Near-infrared-ray-absorbing composition, near-infrared-ray cut filter using same, manufacturing method therefor, camera module, and manufacturing method therefor

Patent metadata

Field	Value
Publication number	US-9826129-B2
Application number	US-201514876287-A
Country	US
Kind code	B2
Filing date	Oct 6, 2015
Priority date	Apr 11, 2013
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

Provided are a near-infrared-ray-absorbing composition having strong near-infrared shielding properties when a cured film is produced, a near-infrared-ray cut filter, a manufacturing method therefor, a camera module, and a manufacturing method therefor. The near-infrared-ray-absorbing composition includes a copper complex obtained by reacting a compound (A) having at least two coordination sites with a copper component.

First claim

What is claimed is:

1. A near-infrared-ray-absorbing composition comprising:
a copper complex obtained by reacting a compound (A) having at least two coordination sites with a copper component, wherein the compound (A) is a compound (A3) having three or more coordinating atoms to be coordinated with an unshared electron pair and the coordinating atoms are nitrogen atoms; and wherein the composition further comprises a curable compound which contains at least one of a trifunctional or higher acrylate and a trifunctional or higher methacrylate, and a trifunctional or higher epoxy resin.

2. The near-infrared-ray-absorbing composition according to claim 1 , further comprising:
a curable compound and a solvent.

3. A near-infrared-ray-absorbing composition comprising:
a curable compound, a solvent, and a copper complex obtained by reacting a compound (A) having at least two coordination sites with a copper component, wherein the compound (A) is a compound (A3) having three or more coordinating atoms to be coordinated with an unshared electron pair and the coordinating atoms are nitrogen atoms,
wherein the curable compound is at least one of a trifunctional or higher acrylate, a trifunctional or higher methacrylate, and a trifunctional or higher epoxy resin.

4. A near-infrared-ray cut filter obtained using the near-infrared-ray-absorbing composition according to claim 1 .

5. A method for manufacturing a near-infrared-ray cut filter, comprising:
forming a film by applying the near-infrared-ray-absorbing composition according to claim 1 to a light-receiving side of a solid-state imaging element.

6. A camera module comprising:
a solid-state imaging element; and
a near-infrared-ray cut filter disposed in a light-receiving side of the solid-state imaging element,
wherein the near-infrared-ray cut filter is formed by curing the near-infrared-ray-absorbing composition according to claim 1 .

7. A method for manufacturing a camera module having a solid-state imaging element and a near-infrared-ray cut filter disposed in a light-receiving side of the solid-state imaging element, the method comprising:
forming the near-infrared-ray cut filter by applying the near-infrared-ray-absorbing composition according to claim 1 to the light-receiving side of the solid-state imaging element.

8. A near-infrared-ray-absorbing composition comprising: a copper complex obtained by reacting a compound (A) having at least two coordination sites with a copper component, wherein the compound (A) is a compound (A3) having three or more coordinating atoms to be coordinated with an unshared electron pair and the coordinating atoms are nitrogen atoms, and wherein the near-infrared-ray-absorbing composition further comprises a curable compound which contains a compound having a trifunctional or higher epoxy group or an oxetanyl group.

9. The near-infrared-ray-absorbing composition according to claim 1 , wherein the number of atoms linking the coordinating atoms to be coordinated with an unshared electron pair is in a range of 3 to 6.

10. The near-infrared-ray-absorbing composition according to claim 1 , wherein the number of atoms linking the coordinating atoms to be coordinated with an unshared electron pair is 3.

11. The near-infrared-ray-absorbing composition according to claim 1 , wherein the compound (A3) is represented by the following General Formula (V):
Y 1 -L 1 -Y 2   General Formula (V)

wherein each of Y 1 and Y 2 independently represents a ring including the coordinating nitrogen atom to be coordinated with an unshared electron pair or a partial structure selected from the following group (UE) of partial structures; and L 1 represents a single bond or a divalent linking group:

wherein each of R 1 s independently represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heteroaryl group, and each of R 2 s independently represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an alkoxy group, an aryloxy group, a heteroaryloxy group, an alkylthio group, an arylthio group, a heteroarylthio group, an amino group, or an acyl group.

12. The near-infrared-ray-absorbing composition according to claim 1 , wherein the compound (A3) is represented by the following General Formula (V-1) or (V-2):
Y 3 -L 2 -Y 4 -L 3 -Y 5   (V-1)

Y 6 -L 6 -Y 7 -L 7 -Y 8 -L 8 -Y 9   (V-2)

wherein each of Y 3 , Y 5 , Y 6 , and Y 9 independently represents a ring including the coordinating nitrogen atom to be coordinated with an unshared electron pair or a partial structure selected from the following group (UE) of partial structures;
each of Y 4 , Y 7 , and Y 8 independently represents a ring including the coordinating nitrogen atom to be coordinated with an unshared electron pair or at least one group selected from following group (UE-1) of partial structures; and
each of L 2 to L 8 independently represents a single bond or a divalent linking group, wherein the divalent linking group is an alkylene group having 1 to 12 carbon atoms, an arylene group having 6 to 12 carbon atoms, —SO—, —O—, —SO 2 —or a group formed of a combination thereof;

wherein in Group (UE), each of R 1 s independently represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heteroaryl group, and each of R 2 s independently represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, a heteroaryl group, an alkoxy group, an aryloxy group, a heteroaryloxy group, an alkylthio group, an arylthio group, a heteroarylthio group, an amino group, or an acyl group,
and wherein in Group (UE-1), each of Rs independently represents a hydrogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or a heteroaryl group.

Assignees

• Fujifilm Corp

Inventors

• Inasaki Takeshi
• Kawashima Takashi
• Hitomi Seiichi
• Sasaki Kouitsu

Classifications

• H04N23/57

  Mechanical or electrical details of cameras or camera modules specially adapted for being embedded in other devices · CPC title

• C07F9/143

  with unsaturated acyclic alcohols · CPC title

• C07F1/08

  Copper compounds · CPC title

• H04N5/33

  Transforming infrared radiation (cameras or camera modules for generating image signals from infrared radiation H04N23/20; circuitry of SSIS for transforming infrared radiation into image signals H04N25/20) · CPC title

• C07F7/1804

  Compounds having Si-O-C linkages (Si-O-acyl linkages C07F7/1896) · CPC title