Process for preparing an aqueous solution of a methylcellulose

Patent metadata

Field	Value
Publication number	US-9826768-B2
Application number	US-201414771891-A
Country	US
Kind code	B2
Filing date	Apr 8, 2014
Priority date	Apr 12, 2013
Publication date	Nov 28, 2017
Grant date	Nov 28, 2017

Abstract

A process for preparing an aqueous solution of a methylcellulose having anhydroglucose units joined by 1-4 linkages wherein hydroxy groups of anhydroglucose units are substituted with methyl groups such that s23/s26 is 0.36 or less, wherein s23 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 3-positions of the anhydroglucose unit are substituted with methyl groups and wherein s26 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 6-positions of the anhydroglucose unit are substituted with methyl groups, comprises the step of mixing the methylcellulose with an aqueous liquid at a temperature of not higher than 10° C. at a shear rate of at least 1000 s −1 .

First claim

The invention claimed is:

1. A process for preparing an aqueous solution of a methylcellulose having anhydroglucose units joined by 1-4 linkages wherein hydroxy groups of anhydroglucose units are substituted with methyl groups such that s23/s26 is 0.36 or less,
wherein s23 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 3-positions of the anhydroglucose unit are substituted with methyl groups and s26 is the molar fraction of anhydroglucose units wherein only the two hydroxy groups in the 2- and 6-positions of the anhydroglucose unit are substituted with methyl groups,
wherein the process comprises the step of mixing the methylcellulose with an aqueous liquid at a shear rate of at least 1000 s −1 .

2. The process of claim 1 wherein an aqueous solution comprising from 0.2 to 2.5 percent of the methylcellulose is prepared, based on the total weight of the aqueous solution.

3. The process of claim 1 , wherein the viscosity of the methylcellulose is from 200 to 10000 mPa·s, when measured as a 2 wt. % solution in water at 5° C. at a shear rate of 10 s −1 .

4. The process of claim 1 comprising the step of mixing a methylcellulose, wherein hydroxy groups of anhydroglucose units are substituted with methyl groups such that s23/s26 is 0.27 or less, with the aqueous liquid at a temperature of not higher than 10° C.

5. The process of claim 1 comprising the step of mixing a methylcellulose, wherein hydroxy groups of anhydroglucose units are substituted with methyl groups such that s23/s26 is 0.27 or less, with an aqueous liquid at a temperature of from 11° C. to 23° C.

6. The process of claim 1 , wherein an aqueous solution is prepared comprising from 0.2 to 2.5 percent of the methylcellulose (MC) and having a gel fracture force F GF (37° C.) of
i) at least 1.4 N when the MC concentration is from 0.2 to 0.4 percent,
ii) at least 2.0 N when the MC concentration is from 0.5 to 0.7 percent,
iii) at least 2.5 N when the MC concentration is from 0.8 to 1.0 percent,
iv) at least 3.5 N when the MC concentration is from 1.1 to 1.3 percent,
v) at least 4.5 N when the MC concentration is from 1.4 to 1.6 percent,
vi) at least 9.0 N when the MC concentration is from 1.7 to 1.9 percent,
vii) at least 11.0 N when the MC concentration is from 2.0 to 2.2 percent, or
viii) at least 13.0 N when the MC concentration is from 2.3 to 2.5 percent,
based on the total weight of the aqueous solution and
having a gel fracture force F GF (37° C.) of up to 20 N when the MC concentration is up to 1.6 percent and a gel fracture force F GF (37° C.) of up to 75 N when the MC concentration is up to 2.5 percent.

Assignees

• Dow Global Technologies Llc

Inventors

• Deo Puspendu
• Brown Kathryn
• Wallick David E
• Sammler Robert L
• Li Yongfu

Classifications

• A23L29/262 Primary

  Cellulose; Derivatives thereof, e.g. ethers · CPC title

• C08J3/03

  in aqueous media · CPC title

• A23V2002/00

  Food compositions, function of food ingredients or processes for food or foodstuffs · CPC title

• C08J3/075

  Macromolecular gels · CPC title

• A23L33/24

  Cellulose or derivatives thereof · CPC title