Sensor element and a method for detecting a parameter of a gas mixture in a gas chamber

Patent metadata

Field	Value
Publication number	US-9829457-B2
Application number	US-201213982454-A
Country	US
Kind code	B2
Filing date	Jan 26, 2012
Priority date	Jan 28, 2011
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

A sensor element for detecting a parameter of a gas mixture in a gas chamber, having a first electrode and a first diffusion barrier layer arranged to be coupled to said first electrode in a predetermined first region, and arranged such that the gas mixture of the gas chamber only impinges on the first electrode in the first region via the first diffusion barrier layer. In addition, the sensor element has a second electrode arranged such that the gas mixture of the gas chamber impinges on the second electrode in a further first region. The sensor element includes a solid electrolyte designed to be coupled to the first and the second electrodes.

First claim

The invention claimed is:

1. A sensor element configured to detect a parameter of a gas mixture in a gas chamber, comprising:
a first electrode;
a first diffusion barrier layer disposed such that it is coupled to the first electrode in a specified first region, wherein the first electrode is acted upon by the gas mixture of the gas chamber via the first diffusion barrier layer only in the first region;
a second electrode disposed such that it is acted upon directly by the gas mixture in another first region; and
a solid state electrolyte coupled to the first and second electrodes,
wherein the sensor element has a planar layered structure, the first electrode and the second electrode being spaced apart along a first axis at specified intervals so that their respective edges are spaced apart from each other along the first axis and along a second axis that extends orthogonally to the respective layers and orthogonally to the first axis, are vertically offset relative to each other, and at least partly embedded in the solid state electrolyte, and
wherein one surface of the second electrode and one surface of the first diffusion barrier layer form a plane, via which the second electrode is acted upon directly by the gas mixture of the gas chamber and via which the first electrode is indirectly acted upon by the gas mixture of the gas chamber via the first diffusion barrier layer.

2. The sensor element as claimed in claim 1 , wherein the first diffusion barrier layer comprises zirconium dioxide.

3. The sensor element as claimed in claim 1 , wherein the another first region of the second electrode has a larger area than the first region of the first electrode.

4. The sensor element as claimed in claim 1 , further comprising:
a heating element configured to heat the solid state electrolyte, wherein
the heating element configured to be controlled during a measurement phase to switch off and
during an operating phase the heating element is configured to be controlled to set up a specified operating temperature of the solid state electrolyte.

5. The sensor element as claimed in claim 1 , wherein the first diffusion barrier layer comprises a porous ceramic material.

6. The sensor element as claimed in claim 5 , wherein the first diffusion barrier layer comprises zirconium dioxide.

7. The sensor element as claimed in claim 1 , further comprising a second diffusion barrier layer disposed such that it is coupled in the another first region to the second electrode and the second electrode is acted upon by the gas mixture of the gas chamber only in the another first region via the second diffusion barrier layer,
wherein the second diffusion barrier layer has a second diffusion resistance for at least one specified gas component of the gas mixture that is lower than a first diffusion resistance of the first diffusion barrier layer.

8. The sensor element as claimed in claim 7 , wherein the first diffusion barrier layer and the second diffusion barrier layer comprise a same ceramic material.

9. A method for detecting of the parameter of the gas mixture in a gas chamber with a sensor element as claimed in claim 1 that is disposed in the gas chamber and whose first and second electrodes are electrically coupled to a power supply, comprising:
controlling the power supply to switch off during a measurement phase;
detecting an electrode voltage between the first and second during the measurement phase;
determining a pump current based at least in part on a deviation of the electrode voltage from a specified target voltage during the measurement phase;
controlling the power supply to output the pump current to the second electrode of the sensor element in an operating phase that follows the measurement phase in time, wherein the measurement phase and the subsequent controlling of the power supply to output the pump current to the second electrode are carried out multiple times to minimize the deviation between the electrode voltage and the specified target voltage; and
determining the parameter of the gas mixture in the gas chamber based at least in part on the pump current.

10. The method as claimed in claim 9 , wherein the sensor element comprises a heating element configured to heat the solid state electrolyte, wherein
the heating element is controlled during the measurement phase to switch off and
during the operating phase the heating element is controlled to set up a specified operating temperature of the solid state electrolyte.

11. The method as claimed in claim 9 , wherein the parameter represents an oxygen concentration of the gas mixture.

12. The method as claimed in claim 9 , wherein the gas chamber is an induction chamber of an internal combustion engine.

13. A method for detecting of a parameter of a gas mixture in a gas chamber comprising:
disposing a sensor element in the gas chamber having first and second electrodes arranged as a planar layered structure, the first electrode and the second electrode being spaced apart along a first axis at specified intervals so that their respective edges are spaced apart from each other along the first axis and along a second axis that extends orthogonally to the respective layers and orthogonally to the first axis, are vertically offset relative to each other, and at least partly embedded in a solid state electrolyte, and that are electrically coupled to a power supply;
a gas inlet limiter, configured such that the first electrode is acted upon indirectly via a diffusion barrier by the gas mixture of the gas chamber via the gas inlet limiter in a specified first region,
the second electrode offset from the first electrode to not overlap with the first electrode, configured such that it is acted upon directly by the gas mixture of the gas chamber in another first region, and
the solid state electrolyte, configured such that it is coupled to the first and second electrodes, wherein the method further comprises:
controlling the power supply during a measurement phase to switch off,
detecting an electrode voltage between the first and second electrodes during the measurement phase;
determining a pump current based at least in part on a deviation of the electrode voltage from a specified target voltage during the measurement phase;
controlling the power supply to output the pump current to the second electrode of the sensor element in an operating phase that follows the measurement phase in time, wherein the measurement phase and the subsequent controlling of the power supply to output the pump current to the second electrode are carried out multiple times to minimize the deviation between the electrode voltage and the specified target voltage; and
determining the parameter of the gas mixture in the gas chamber based at least in part on the pump current.

14. The method as claimed in claim 13 , wherein the gas inlet limiter comprises a first diffusion barrier layer disposed such that it is coupled to the first electrode in a specified first region and the first electrode is acted upon by the gas mixture of the gas chamber via the first diffusion barrier layer only in the first region.

15. The method as claimed in claim 13 , wherein the sensor element comprises a heating element configured to heat the solid state electrolyte, wherein
the heating element is controlled during the measurement phase to switch off and
during the operating phase the heating element is controlled to set up a specified operating temperature of the solid state electrolyte.

Assignees

• Reitmeier Torsten
• Wildgen Andreas
• Continental Automotive Gmbh

Inventors

• Reitmeier Torsten
• Wildgen Andreas

Classifications

• G01N27/4074

  for detection of gases other than oxygen · CPC title

• G01N27/304 Primary

  Gas permeable electrodes · CPC title

• G01N27/4071

  using sensor elements of laminated structure · CPC title

• G01N27/417

  using cells {, i.e. more than one cell} and probes with solid electrolytes · CPC title

• G01N27/4072 Primary

  characterized by the diffusion barrier · CPC title