Leach-resistant leaded copper alloys

Patent metadata

Field	Value
Publication number	US-9829122-B2
Application number	US-201313802995-A
Country	US
Kind code	B2
Filing date	Mar 14, 2013
Priority date	Nov 7, 2011
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

Copper alloys exhibiting enhanced oxidation resistance are provided by adding an amount of sulfur that is effective to enhance oxidative resistance. Such sulfur addition can be achieved by combining elemental forms of copper and sulfur and heating the mixture to form a molten alloy, or by forming a sulfur-rich pre-mix that is added to a base alloy composition. Forming a pre-mix provides improved homogeneity and distribution of the sulfur predominantly in the form of a metal sulfide.

First claim

What is claimed is:

1. A leaded copper alloy having an elemental composition comprising:
at least 50% copper by weight;
phosphorous, antimony and tin, each less than 0.006% by weight;
an amount of lead from about 0.09% to about 0.25% by weight, the lead comprising a lead segregate phase;
an amount of silicon from about 0.5% to about 6% by weight;
an amount of zinc from about 35% to about 45% by weight; and
an amount of nickel from about 0.1% to about 6% by weight;
an amount of sulfur from about 2.5% to 4% by weight and that is effective to enhance oxidative resistance of lead within a copper alloy,
wherein the amount of sulfur is throughout a substantial bulk of the alloy within the lead segregate phase in the form of a lead sulfide.

2. An alloy according to claim 1 , further comprising one or more additives selected from the group consisting of selenium, tellurium, manganese, bismuth, iron, aluminum, and arsenic, each of the one or more additives present in an amount from about 0.1% to about 6% by weight.

3. A water-conveying conduit system comprising:
a conduit component fabricated from a leaded copper alloy comprising at least 50% copper by weight; an amount of lead from about 0.09% to about 0.25% by weight, the lead comprising a lead segregate phase; an amount of silicon from about 0.5% to about 6% by weight; phosphorous, antimony and tin, each less than 0.006% by weight; an amount of zinc from about 35% to about 45% by weight; an amount of nickel from about 0.1% to about 6% by weight; and an amount of sulfur from about 2.5% to 4% by weight and that is effective to enhance oxidative resistance, wherein the amount of sulfur is through a substantial bulk of the alloy within the lead segregate phase in the form of a lead sulfide.

4. A process for preparing an oxidation resistant leaded copper alloy, comprising the steps of:
combining copper, lead, zinc, silicon, nickel, and sulfur to form a molten alloy, wherein the copper is present in an amount greater than about 50% by weight of the molten alloy, the lead is present from about 0.09% to about 0.25% by weight of the molten alloy, the lead comprising a lead segregate phase, the zinc is present from about 35% to about 45% by weight of the molten alloy, the silicon is present from about 0.5% to about 6% by weight, the nickel is present from about 0.1% to about 6% by weight, and the sulfur is present in an amount from about 2.5% to 4% by weight and that is effective to enhance oxidative resistance of the alloy; and
allowing the molten alloy to cool and thereby solidify,
wherein phosphorous, antimony and tin are at trace amounts in the alloy, each less than 0.006% by weight, and
further wherein the amount of sulfur is through a substantial bulk of the alloy within the lead segregate phase in the form of a lead sulfide.

5. The process according to claim 4 , further comprising the step of:
heat treating the solidified alloy.

6. The process according to claim 5 , wherein the step of heat treating the solidified alloy comprises raising the temperature of the alloy from about 1000° F. to about 1450° F. and maintaining the increased temperature for about 1 hour to about 2 hours.

7. The process according to claim 4 , wherein the step of combining the copper, lead, and sulfur includes the steps of:
preparing a base alloy;
preparing a molten pre-mix containing sulfur and a pre-mix metal; and
adding the molten pre-mix to the base alloy.

8. The process according to claim 7 , wherein the step of preparing the molten pre-mix comprises combining the sulfur and the pre-mix metal, the pre-mix metal chosen from the group consisting of copper, zinc, aluminum, lead, bismuth, and a combination thereof.

9. The process according to claim 8 , wherein the step of preparing the base alloy comprises melting copper to form the base alloy, the base alloy comprising molten copper.

10. The process according to claim 9 , wherein the step of preparing the base alloy further comprises adding at least one additive selected from the group consisting of selenium, tellurium, manganese, bismuth, iron, aluminum, and arsenic, each of the one or more additives in an amount from about 0.1% to about 6% by weight.

Assignees

• Nibco

Inventors

• Lawrence Benjamin L

Classifications

• C22C9/02

  with tin as the next major constituent · CPC title

• C22C1/00

  Making non-ferrous alloys (by electrothermic methods C22B4/00; by electrolysis C25C1/24, C25C3/36) · CPC title

• C22C9/08

  with lead as the next major constituent · CPC title

• C22C9/04

  with zinc as the next major constituent · CPC title

• C22C9/06

  with nickel or cobalt as the next major constituent · CPC title