Adhesive composition and masking article for producing precise paint lines

Patent metadata

Field	Value
Publication number	US-9828530-B2
Application number	US-201314102258-A
Country	US
Kind code	B2
Filing date	Dec 10, 2013
Priority date	Dec 14, 2012
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

An adhesive article for masking a portion of a substrate surface from a liquid coating applied to the surface includes a support having first and second opposed major surfaces, and a cationic or zwitterionic adhesive composition disposed on at least a portion of at least one of the first and second opposed major surfaces. The adhesive composition provides a barrier that impedes the migration of the coating past the edge of the adhesive article.

First claim

We claim:

1. A masked environment including a masking tape, the environment comprising;
a masked substrate having a masked surface and an unmasked surface;
the masking tape applied to the masked surface, the tape comprising
a support having first and second opposed major surfaces; and
an adhesive composition comprising one or more surfactants at least one of which has quaternary ammonium functionality and a polymer, the polymer comprising the polymerized product of:
about 0.2 wt % to 5 wt % based on the total weight of the polymer of acrylic acid, methacrylic acid, a carboxylate salt thereof, or a mixture of two or more thereof, wherein the amount of carboxylate salt is determined based on the weight of the corresponding free acid;
about 50 wt % to 95 wt % based on the total weight of the polymer of an acrylate or methacrylate ester of an alcohol having between 8 and 12 carbon atoms, or a mixture of two or more thereof;
about 2 wt % to about 12 wt % based on the total weight of the polymer of an acrylate or methacrylate ester having an alkylammonium functionality; and

a paint formulation applied to the unmasked surface and at least a portion of the support, wherein the masked surface and the adhesive composition define an interface, and wherein the tape inhibits the migration of the paint beyond an edge of the interface.

2. The masked environment of claim 1 wherein the polymer and the one or more surfactants together comprise about 15 wt % to 60 wt % of the composition and the composition further comprises water.

3. The masked environment of claim 1 wherein the carboxylate salt of acrylic acid or methacrylic acid is a sodium salt.

4. The masked environment of claim 1 wherein the acrylate or methacrylate ester of an alcohol having between 8 and 12 carbon atoms is isooctyl acrylate.

5. The masked environment of claim 1 wherein the acrylate or methacrylate ester including an alkylammonium functionality is the reaction product of 2-(dimethylamino)ethyl acrylate or 2-(dimethylamino)ethyl methacrylate with an alkyl bromide or an alkyl chloride having between 1 and 24 carbon atoms.

6. The masked environment of claim 1 wherein the acrylate or methacrylate ester including an alkylammonium functionality is 2-(trimethylammonium)ethyl methacrylate chloride.

7. The masked environment of claim 1 wherein the polymer comprises about 85 wt % to 95 wt % based on the total weight of the polymer of an acrylate or methacrylate ester of an alcohol having between 8 and 12 carbon atoms.

8. The masked environment of claim 1 wherein the polymer comprises the polymerized product of sodium methacrylate, isooctyl acrylate, 2-(trimethylammonium)ethyl methacrylate chloride, and vinyl acetate.

9. The masked environment of claim 1 further comprising a release liner contacting at least a portion of the adhesive composition, such that the contacted adhesive composition is disposed between the support and the release liner.

10. The masked environment of claim 1 , characterized by a substantial absence of an edge treatment.

11. The masked environment of claim 1 , wherein the composition is an emulsion.

12. A masking tape comprising:
a support having first and second opposed major surfaces;
a paint formulation applied to at least a portion of the support; and
an adhesive composition comprising a polymer, the polymer comprising the polymerized product of:
about 50 wt % to 95 wt % based on the total weight of the polymer of an acrylate or methacrylate ester of an alcohol having between 8 and 12 carbon atoms, or a mixture of two or more thereof;
about 2 wt % to 12 wt % based on the total weight of the polymer of an acrylate or methacrylate ester having an alkylammonium functionality; and
about 0.50 wt % to 30 wt % based on the total weight of the polymer of vinyl acetate, isobutyl acrylate, N-vinyl pyrrolidone, or a mixture of two or more thereof;

wherein the adhesive composition includes one or more surfactants at least one of which has quaternary ammonium functionality, and wherein the tape inhibits the migration of the paint beyond an edge of an interface at least partially defined by the adhesive composition.

13. A masking tape comprising:
a support having first and second opposed major surfaces, and a paint formulation applied to at least a portion of the support;
an adhesive composition comprising a polymer, the polymer comprising the polymerized product of:
about 50 wt % to about 95 wt % based on the total weight of the polymer of an acrylate or methacrylate ester of an alcohol having between 8 and 12 carbon atoms, or a mixture of two or more thereof;
about 2 wt % to about 45 wt % based on the total weight of the polymer of an acrylate or methacrylate ester having an alkylammonium functionality; and
about 0.5 wt % to about 2 wt % based on the total weight of the polymer of a crosslinker; and
a low adhesion backsize coating on the second major surface, and wherein the tape inhibits the migration of the paint beyond an edge of an interface at least partially defined by the adhesive composition.

14. A masking tape comprising:
a support having first and second opposed major surfaces;
an adhesive composition on the first major surface, the composition including a polymer comprising the polymerized product of:
about 0.2 wt % to about 5 wt % based on the total weight of the polymer of sodium methacrylate
about 50 wt % to about 95 wt % based on the total weight of the polymer of isooctyl acrylate
about 2 wt % to about 10 wt % based on the total weight of the polymer of 2-(trimethylammonium)ethyl methacrylate chloride; and
a low adhesion backsize coating and a paint formulation on the second major surface.

Assignees

• 3M Innovative Properties Co

Inventors

• Ali Mahfuza B
• Johnson Elizabeth E
• Crandall Michael D

Classifications

• C09J2203/31

  as a masking tape for painting · CPC title

• C09J133/14

  of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen · CPC title

• Y10T428/1476

  Release layer · CPC title

• Y10T428/2848

  Three or more layers · CPC title

• Y10T428/2891

  including addition polymer from alpha-beta unsaturated carboxylic acid [e.g., acrylic acid, methacrylic acid, etc.] Or derivative thereof · CPC title