Method for producing an electrode for a lithium accumulator and associated electrode

Patent metadata

Field	Value
Publication number	US-9825286-B2
Application number	US-201314646756-A
Country	US
Kind code	B2
Filing date	Nov 25, 2013
Priority date	Nov 26, 2012
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

A method for producing an electrode comprising a core-shell nanocomposite material of which the core is made from silicon and the shell from carbon is provided. The method includes A) synthesising the nanocomposite material by pyrolysing a silicon core to form a core and then pyrolysing a a carbon shell precursor to form a carbon shell around the core, wherein the quantities of silicon and carbon precursor are injected in a proportion such that the mass percentage of carbon in the nanocomposite material is greater than or equal to 45%; B) dispersing the nanocomposite material synthesised in step A) in a solvent to form an ink; C) applying this ink to a support intended to form an electricity collector; D) eliminating the solvent from the ink applied to the support in step C) to obtain the electrode; E) pressing or calendaring the electrode.

First claim

The invention claimed is:

1. A method for producing an electrode comprising a core-shell nanocomposite material of which the core is made of silicon and the shell of carbon, characterized in that it includes the following steps:
A) synthesizing the nanocomposite material in accordance with the following substeps:
a) injecting a silicon core precursor into a first chamber of a reactor;
b) pyrolysing the silicon core precursor in order to form the nanoparticle core;
c) transporting the nanoparticle core thus formed in step (b) into a second chamber of the reactor communicating with the first chamber;
d) injecting a carbon shell precursor into the second chamber of the reactor;
e) pyrolysing the shell precursor in order to form the nanoparticle shell and ensure the homogeneous deposition of this shell around the core;
f) collecting the nanoparticles thus formed so as to obtain the nanocomposite material;

in which the quantities of silicon and carbon precursor are injected in a proportion such that the carbon mass fraction in the nanocomposite material is greater than or equal to 45%;
B) dispersing the nanocomposite material synthesized in step A) in a solvent to form an ink;
C) applying this ink onto a support intended to form an electricity collector;
D) eliminating the solvent from the ink applied onto the support in step C) to obtain the electrode;
E) pressing or calendering the electrode.

2. The method as claimed in claim 1 , wherein step a) is performed using an inert gas.

3. The method as claimed in claim 1 , wherein step b) and/or step e) is/are performed by laser pyrolysis.

4. The method as claimed in claim 1 , wherein the quantities of silicon and carbon precursor are injected in a proportion such that the carbon mass fraction in the nanocomposite material is between 45% and 90%.

5. The method as claimed in claim 1 , wherein step B) consists of dispersing an electrically conductive agent in the solvent, in addition to the nanocomposite material, to form the ink.

6. The method as claimed in claim 5 , wherein said electrically conductive agent is carbon black, carbon fibers or carbon nanotubes, or a mixture thereof.

7. The method as claimed in claim 1 , wherein step B) consists of dispersing a polymer binder in the solvent, in addition to the nanocomposite material and, in addition to an electrically conductive agent, where such an electrically conductive agent is present.

8. The method as claimed in claim 1 , wherein step D) includes a step of drying.

9. The method as claimed in claim 1 wherein the quantities of silicon and carbon precursor are injected in a proportion such that the carbon mass fraction in the nanocomposite material is between 60% and 80%.

10. The method as claimed in claim 5 , wherein the conductive agent comprises carbon black, carbon fibers or carbon nanotubes, or a mixture thereof.

Assignees

• Commissariat Energie Atomique

Inventors

• Leconte Yann
• Herlin-Boime Nathalie
• Quinsac Axelle
• Porcher Willy
• Brestaz Marc
• Jouanneau Si Larbi Séverine

Classifications

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• H01M4/583

  Carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/625

  Carbon or graphite · CPC title

• H01M4/1395

  of electrodes based on metals, Si or alloys · CPC title

• H01M10/052

  Li-accumulators · CPC title