Method for making lithium ion battery anode active material

Patent metadata

Field	Value
Publication number	US-9825288-B2
Application number	US-201414907295-A
Country	US
Kind code	B2
Filing date	Jul 2, 2014
Priority date	Jul 23, 2013
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

A method for making a lithium ion battery anode active material comprising: providing silicon particles and a silane coupling agent, wherein the silane coupling agent comprises a hydrolysable functional group and an organic functional group; mixing the silicon particles and the silane coupling agent in water to obtain a first mixture; adding a monomer or oligomer to the first mixture to obtain a second mixture, the surfaces of the silicon particles being coated with a polymer layer by in situ polymerization method to obtain silicon polymer composite material, the monomer or the oligomer reacting with the organic functional group of the silane coupling agent in a polymerization, thereby a generated polymer layer being chemically grafted on the surfaces of the silicon particles; and heating the silicon polymer composite material to carbonize the polymer layer to form a carbon layer coated on the surfaces of the silicon particles.

First claim

What is claimed is:

1. A method for making a lithium ion battery anode active material comprising:
providing silicon particles and a silane coupling agent, wherein the silane coupling agent comprises a hydrolysable functional group and an organic functional group;
mixing the silicon particles and the silane coupling agent in water to obtain a first mixture, the hydrolysable functional group of the silane coupling agent being hydrolyzed and chemically grafted on surfaces of the silicon particles;
adding a monomer comprising at least one of acrylonitrile and acrylic to the first mixture to obtain a second mixture;
in situ polymerizing the monomer to coat the surfaces of the silicon particles with a polymer layer to obtain a silicon polymer composite material, the monomer reacting with the organic functional group of the silane coupling agent in the in situ polymerizing, thereby chemically grafting the polymer layer on the surfaces of the silicon particles; and
heating the silicon polymer composite material to carbonize the polymer layer to form a carbon layer coated on the surfaces of the silicon particles, thereby achieving silicon carbon composite material.

2. The method for making a lithium ion battery anode active material of claim 1 , wherein a ratio of a volume of the monomer to a mass of the silicon particles is in a range from about 3 ml/g to about 10 ml/g.

3. The method for making a lithium ion battery anode active material of claim 1 , wherein a thickness of the carbon layer is in a range from about 10 nm to about 30 nm.

4. The method for making a lithium ion battery anode active material of claim 1 , wherein the heating comprises:
heating the silicon polymer composite material at a first temperature greater than or equal to 100° C. and less than 300° C.; and
further heating the silicon polymer composite material at a second temperature in a range from about 600° C. to about 900° C.

5. The method for making a lithium ion battery anode active material of claim 1 , wherein the mixing the silicon particles and the silane coupling agent in water to obtain the first mixture, comprises:
adding the silicon particles into water to form a dispersion liquid; and
adding the silane coupling agent into the dispersion liquid to form the first mixture.

6. The method for making a lithium ion battery anode active material of claim 5 , wherein an organic solvent is added into the water to form the dispersion liquid, the organic solvent is miscible with the silane coupling agent, and a volume ratio of the water to the organic solvent is in a range from about 1:2 to about 1:10.

7. The method for making a lithium ion battery anode active material of claim 6 , wherein the organic solvent is selected from the group consisting of ethanol, methanol, ether, isopropanol, toluene, and combinations thereof.

8. The method for making a lithium ion battery anode active material of claim 5 , wherein the silicon particles are etched by hydrofluoric acid before the silane coupling agent is added into the dispersion liquid, and a ratio of a volume of the hydrofluoric acid to a mass of the silicon particles is in a range from about 0.9 ml/g to about 2 ml/g.

9. The method for making a lithium ion battery anode active material of claim 5 , wherein the silane coupling agent is added drop by drop to the dispersion liquid at a rate in a range from about 0.2 ml/min to about 1 ml/min.

10. The method for making a lithium ion battery anode active material of claim 5 , wherein an acid is added to the first mixture to adjust the pH value and maintain the first mixture at an acidic environment, and the pH value is in a range from about 3 to about 4.

11. The method for making a lithium ion battery anode active material of claim 1 , wherein a mass ratio of the silicon particles to the silane coupling agent is in a range from about 0.1 to about 0.3.

12. The method for making a lithium ion battery anode active material of claim 1 , wherein the silane coupling agent is selected from the group consisting of vinyltriethoxysilane, methyl trimethoxysilane, tetraethoxysilane, vinyl trimethoxy silane, methyl vinyl dimethyl silane, γ-methacryloxypropyl trimethoxy silane (KH570), methacryloxy propyl methyl dimethoxy silane (KH571), γ-aminopropyltriethoxysilane, γ-mercaptopropyl trimethoxysilane, γ-cyanopropyl trimethoxysilane, γ-glycidoxypropyl trimethoxysilane, β-(3,4-epoxycyclohexyl) ethyl trimethoxysilane, γ-aminopropyltrimethoxysilane, and combinations thereof.

13. The method for making a lithium ion battery anode active material of claim 1 , wherein the carbon layer is a continuous layer and uniformly coated on the surfaces of the silicon particles.

Assignees

• Jiangsu Huadong Inst Of Li-Ion Battery Co Ltd
• Univ Tsinghua

Inventors

• Cui qing-wei
• Li Jian-Jun
• He xiang-ming
• Cao Jiang
• Wang Li
• Dai Zhong-Jia

Classifications

• H01M4/0471

  involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis · CPC title

• H01M4/366 Primary

  as layered products · CPC title

• H01M4/386

  Silicon or alloys based on silicon · CPC title

• H01M4/587

  for inserting or intercalating light metals · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title