	Value
Publication number	US-9831068-B2
Application number	US-201615200403-A
Country	US
Kind code	B2
Filing date	Jul 1, 2016
Priority date	Jul 13, 2015
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

A method activates the inner surface of a substrate tube via plasma etching with a fluorine-containing etching gas. An exemplary method includes the steps of (i) supplying a supply flow of gas to the interior of a substrate tube, wherein the supply flow includes a main gas flow and a fluorine-containing etching gas flow, (ii) inducing a plasma via electromagnetic radiation to create a plasma zone within the substrate tube's interior, and (iii) longitudinally reciprocating the plasma zone over the length of the substrate tube between a reversal point near the supply side and a reversal point near the discharge side of the substrate tube. The flow of the fluorine-containing etching gas is typically provided when the plasma zone is near the supply side reversal point.

First claim

The invention claimed is:

1. A method for activating an inner surface of a substrate tube for the manufacturing of an optical-fiber preform by means of plasma etching with a fluorine-containing etching gas, the plasma etching comprising the steps of:
supplying a supply flow of gas to a central cavity of a substrate tube, wherein the supply flow comprises a main gas flow and a fluorine-containing etching gas flow;
inducing a plasma by means of electromagnetic radiation in at least a part of the substrate tube to create a plasma zone in the central cavity of the substrate tube; and
moving the plasma zone back and forth in longitudinal direction over the length of the substrate tube between a reversal point located near the supply side and a reversal point located near the discharge side of the substrate tube;
wherein the flow of the fluorine-containing etching gas is provided only when the plasma zone is present between the reversal point near the supply side and a pre-determined axial position located between the reversal point near the supply side and the reversal point near the discharge side; and
wherein the pre-determined axial position located between the reversal point near the supply side and the reversal point near the discharge side is separated from the reversal point near the supply side by a length equaling between 1 and 20 percent of the total available length of the substrate tube.

2. The method according to claim 1 , wherein the pre-determined axial position located between the reversal point near the supply side and the reversal point near the discharge side is separated from the reversal point near the supply side by a length equaling between 5 and 10 percent of the total available length of the substrate tube.

3. The method according to claim 1 , wherein the predetermined axial position is the reversal point near the discharge side.

4. The method according to claim 1 , wherein the fluorine-containing etching gas comprises a fluorine-containing compound and a carrier gas.

5. The method according to claim 4 , wherein:
the fluorine-containing compound is selected from the group consisting of CCl 2 F 2 , CF 4 , C 2 F 6 , C 4 F 8 , SF 6 , F 2 , NF 3 , SO 2 F 2 , CHF 3 , CClF 3 , and CCl 3 F, or a combination thereof; and/or
the carrier gas is selected from the group consisting of oxygen (O 2 ), nitrogen (N 2 ), and argon (Ar), or a combination thereof.

6. The method according to claim 4 , wherein the fluorine-containing compound is C 2 F 6 and the carrier gas is O 2 .

7. The method according to claim 4 , wherein the fluorine-containing etching gas flow comprises the fluorine-containing compound in an amount between 100 sccm and 500 sccm.

8. The method according to claim 4 , wherein the fluorine-containing etching gas flow comprises the carrier gas in an amount between 1000 sccm and 5000 sccm.

9. The method according to claim 1 , wherein the temperature of the plasma-etching steps is about 1300° C. or less.

10. The method according to claim 1 , wherein:
the supply flow is between 3 and 5 slm; and/or
the main gas flow is between 3 and 5 slm.

11. The method according to claim 1 , wherein the reversal point near the discharge side is separated from the reversal point near the supply side by a length equaling between 1 and 20 percent of the total available length of the substrate tube.

12. The method according to claim 1 , wherein the reversal point near the discharge side is separated from the reversal point near the supply side by a length equaling between 5 and 10 percent of the total available length of the substrate tube.

13. A process of manufacturing an optical-fiber preform via inside vapor deposition, the process comprising the steps of:
providing a substrate tube having an activated inner surface obtained according to the method of claim 1 ;
supplying doped and/or undoped glass-forming gases into the substrate tube having an activated inner surface;
depositing glass layers on the inside of the substrate tube to form a deposited tube; and
collapsing the deposited tube into an optical-fiber preform.

14. An optical-fiber preform made by the process according to claim 13 .

15. A method of manufacturing an optical fiber by drawing the optical-fiber preform according to claim 14 .

16. An optical fiber made by the method according to claim 15 .

17. A method for activating an inner surface of a substrate tube via plasma etching with a fluorine-containing etching gas, comprising:
supplying a supply flow of gas to the interior of a substrate tube, wherein the supply flow includes a main gas flow and a fluorine-containing etching gas flow;
inducing a plasma via electromagnetic radiation to create a plasma zone within the substrate tube's interior; and
longitudinally reciprocating the plasma zone between a reversal point near the supply side of the substrate tube and a reversal point near the discharge side of the substrate tube, wherein the reversal point near the discharge side of the substrate tube is separated from the reversal point near the supply side of the substrate tube by a length equaling between 1 and 20 percent of the total available length of the substrate tube.

18. The method according to claim 17 , wherein the fluorine-containing etching gas comprises a fluorine-containing compound and a carrier gas.

19. The method according to claim 18 , wherein:
the fluorine-containing compound comprises CCl 2 F 2 , CF 4 , C 2 F 6 , C 4 F 8 , SF 6 , F 2 , NF 3 , SO 2 F 2 , CHF 3 , CClF 3 , or CCl 3 F, or a combination thereof; and/or
the carrier gas comprises oxygen (O 2 ), nitrogen (N 2 ), or argon (Ar), or a combination thereof.

20. The method according to claim 18 , wherein the fluorine-containing compound is C 2 F 6 and the carrier gas is O 2 .

21. The method according to claim 17 , wherein the reversal point near the discharge side of the substrate tube is separated from the reversal point near the supply side of the substrate tube by a length equaling between 5 and 10 percent of the total available length of the substrate tube.

Assignees

• Draka Comteq Bv
• Draka Comteq Bv

Inventors

• Milicevic Igor
• Krabshuis Gertjan
• Van Stralen Mattheus Jacobus Nicolaas
• Gerharts Peter
• Hartsuiker Johannes Antoon

Classifications

• H01J37/32339

  using electromagnetic radiation · CPC title

• H01J37/3244 Primary

  Gas supply means · CPC title

• C03B37/01861

  Means for changing or stabilising the diameter or form of tubes or rods · CPC title

• C03B37/01228

  Removal of preform material (C03B37/01251 takes precedence) · CPC title

• C03C15/00

  Surface treatment of glass, not in the form of fibres or filaments, by etching (etching or surface-brightening compositions, in general C09K13/00) · CPC title