Storage element and process for the production thereof

Patent metadata

Field	Value
Publication number	US-9825282-B2
Application number	US-201214239142-A
Country	US
Kind code	B2
Filing date	Sep 3, 2012
Priority date	Sep 27, 2011
Publication date	Nov 21, 2017
Grant date	Nov 21, 2017

Abstract

A storage element for a solid electrolyte battery is provided, having a main member of a porous ceramic matrix in which particles, that are made of a metal and/or a metal oxide and jointly form a redox couple, are embedded, the particles having a lamellar shape.

First claim

The invention claimed is:

1. A storage element for a solid electrolyte battery, comprising
a main body made of a porous ceramic matrix in which particles of a metal and/or a metal oxide are incorporated and occupy a volume that is less than a volume of the ceramic matrix and which together form a redox pair,
wherein the particles have a platelet-like form with an aspect ratio of more than 10, wherein the aspect ratio is a ratio of a long axis and a short axis of the particles.

2. The storage element as claimed in claim 1 , wherein the particles have a median grain size d50 of 10 to 20 μm.

3. The storage element as claimed in claim 1 , wherein the particles have a grain size d90 of less than 60 μm, wherein grain size d90 is a grain size that is not exceeded by 90% of the particles.

4. The storage element as claimed in claim 1 , wherein the particles are oriented with respect to a preferential direction to enhance a packing density of the particles and reduce sintering of the particles.

5. The storage element as claimed in claim 1 , wherein the particles comprise iron and/or an iron oxide.

6. The storage element as claimed in claim 1 , wherein the matrix comprises sintered ceramic particles distinct from the particles of the metal and/or the metal oxide and wherein a portion of a surface area of the particles of the metal and/or the metal oxide is coated with the sintered ceramic particles to prevent the particles of the metal and/or the metal oxide from making mutual contact.

7. The storage element as claimed in claim 6 , wherein the ceramic particles have a median grain size d50 of less than 1 μm.

8. The storage element as claimed in claim 6 , wherein the ceramic particles comprise a redox-inert material.

9. A process for producing a storage element for a solid electrolyte battery, comprising:
shaping a slip of ceramic particles and particles of a metal and/or a metal oxide distinct from the ceramic particles which together form a redox pair to form a green body, which is subsequently sintered, and
separating the particles of metal and/or metal oxide based on sintering the ceramic particles together,
wherein platelet-like particles of metal and/or metal oxide are used.

10. The process as claimed in claim 9 , wherein the green body is shaped by:
moving a sheet casting apparatus in a first direction over a support sheet;
inducing shear forces on the particles of the metal and/or the metal oxide in the slip in a second direction opposite to the first direction based on the moving the sheet;
passing the particles of the metal and/or the metal oxide in the slip through a discharge gap between the moving sheet and the support sheet; and
orienting the particles of the metal and/or the metal oxide in a preferential direction.

11. The process as claimed in claim 9 , wherein, in order to shape the green body, firstly a green sheet is produced on the support sheet by sheet casting, the support sheet is subsequently removed and a plurality of green sheet portions are stacked to form the green body and subsequently laminated and debindered.

12. The process as claimed in claim 9 , wherein micaceous iron oxide particles having a median grain size d50 of 10 to 20 μm and a grain size d90 of less than 60 μm and also an aspect ratio of more than 10 are used as particles of the metal and/or metal oxide.

13. The process as claimed in claim 9 , wherein particles of A 1 2 0 3 , MgO or ZrO 2 having a median grain size d50 of less than 1 μm are used as ceramic particles.

14. The storage element as claimed in claim 5 , wherein the iron oxide comprises micaceous iron oxide.

15. The storage element as claimed in 8 , wherein the redox-inert material comprises A 1 2 O 3 , MgO or ZrO 2 .

16. A storage element for a solid electrolyte battery, comprising
a main body made of a porous ceramic matrix comprising ceramic particles and particles of a metal and/or a metal oxide which together form a redox pair are incorporated,
wherein the particles of the metal and/or the metal oxide have a platelet-like form and a median grain size d50 of at least 10 μm;
and wherein a portion of a surface area of the particles of the metal and/or the metal oxide is coated with the ceramic particles to prevent sintering of the particles of metal and/or metal oxide.

17. The storage element as claimed in claim 16 , wherein the ceramic particles are sintered together and form pores over the surface area such that the surface area is accessible to reaction gas.

18. The storage element as claimed in claim 16 , wherein the ceramic particles have a median grain size d50 of less than 1 μm and wherein the median grain size d50 of the metal and/or metal oxide particles is in a range of 10 to 20 μm.

19. The storage element as claimed in claim 16 , wherein the particles of the metal and/or the metal oxide have an aspect ratio of more than 10 and wherein the ceramic particles comprise a redox-inert material.

20. The storage element as claimed in claim 1 , wherein particles of the metal and the metal oxide are incorporated in the porous ceramic matrix.

Assignees

• Schuh Carsten
• Soller Thomas
• Siemens Ag

Inventors

• Schuh Carsten
• Soller Thomas

Classifications

• Y02E60/50

  Fuel cells · CPC title

• H01M2004/021

  Physical characteristics, e.g. porosity, surface area · CPC title

• H01M4/523

  for non-aqueous cells (H01M4/525 takes precedence) · CPC title

• H01M4/38 Primary

  of elements or alloys · CPC title

• H01M4/803

  of only powdered material · CPC title