Phthalate-free PP homopolymers for meltblown fibers

Patent metadata

Field	Value
Publication number	US-9828698-B2
Application number	US-201415039107-A
Country	US
Kind code	B2
Filing date	Dec 1, 2014
Priority date	Dec 4, 2013
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

The present invention is directed to a new polypropylene composition comprising a propylene homopolymer, to a melt-blown fiber comprising the polypropylene composition, to a melt blown web comprising the melt blown fiber and/or the polypropylene composition, to an article comprising the melt blown fiber and/or the melt blown web as well as to the use of the polypropylene composition for improving the relation between pressure drop and hydrohead of a melt-blown web.

First claim

The invention claimed is:

1. A polypropylene composition comprising a propylene homopolymer, the propylene homopolymer having at least 99.8 wt.-% of propylene units, the polypropylene composition and/or propylene homopolymer having
a) a melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 of ≧400 g/10 min, and
b) a melting temperature Tm of ≧150° C.,
wherein the polypropylene composition comprises at least 95.0 wt.-% of the propylene homopolymer,
wherein the polypropylene composition and/or propylene homopolymer is free of phthalic acid esters, and
wherein the polypropylene composition and/or propylene homopolymer has/have been visbroken.

2. The polypropylene composition according to claim 1 , wherein the polypropylene composition and/or propylene homopolymer has/have
a) a melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 in the range from 400 to 3,000 g/10 min, and/or
b) a melting temperature Tm in the range from 150 to 200° C.

3. The polypropylene composition according to claim 1 , wherein the polypropylene composition and/or propylene homopolymer has/have been visbroken with a visbreaking ratio [final MFR 2 (230° C./2.16 kg)/initial MFR 2 (230° C./2.16 kg)] of 5 to 50, wherein “final MFR 2 (230° C./2.16 kg)” is the MFR 2 (230° C./2.16 kg) of the polypropylene composition and/or propylene homopolymer after visbreaking and “initial MFR 2 (230° C./2.16 kg)” is the MFR 2 (230° C./2.16 kg) of the polypropylene composition and/or propylene homopolymer before visbreaking.

4. The polypropylene composition according to claim 1 , wherein the polypropylene composition and/or propylene homopolymer has/have
a) 2,1 erythro regio-defects of equal or below 0.4 mol.-% determined by 13 C-NMR spectroscopy, and/or
b) a pentad isotacticity (mmmm) of more than 90.0%, and/or
c) a xylene cold soluble content (XCS) determined according ISO 16152 (25° C.) of at least 1.8 wt.-%, and/or
d) a crystallization temperature Tc of ≧110° C.

5. The polypropylene composition homopolymer according to claim 1 , wherein the propylene homopolymer before visbreaking fulfills inequation (I)
VOC≦(MFR×0.08)+201.0  (I)

wherein
VOC is the volatile organic compound (VOC) value [in ppm] measured according to VDA 278:2002 of the propylene homopolymer before visbreaking; MFR is the melt flow rate MFR 2 (230° C./2.16 kg) measured according to ISO 1133 of the propylene homopolymer before visbreaking.

6. The polypropylene composition according to claim 1 , wherein the propylene homopolymer has been polymerized in the presence of
a) a Ziegler-Natta catalyst (ZN-C) comprising compounds (TC) of a transition metal of Group 4 to 6 of IUPAC, a Group 2 metal compound (MC) and an internal donor (ID), wherein said internal donor (ID) is a non-phthalic compound;
b) optionally a co-catalyst (Co), and further
c) optionally an external donor (ED).

7. The polypropylene composition according to claim 6 , wherein
a) the internal donor (ID) is selected from optionally substituted malonates, maleates, succinates, glutarates, cyclohexene-1,2-dicarboxylates, benzoates and derivatives and/or mixtures thereof; and
b) the molar-ratio of co-catalyst (Co) to external donor (ED) [Co/ED] is 5 to 45.

8. The polypropylene composition according to claim 1 , wherein the propylene homopolymer is produced in a sequential polymerization process comprising at least two reactors (R1) and (R2), in the first reactor (R1) a first propylene homopolymer fraction (H-PP1) is produced and subsequently transferred into the second reactor (R2), in the second reactor (R2) a second propylene homopolymer fraction (H-PP2) is produced in the presence of the first propylene homopolymer fraction (H-PP1).

9. The polypropylene composition according to claim 2 , wherein the polypropylene composition and/or propylene homopolymer has/have been visbroken with a visbreaking ratio [final MFR 2 (230° C./2.16 kg)/initial MFR 2 (230° C./2.16 kg)] of 5 to 50, wherein “final MFR 2 (230° C./2.16 kg)” is the MFR 2 (230° C./2.16 kg) of the polypropylene composition and/or propylene homopolymer after visbreaking and “initial MFR 2 (230° C./2.16 kg)” is the MFR 2 (230° C./2.16 kg) of the polypropylene composition and/or propylene homopolymer before visbreaking.

10. The polypropylene composition according to claim 2 , wherein the polypropylene composition and/or propylene homopolymer has/have
a) 2,1 erythro regio-defects of equal or below 0.4 mol.-% determined by 13 C-NMR spectroscopy, and/or
b) a pentad isotacticity (mmmm) of more than 90.0%, and/or
c) a xylene cold soluble content (XCS) determined according ISO 16152 (25° C.) of at least 1.8 wt.-%, and/or
d) a crystallization temperature Tc of ≧110° C.

11. The polypropylene composition according to claim 2 , wherein the propylene homopolymer is the only polymer present in the polypropylene composition.

12. A melt-blown fiber having an average diameter of not more than 5.0 μm, said fiber comprising a polypropylene composition as defined in claim 1 .

13. The melt-blown web comprising the melt blown fiber according to claim 12 .

14. An article comprising a melt-blown fiber according to claim 12 , wherein said article is selected from the group consisting of filtration medium, diaper, sanitary napkin, panty liner, incontinence product for adults, protective clothing, surgical drape, surgical gown, and surgical wear.

15. A melt-blown web having an air permeability in the range from 500 to 2,000 mm/s, and comprising the polypropylene composition of claim 1 ,
wherein the melt-blown web has a property defined by inequation (III)
(PD-web)/(HH-web)≦0.88  (III)

wherein
(PD-web) is the pressure drop (Pa), measured across a thickness direction of the melt-blown web according to DIN ISO 9237, of a melt-blown web having a weight per unit area of 9.5±1.0 g/m 2 ,
(HH-web) is the hydrohead (3 rd drop, cm −2 H 2 O), measured across a thickness direction of the melt-blown web according to standard test WSP 80.6 (09), of a melt-blown web having a weight per unit area of 9.5±1.0 g/m 2 .

Assignees

• Borealis Ag

Inventors

• Wang Jingbo
• Klimke Katja
• Fiebig Joachim
• Van Paridon Henk
• Luyten Anita
• Gahleitner Markus

Classifications

• D04H3/005

  Synthetic yarns or filaments (D04H3/013 takes precedence) · CPC title

• D01D5/0985

  by means of a flowing gas (e.g. melt-blowing) · CPC title

• C08F2500/15

  Isotactic · CPC title

• C08F110/06

  Propene · CPC title

• C08F2/001

  Multistage polymerisation processes characterised by a change in reactor conditions without deactivating the intermediate polymer (C08F295/00, C08F297/00 take precedence) · CPC title