Polymerizable composition and method for manufacturing liquid crystal device

Patent metadata

Field	Value
Publication number	US-9828550-B2
Application number	US-201314652351-A
Country	US
Kind code	B2
Filing date	Dec 16, 2013
Priority date	Dec 14, 2012
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

Provided are a liquid crystal device, a composition capable of forming a liquid crystal layer, a method of manufacturing the liquid crystal device, a system for manufacturing the liquid crystal device, and a use of the liquid crystal device. The liquid crystal device is a device capable of exhibiting, for example, a normally white or black mode, which may exhibit a high contrast ratio and be driven with a low driving voltage, and exhibit excellent durability such as thermal stability. Such a liquid crystal device may be applied to various optical modulators such as a smart window, a window protective film, a flexible display device, an active retarder for displaying 3D images, or a viewing angle control film.

First claim

What is claimed is:

1. A polymerizable composition, comprising: a precursor of an alignable polymer network comprising a bifunctional acrylate compound, and optionally at least one selected from the group consisting of a multifunctional acrylate compound that is a tri-or more functional acrylate compound and a monofunctional acrylate compound such that they satisfy the Equations 1 to 3 below:
A≧ 1.3× B   [Equation 1]

A≧C  [Equation 2]

A≧ 0.6×( B+C )  [Equation 3]

wherein the “A,” “B” and “C” are weight ratios, respectively, between the compounds obtained after converting the sum of weights of the bifunctional acrylate compound, the multifunctional acrylate compound and the monofunctional acrylate compound in the precursor to be 100,
wherein a value (A−1.3×B) obtained by subtracting 1.3×B from A is within a range of 0.5 to 100, and a value (A-C) obtained by subtracting C from A is within a range of 0 to 100, and a value (A−0.6×(B+C)) obtained by subtracting 0.6×(B+C) from A is within a range of 2 to 100,
wherein the bifunctional acrylate compound is represented by Formula 1:

where the “R” is each independently hydrogen or an alkyl group having 1 to 4 carbon atoms, and the “X” is an alkylene or alkylidene group having 1 to 20 carbon atoms,
wherein the polymerizable composition satisfies Equation B:
(1− a )×{(2 n 0 2 +n e 2 )/3} 0.5 ≦n p ≦(1+ a )× n e   [Equation B]

where the “a” is a number within a range from 0 to 0.5, the “n o ” is an ordinary refractive index of the liquid crystal compound, the “n e ” is an extraordinary refractive index of the liquid crystal compound, and the “n p ” is a refractive index of the polymer network.

2. The polymerizable composition of claim 1 , wherein the polymerizable composition comprises:
5 to 50 parts by weight of the precursor of an alignable polymer network; and
50 to 95 parts by weight of a liquid crystal compound.

3. The polymerizable composition according to claim 1 , wherein the precursor satisfies the following Equations 4 to 6:
A≧40  [Equation 4]

B≦30  [Equation 5]

C≦50  [Equation 6]

wherein the “A,” “B” and “C” are weight ratios, respectively, between the compounds obtained after converting the sum of weights of the bifunctional acrylate compound, the multifunctional acrylate compound and the monofunctional acrylate compound in the precursor to be 100.

4. The polymerizable composition according to claim 1 , wherein the precursor comprises a multifunctional acrylate compound represented by Formula 2:

where the “n” is a number within a range of 3 or more, the “m” is a number within a range from 0 to 5, the “R” is each independently hydrogen or an alkyl group having 1 to 4 carbon atoms, the “X” is a (m+n) valent radical, and the “Y” is hydrogen or an alkyl group.

5. The polymerizable composition according to claim 4 , wherein the “X” of Formula 2 is a (m+n) valent radical derived from a hydrocarbon having 2 to 20 carbon atoms.

6. The polymerizable composition according to claim 1 , wherein the precursor comprises a monofunctional acrylate compound represented by Formula 3:

where the “R” is hydrogen or an alkyl group having 1 to 4 carbon atoms, and the “X” is an alkyl group having 1 to 20 carbon atoms.

7. The polymerizable composition according to claim 1 , which satisfies Equation C:
( n e +n o )/2− b ≦{(2 n o 2 +n e 2 )/3} 0.5 ≦( n e +n o )/2+ b   [Equation C]

where the “n e ” is an extraordinary refractive index of the liquid crystal compound, the “n 0 ” is an ordinary refractive index of the liquid crystal compound, and the “b” is a number within a range from 0.1 to 1.

8. The polymerizable composition according to claim 1 , which is a solventless type.

9. A method of manufacturing a liquid crystal device, comprising:
forming a liquid crystal layer comprising an alignable polymer network and a liquid crystal compound in the alignable polymer network by polymerizing a layer comprising the polymerizable composition of claim 1 .

10. The method according to claim 9 , wherein the layer comprising the polymerizable composition is formed by roll coating, printing, inkjet coating, slit nozzling, bar coating, comma coating, spin coating, gravure coating or squeeze coating.

11. The method according to claim 10 , wherein the layer comprising the polymerizable composition is formed by placing the polymerizable composition between two base layers, and applying a pressure to at least one of the base layers.

12. The method according to claim 10 , wherein a solventless composition is used as the polymerizable composition.

13. The method according to claim 9 , wherein the polymerization is performed while the layer comprising the polymerizable composition is in contact with an alignment layer.

14. The method according to claim 9 , wherein the polymerization is performed while the polymerizable composition is maintained in a nematic phase.

15. The polymerizable composition of claim 1 , wherein the precursor comprises a bifunctional acrylate compound represented by Formula 1:

each “R” is independently hydrogen or an alkyl group having 1 to 4 carbon atoms, and the “X” is an alkylene or alkylidene group having 1 to 20 carbon atoms,
wherein the precursor comprises a multifunctional acrylate compound represented by Formula 2:

wherein “n” is 3 or more,
“m” is from 0 to 5,
each “R” is independently hydrogen or an alkyl group having 1 to 4 carbon atoms,
“X” is a (m+n) valent radical, and
“Y” is hydrogen or an alkyl group,
and wherein the precursor comprises a monofunctional acrylate compound represented by Formula 3:

wherein each “R” is independently hydrogen or an alkyl group having 1 to 4 carbon atoms, and “X” is an alkyl group having 1 to 20 carbon atoms.

Assignees

• Lg Chemical Ltd

Inventors

• You Jung Sun
• Oh Dong Hyun
• Min Sung Joon
• Kim Kyung Jun
• Lee Dae Hee
• Chang Jun Won
• Park Moon Soo

Classifications

• C08L33/04

  Homopolymers or copolymers of esters {(C08L43/04 takes precedence)} · CPC title

• C08L33/14

  of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen · CPC title

• G02F1/133528

  Polarisers · CPC title

• C09K19/42

  Mixtures of liquid crystal compounds covered by two or more of the preceding groups C09K19/06 - C09K19/40 · CPC title

• C08F222/10

  Esters · CPC title