Method of manufacturing porous ceramic body and composition for porous ceramic body

Patent metadata

Field	Value
Publication number	US-9828481-B2
Application number	US-201314410898-A
Country	US
Kind code	B2
Filing date	Jun 28, 2013
Priority date	Jun 29, 2012
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

Disclosed is a method of manufacturing a porous ceramic body, which includes: (S1) mixing silica powders having a particle size of 0.045˜0.5 mm, zircon flour and wax, thus preparing a ceramic mixture; (S2) placing the ceramic mixture into a mold, thus producing a green body; and (S3) sintering the green body at high temperature, thus obtaining a porous ceramic body, wherein the silica having a particle size of 0.1˜0.5 mm is contained in an amount of 50˜80 wt % based on the total weight of the porous ceramic body; and also which produces a bulk porous ceramic body having good strength and leaching properties with excellent dimensional stability and shape stability.

First claim

What is claimed is:

1. A method of manufacturing a porous ceramic body, comprising:
(S1) mixing fused silica powders having a particle size of 0.045˜0.5 mm, zircon flour and wax, thus preparing a ceramic mixture;
(S2) placing the ceramic mixture into a mold, thus producing a green body; and
(S3) sintering the green body at a high temperature, thus obtaining a porous ceramic body,
wherein the fused silica powders having a particle size of 0.1˜0.5 mm are contained in an amount of 50˜80 wt % based on a total mass of the porous ceramic body,
wherein in S1, the wax is a mixture comprising two kinds of wax having different melting points mixed at a weight ratio of 6:4˜9:1; and
wherein in S1, the fused silica powders having a particle size of 0.045˜0.5 mm comprises:
fused silica powders having a particle size of 0.2˜0.5 mm;
fused silica powders having a particle size of 0.1˜0.2 mm;
fused silica powders having a particle size of 0.149 mm; and
fused silica powders having a particle size of 0.045 mm.

2. The method of claim 1 , wherein in S1, the zircon flour has a particle size of 0.045 mm.

3. The method of claim 1 , wherein in S1, the wax is contained in an amount of 5˜40 wt % based on a total mass of the ceramic mixture.

4. The method of claim 1 , wherein in S1, the ceramic mixture comprises, based on a total mass thereof:
1˜15 wt % of fused silica powders having a particle size of 0.2˜0.5 mm;
1˜40 wt % of fused silica powders having a particle size of 0.1˜0.2 mm;
5˜40 wt % of fused silica powders having a particle size of 0.149 mm;
5˜50 wt % of fused silica powders having a particle size of 0.045 mm;
10˜50 wt % of zircon flour having a particle size of 0.045 mm; and
5˜40 wt % of wax.

5. The method of claim 1 , wherein in S1, the ceramic mixture further comprises an additive selected from the group consisting of alumina, silicon carbide, polyvinylalcohol, cellulose, polyvinylbutyral, acrylate and ethyl silicate.

6. The method of claim 1 , wherein in S1, the wax is selected from the group consisting of paraffin wax, microcrystalline wax, polyolefin wax, beeswax, carnauba wax and mixtures thereof.

7. The method of claim 6 , wherein in S1, the wax is a mixture comprising paraffin wax having a melting point of 70° C. and microcrystalline wax having a melting point of 82° C. mixed at a weight ratio of 8:2.

8. The method of claim 1 , wherein S1 further comprises maintaining the ceramic mixture at a temperature of 50˜85° C., after preparing the ceramic mixture.

9. The method of claim 1 , wherein in S3, the green body is sintered at a temperature of 1000˜1400° C.

10. The method of claim 9 , wherein a holding time of sintering the green body is 2˜24 hr.

Assignees

• Korea Inst Energy Res

Inventors

• Yeo Jeong-Gu
• Lee Jin-Seok
• Kim Young-Hwan
• Jung Yeon-Gil
• Paik Ungyu

Classifications

• C04B2235/3248

  Zirconates or hafnates, e.g. zircon · CPC title

• C04B2235/656

  characterised by specific heating conditions during heat treatment · CPC title

• C08J9/0095 Primary

  Mixtures of at least two compounding ingredients belonging to different one-dot groups · CPC title

• C04B35/62665

  Flame, plasma or melting treatment · CPC title

• C04B2235/5427

  millimeter or submillimeter sized, i.e. larger than 0,1 mm · CPC title