Low cost and high strength titanium alloy and heat treatment process

Patent metadata

Field	Value
Publication number	US-9828662-B2
Application number	US-201313979713-A
Country	US
Kind code	B2
Filing date	Mar 28, 2013
Priority date	Sep 14, 2012
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

Systems and methods of a low cost, high strength titanium alloy are disclosed. According to illustrative implementations, the weight percent of the alloy composition may be: Fe content 3%˜7%, Al content 3%˜5%, C content 0.01%˜0.02%, with the balance being Ti and unavoidable impurities. Industrial pure iron, carbon steel, and industrial pure aluminum etc. may be used as the raw materials. In one exemplary method, the raw materials are mixed before being pressed to a block. The block may be double-melted to an alloy cast ingot, forged by a conventional titanium alloy forging process, and subsequently undergo a solid solution treatment of (820° C.˜950° C.)/1 h+water quenching, and an ageing treatment of (450° C.˜550° C.)/4 h+air cooling, wherein the mechanical properties of the alloy are that σb=1000˜1250 MPa, δ=5%-12%.

First claim

What is claimed is:

1. A method of producing a high strength titanium alloy, the method comprising:
providing an alloy comprising Ti, Fe, Al, and C, wherein weight percentage of elements in the alloy are: content of Fe is 3%-7%, content of Al is 3%-5%, content of C is 0.01%-0.02%, with a balance being Ti, and impurities;
providing a first solid solution treatment to the alloy at a temperature of 940° C., for a period of 40 minutes, followed by water quenching;
providing an first ageing treatment to the alloy at a temperature of 500° C., for 4 hours, followed by air cooling;
providing a second solid solution treatment to the alloy at a temperature of 900° C., for a period of 40 minutes, followed by water quenching; and
providing a second ageing treatment at a temperature of 500° C., for 4 hours, followed by air cooling; and
wherein the alloy has a tensile strength of at least 1180 MPa, a yield strength of at least 980 MPa, and an elongation of at least 8%.

2. The method of claim 1 , wherein the alloy is comprised of titanium of sponge/base grade 0, iron of 99.3% industrial purity, aluminum of 99.5% industrial purity, and carbon of industrial 45 grade.

3. The method of claim 2 , wherein the alloy has a tensile strength of at least 1290 MPa, a yield strength of at least 1180 MPa, and an elongation of at least 10%.

4. The method of claim 1 , further comprising:
prior to providing the solid solution treatment, pressing the alloy to a block with a 200 ton hydraulic machine.

5. The method of claim 4 , further comprising:
double-melting the pressed block with a 5 kilogram vacuum suspension induction furnace using a smelting temperature between 1700° C. and 1850° C. to provide a cast ingot of the alloy.

6. The method of claim 1 , further comprising:
prior to the providing a solid solution treatment, forging bars and/or plates of the alloy via cogging forging including an initial cogging heating at a temperature between 950° C. and 1050° C., followed by a final precision forging at a temperature between 800° C. and 900° C.

7. The method of claim 6 wherein the initial cogging heating is performed at a temperature of 980° C., and wherein the final precision forging includes multi-pass upsetting and stretching processes at a temperature of 850° C.

8. The method of claim 1 wherein, prior to the providing a solid solution treatment, the alloy is forged into a φ25 mm bar, and wherein, as a result of the forging, the alloy has a tensile strength of at least 1100 MPa, a yield strength of at least 950 MPa, and an elongation of at least 13%.

9. The method of claim 1 wherein the alloy has a tensile strength of at least 1290 MPa, a yield strength of at least 1180 MPa, and an elongation of at least 10%.

10. The method of claim 1 wherein the weight percentage content of Fe is 3%, the weight percentage of Al is 5%, and the weight percentage of C is 0.01%, and wherein the alloy has an elongation of at least 16%.

11. The method of claim 1 wherein the alloy is created from an ingot that received a heat treatment at a temperature of between 500° C. and 650° C., for a period of 1 hour, wherein the alloy has an elongation of at least 9%.

12. The method of claim 1 wherein the weight percentage content of Fe is 3%, the weight percentage of Al is 3%, and the weight percentage of C is 0.01%, and wherein the alloy has an elongation of at least 9%.

13. The method of claim 1 wherein the weight percentage content of Fe is 5%, the weight percentage of Al is 3%, and the weight percentage of C is 0.01%, and wherein the alloy has an elongation of at least 9%.

14. The method of claim 1 wherein the weight percentage content of Fe is 7%, the weight percentage of Al is 3%, and the weight percentage of C is 0.02%, and wherein the alloy has an elongation of at least 9%.

15. The method of claim 1 wherein the weight percentage content of Fe is 7%, the weight percentage of Al is 5%, and the weight percentage of C is 0.02%, and wherein the alloy has an elongation of at least 9%.

16. The method of claim 1 wherein the weight percentage content of Fe is 5%, the weight percentage of Al is 3%, and the weight percentage of C is 0.01%, and wherein the alloy has an elongation of at least 9%.

17. The method of claim 1 wherein the weight percentage content of Fe is 7%, the weight percentage of Al is 3%, and the weight percentage of C is 0.02%, and wherein the alloy has an elongation of at least 9%.

18. The method of claim 1 wherein the weight percentage content of Fe is 7%, the weight percentage of Al is 5%, and the weight percentage of C is 0.02%, and wherein the alloy has an elongation of at least 9%.

19. The method of claim 1 wherein the alloy has an elongation of at least 9%.

20. The method of claim 1 wherein the alloy has an elongation of at least 10%.

Assignees

• Univ Beijing Technology

Inventors

• Li Bolong
• Liu Tong
• Wang Wei
• Huang Hui
• Li Hongmei
• Rong Li

Classifications

• C22F1/00

  Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working (apparatus for mechanical working of metal B21, B23, B24) · CPC title

• C22C14/00

  Alloys based on titanium · CPC title

• C22F1/002

  by rapid cooling or quenching; cooling agents used therefor · CPC title

• C22F1/18

  High-melting or refractory metals or alloys based thereon · CPC title

• C22F1/183 Primary

  of titanium or alloys based thereon · CPC title